Corrosion Protection Efficiency of Bilayer Porphyrin-Polyaniline Film Deposited on Carbon Steel

2015 ◽  
Vol 352 (1) ◽  
pp. 16-24 ◽  
Author(s):  
Iuliana Popa ◽  
Eugenia Fagadar-Cosma ◽  
Bogdan-Ovidiu Taranu ◽  
Mihaela Birdeanu ◽  
Gheorghe Fagadar-Cosma ◽  
...  
Keyword(s):  
Carbon Steel ◽  
Corrosion Protection ◽  
Protection Efficiency ◽  
Polyaniline Film

scholarly journals Fabrication and evaluation of Rb2Co(H2P2O7)2·2H2O/waterborne polyurethane nanocomposite coating for corrosion protection aspects

RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55074-55080 ◽  
Author(s):  
M. A. Deyab ◽  
R. Essehli ◽  
B. El Bali ◽  
M. Lachkar
Keyword(s):  
Carbon Steel ◽  
Corrosion Protection ◽  
Waterborne Polyurethane ◽  
Nanocomposite Coating ◽  
Nacl Solution ◽  
Protection Efficiency

Here we investigate the influence of new acidic pyrophosphate (Rb2Co(H2P2O7)2·2H2O) (DP) incorporation in waterborne polyurethane (WBPU) coatings on the corrosion protection efficiency of WBPU coatings for carbon steel in 3.5% NaCl solution.

Surface modification of graphene-coated carbon steel using aromatic molecules for enhancing corrosion resistance; comparison between type of aryl substitution with different spatial situations

2018 ◽  
Vol 65 (3) ◽  
pp. 249-262 ◽  
Author(s):  
Zahra Shams Ghahfarokhi ◽  
Mojtaba Bagherzadeh ◽  
Ebrahim Ghiamati Yazdi ◽  
Abbas Teimouri
Keyword(s):  
Surface Modification ◽  
Carbon Steel ◽  
Corrosion Protection ◽  
Protection Efficiency ◽  
Graphene Surface ◽  
Content Type ◽  
X Ray ◽  
Aromatic Molecules ◽  
Proposed Modification ◽  
Coated Carbon

Purpose The purpose of this paper is study of the type of functional group and its situation on phenyl molecule, in increasing the corrosion protection of modified graphene layers by it. Corrosion protection efficiency of graphene was raised via modifying the surface of graphene-coated carbon steel (CS/G) by using aromatic molecules. Phenyl groups with three different substitutions including COOH, NO2 and CH3 grafted to graphene via diazonium salt formation route, by using carboxy phenyl, nitro phenyl and methyl phenyl diazonium salts in ortho, meta and para spatial situations. Design/methodology/approach Molecular bindings were characterized by using X-ray diffractometer, fourier-transform infrared spectroscopy (FTIR), Raman and scanning electron microscopy (SEM)/ energy dispersive X-ray analysis (EDXA) methods. Anti-corrosion performance of modified CS/G electrodes was evaluated by weight loss and electrochemical techniques, potentiodynamic polarization (Tafel) and electrochemical impedance spectroscopy, in 3.5 per cent NaCl solution. Findings The obtained results confirmed covalently bonding of phenyl groups to the graphene surface. Also, the observed results showed that substitution spatial situations on phenyl groups can affect charge transfer resistance (Rct), corrosion potential (Ecorr), corrosion current density (jcorr) and the slope of the anodic and cathodic reaction (ßa,c), demonstrating that the proposed modification method can hinder the corrosion reactions. The proposed modification led to restoring the graphene surface defects and consequently increasing its corrosion protection efficiency. Originality/value The obtained results from electrochemical methods proved that protection efficiency was observed in order COOH < NO2 < CH3 and MPD in the para spatial situation and showed the maximum protection efficiency of 98.6 per cent in comparison to other substitutions. Finally, the ability of proposed graphene surface modification route was further proofed by using surface methods, i.e. SEM and EDXA, and contact angles measurements.

scholarly journals Corrosion Protection Study of Carbon Steel and 316 Stainless Steel Alloys Coated by Nanoparticles

2014 ◽  
Vol 11 (1) ◽  
pp. 116-122
Author(s):  
Baghdad Science Journal
Keyword(s):  
Stainless Steel ◽  
Zinc Oxide ◽  
Carbon Steel ◽  
Atomic Force Microscope ◽  
Corrosion Protection ◽  
Saline Water ◽  
Steel Alloys ◽  
Protection Efficiency ◽  
316 Stainless Steel ◽  
Atomic Force

The Corrosion protection effectiveness of Alimina(Al2O3,50nm)and Zinc oxide (ZnO,30nm) nanoparticales were studied on carbon steel and 316 stainless steel alloys in saline water (3.5%NaCl)at four temperatures: (20,30,40,50 OC)using three electrodes potentiostat. An average corrosion protection efficiencies of 65 %and 80% was achieved using Al2O3 NP's on carbon steel and stainless steel samples respectively, and it seems that no effect of rising temperature on the performances of the coated layers. While ZnO NP'S showed protection efficiency around 65% for the two alloys and little effected by temperature rising on the performanes of the coated layers. The morphology of the coated spesiemses was examined by Atomic force microscope.

AK STEEL 409 ULTRA FORM

Alloy Digest ◽  
2007 ◽  
Vol 56 (4) ◽  
Keyword(s):  
Stainless Steel ◽  
High Temperature ◽  
Carbon Steel ◽  
Physical Properties ◽  
Tensile Properties ◽  
Corrosion Protection ◽  
Automotive Exhaust ◽  
Standard Type ◽  
Temperature Performance ◽  
Complex Shapes

Abstract AK Steel 409 Ultra Form was created for applications needing oxidation or corrosion protection beyond the capability of carbon steel and some coated steels. AK Steel 409 Ultra Form is more formable than standard Type 409 stainless steel and is particularly suitable for parts requiring more complex shapes and improved weldability. Examples of applications include automotive exhaust tubing and stampings. This datasheet provides information on physical properties, hardness, elasticity, and tensile properties as well as deformation. It also includes information on high temperature performance as well as forming and joining. Filing Code: SS-990. Producer or source: AK Steel, Butler Operations.

Performance of coatings containing treated silica fume in the corrosion protection of reinforced concrete

2018 ◽  
Vol 47 (4) ◽  
pp. 350-359 ◽  
Author(s):  
Nivin M. Ahmed ◽  
Mostafa G. Mohamed ◽  
Reham H. Tammam ◽  
Mohamed R. Mabrouk
Keyword(s):  
Reinforced Concrete ◽  
Silica Fume ◽  
Corrosion Protection ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Dual Function ◽  
Core Shell ◽  
Protection Efficiency ◽  
Content Type ◽  
Anticorrosive Pigments

Purpose This study aims to apply novel anticorrosive pigments containing silica fume-phosphates (Si-Ph), which were prepared using core-shell technique by covering 80-90 per cent silica fume (core) with 10-20 per cent phosphates (shell) previously, to play dual functions simultaneously as anticorrosive pigments in coating formulations and as an anticorrosive admixture in concrete even if it is not present in the concrete itself. Two comparisons were held out to show the results of coatings on rebars containing core-shell pigments in concrete, and concrete admixtured with silica fume can perform a dual function as anticorrosive pigment and concrete admixture. The evaluation of corrosion protection efficiency of coatings containing core-shell pigments and those containing phosphates was performed. Design/methodology/approach Simple chemical techniques were used to prepare core-shell pigments, and their characterization was carried out in a previous work. These pigments were incorporated in solvent-based paint formulations based on epoxy resin. Different electrochemical techniques such as open-circuit potential and electrochemical impedance spectroscopy were used to evaluate the anticorrosive efficiency of the new pigments. Findings The electrochemical measurements showed that concrete containing coated rebars with core-shell pigments exhibited almost similar results to that of concrete admixtured with silica fume. Also, the anticorrosive performance of coatings containing Si-Ph pigments offered protection efficiency almost similar to that of phosphates, proving that these new pigments can perform both roles as anticorrosive pigment and concrete admixture. Originality/value Although the new Si-Ph pigments contain more than 80 per cent waste material, its performance can be compared to original phosphate pigments in the reinforced concrete.

Synthesis, characterization and corrosion protection properties of polyN-(p-bromophenyl)-2-methacrylamide-co-glycidyl methacrylate on low nickel stainless steel

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Sakvai Mohammed Safiullah ◽  
Deivasigamani Thirumoolan ◽  
Kottur Anver Basha ◽  
K. Mani Govindaraju ◽  
Dhanraj Gopi ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Corrosion Protection ◽  
Glycidyl Methacrylate ◽  
Electrochemical Impedance ◽  
Thermo Gravimetric Analysis ◽  
Gel Permeation Chromatography ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Protection Efficiency ◽  
Ft Ir

Abstract The synthesis of copolymers from different feed ratios of N-(p-bromophenyl)-2- methacrylamide (PBPMA) and glycidyl methacrylate (GMA) was achieved by using free radical solution polymerization technique and characterized using FT-IR, 1H and 13C NMR spectroscopy. The thermal stability of the synthesized copolymers was studied using thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The molecular weight of the copolymer is determined by gel permeation chromatography (GPC). The corrosion performances of low nickel stainless steel specimens dip coated with different composition of copolymers were investigated in 0.5 M H2SO4 using potentiodynamic polarization and electrochemical impedance spectroscopic (EIS) techniques. The polarization and impedance measurements showed different corrosion protection efficiency with change in composition of the copolymers. It was found that the corrosion protection properties are owing to the barrier effect of the polymer layer covered on the low nickel stainless steel surfaces. However, it is observed that the mole ratio of PBPMA and GMA plays a major role in the protective nature of the copolymer.

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