Aqueous Emulsion Polymerization of Substituted Acetylenes: Effects of Organic Solvent and Analysis of Blue Shifts and Emulsion Polymerization Mechanism

2012 ◽  
Vol 213 (6) ◽  
pp. 603-609 ◽  
Author(s):  
Bo Chen ◽  
Xuan Liu ◽  
Chuqi Xu ◽  
Ci Song ◽  
Xiaofeng Luo ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Emulsion Polymerization ◽  
Aqueous Emulsion ◽  
Polymerization Mechanism ◽  
Substituted Acetylenes

scholarly journals Synthesis of diblock copolymer spheres, worms and vesicles via RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate

2021 ◽  
Author(s):  
Saul J. Hunter ◽  
Joseph R. Lovett ◽  
Oleksandr O. Mykhaylyk ◽  
Elizabeth R. Jones ◽  
Steven P. Armes
Keyword(s):  
Phase Diagram ◽  
Emulsion Polymerization ◽  
Diblock Copolymer ◽  
Aqueous Emulsion

RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate using a poly(glycerol monomethacrylate) precursor leads to diblock copolymer spheres, worms or vesicles. A pseudo-phase diagram is constructed and the vesicles are briefly evaluated as a Pickering emulsifier.

A “green” method for preparing ABCBA penta-block elastomers by using RAFT emulsion polymerization

2017 ◽  
Vol 8 (19) ◽  
pp. 3013-3021 ◽  
Author(s):  
Zhi Qiao ◽  
Teng Qiu ◽  
Weiwei Liu ◽  
Liangdong Zhang ◽  
Jinqiang Tu ◽  
...  
Keyword(s):  
Organic Solvent ◽  
Emulsion Polymerization ◽  
Raft Polymerization ◽  
Solvent Free ◽  
Emulsion System ◽  
Green Method ◽  
One Pot ◽  
Block Terpolymers

A clean method for preparing ABCBA penta-block terpolymers was developed in a surfactant and organic solvent free emulsion system via one-pot RAFT polymerization.

scholarly journals Tuning the membrane permeability of polymersome nanoreactors developed by aqueous emulsion polymerization-induced self-assembly

Nanoscale ◽  
2019 ◽  
Vol 11 (26) ◽  
pp. 12643-12654 ◽  
Author(s):  
Spyridon Varlas ◽  
Jeffrey C. Foster ◽  
Panagiotis G. Georgiou ◽  
Robert Keogh ◽  
Jonathan T. Husband ◽  
...  
Keyword(s):  
Membrane Permeability ◽  
Emulsion Polymerization ◽  
Self Assembly ◽  
Primary Amines ◽  
Cross Linking ◽  
Membrane Modification ◽  
Aqueous Emulsion

Membrane modification of epoxy-functionalized enzyme-loaded polymersomes using a series of primary amines and cross-linking diamines of increasing hydrophobicity resulted in functional nanoreactors with tunable permeability.

Block copolymers as polymeric stabilizers in non-aqueous emulsion polymerization

2011 ◽  
Vol 60 (11) ◽  
pp. 1563-1573 ◽  
Author(s):  
Leonard-I. Atanase ◽  
Gérard Riess
Keyword(s):  
Block Copolymers ◽  
Emulsion Polymerization ◽  
Aqueous Emulsion

Novel reactive polymerizable nonyl phenol ethoxylate surfactants as emulsifier in non-aqueous emulsion polymerization

2014 ◽  
Vol 56 (6) ◽  
pp. 770-787 ◽  
Author(s):  
Ayman M. Atta ◽  
Amro K. F. Dyab ◽  
Hamad A. Al-Lohedan ◽  
Khaled A. AlJenady
Keyword(s):  
Emulsion Polymerization ◽  
Nonyl Phenol ◽  
Aqueous Emulsion ◽  
Nonyl Phenol Ethoxylate

scholarly journals Synthesis of well-defined epoxy-functional spherical nanoparticles by RAFT aqueous emulsion polymerization

2017 ◽  
Vol 8 (33) ◽  
pp. 4856-4868 ◽  
Author(s):  
Fiona L. Hatton ◽  
Joseph R. Lovett ◽  
Steven P. Armes
Keyword(s):  
Emulsion Polymerization ◽  
Sodium Azide ◽  
Glycidyl Methacrylate ◽  
Environmentally Friendly ◽  
Spherical Nanoparticles ◽  
Aqueous Emulsion ◽  
Mild Conditions

The environmentally-friendly synthesis of epoxy-functional spherical nanoparticles is achieved via RAFT aqueous emulsion polymerization of glycidyl methacrylate under mild conditions; derivatization of such nanoparticles with sodium azide or diamines is demonstrated.

Aqueous emulsion polymerizations of methacrylates and styrene via reversible complexation mediated polymerization (RCMP)

2021 ◽  
Author(s):  
Weijia Mao ◽  
Jit Sarkar ◽  
Bo Peng ◽  
Atsushi Goto
Keyword(s):  
Methyl Methacrylate ◽  
Emulsion Polymerization ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Aqueous Emulsion ◽  
Poly Methyl Methacrylate ◽  
Emulsion Polymerizations

Aqueous emulsion polymerization via reversible complexation mediated living radical polymerization yielded low-dispersity poly(methyl methacrylate)s and polystyrenes.

A New Living Emulsion Polymerization Mechanism:  Episulfide Anionic Polymerization

2002 ◽  
Vol 35 (23) ◽  
pp. 8688-8693 ◽  
Author(s):  
A. Rehor ◽  
N. Tirelli ◽  
J. A. Hubbell
Keyword(s):  
Emulsion Polymerization ◽  
Anionic Polymerization ◽  
Polymerization Mechanism
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