Polymers with Alkylsulfanyl Side Chains for Bulk Heterojunction Solar Cells: Toward a Greener Strategy

2017 ◽  
Vol 218 (16) ◽  
pp. 1700111 ◽  
Author(s):  
Francesco Tassinari ◽  
Emanuela Libertini ◽  
Francesca Parenti ◽  
Barbara Ballarin ◽  
Francesco Paolo Di Nicola ◽  
...  
2015 ◽  
Vol 203 ◽  
pp. 221-227 ◽  
Author(s):  
Su Jung Park ◽  
Ji Eun Jung ◽  
Min Kwan Kang ◽  
Yang Ho Na ◽  
Hyun Hoon Song ◽  
...  

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Alexander Kovalenko ◽  
Jana Honová ◽  
Martin Vala ◽  
Stanislav Luňák ◽  
Ladislav Fekete ◽  
...  

An optimized fabrication of bulk-heterojunction solar cells (BHJ SCs) based on previously reported diketopyrrolopyrrole donor, ethyl-hexylated DPP(TBFu)2, as well as two new DPP(TBFu)2derivatives with ethyl-hexyl acetate and diethyl acetal solubilizing side-chains and PC60BM as an acceptor is demonstrated. Slow gradual annealing of the solar cell causing the effective donor-acceptor reorganization, and as a result higher power conversion efficiency (PCE), is described. By replacing a hole transporting layer PEDOT:PSS with MoO3we obtained higher PCE values as well as higher thermal stability of the anode contact interface. DPP(TBFu)2derivative containing ethyl-hexyl acetate solubilizing side-chains possessed the best as-cast self-assembly and high crystallinity. However, the presence of ethyl-hexyl acetate and diethyl acetal electrophilic side-chains stabilizes HOMO energy of isolated DPP(TBFu)2donors with respect to the ethyl-hexylated one, according to cyclic voltammetry.


2019 ◽  
Author(s):  
Jafar Khan ◽  
Yuliar Firdaus ◽  
Federico Cruciani ◽  
Shengjian Liu ◽  
Denis Andrienko ◽  
...  

2012 ◽  
Vol 22 (36) ◽  
pp. 19258 ◽  
Author(s):  
Junichi Hatano ◽  
Naoki Obata ◽  
Shigeru Yamaguchi ◽  
Takeshi Yasuda ◽  
Yutaka Matsuo

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