A New Living Emulsion Polymerization Mechanism:  Episulfide Anionic Polymerization

2002 ◽  
Vol 35 (23) ◽  
pp. 8688-8693 ◽  
Author(s):  
A. Rehor ◽  
N. Tirelli ◽  
J. A. Hubbell
Keyword(s):  
Emulsion Polymerization ◽  
Anionic Polymerization ◽  
Polymerization Mechanism

Anionic polymerization of .beta.-lactones initiated with alkali-metal alkoxides: reinvestigation of the polymerization mechanism

1992 ◽  
Vol 25 (7) ◽  
pp. 2017-2020 ◽  
Author(s):  
Piotr Kurcok ◽  
Marek Kowalczuk ◽  
Krystian Hennek ◽  
Zbigniew Jedlinski
Keyword(s):  
Alkali Metal ◽  
Anionic Polymerization ◽  
Metal Alkoxides ◽  
Polymerization Mechanism

scholarly journals Emulsion Polymerization of Chloroprene. Polymerization Mechanism and Evaluation of Crosslinking Density

1991 ◽  
Vol 23 (7) ◽  
pp. 859-864 ◽  
Author(s):  
Kenji Itoyama ◽  
Nobuhiro Hirashima ◽  
Junji Hirano ◽  
Takashi Kadowaki
Keyword(s):  
Emulsion Polymerization ◽  
Crosslinking Density ◽  
Polymerization Mechanism

Incorporation of Nonionic Emulsifiers Inside Particles in Emulsion Polymerization:  Mechanism and Methods of Suppression†

Langmuir ◽  
2006 ◽  
Vol 22 (21) ◽  
pp. 8727-8731 ◽  
Author(s):  
Masayoshi Okubo ◽  
Hiroshi Kobayashi ◽  
Takumi Matoba ◽  
Yoshiteru Oshima
Keyword(s):  
Emulsion Polymerization ◽  
Polymerization Mechanism

Application of a Novel Initiator on Acrylic Emulsion Polymerization

2011 ◽  
Vol 233-235 ◽  
pp. 1415-1418
Author(s):  
Shao Guo Wen ◽  
Shi Gao Song ◽  
Hong Bo Liu ◽  
Ji Hu Wang ◽  
Qian Xu ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Reaction Rate ◽  
The Other ◽  
Polymerization Reaction ◽  
Polymerization Temperature ◽  
Acrylic Emulsion ◽  
Polymerization Mechanism ◽  
Lower Temperature ◽  
Classical Mechanism ◽  
Mechanism Of The Reaction

New initiator of FFM6 is used to initiate the acrylic emulsion polymerization. The influences of concentration of FFM6 (c[I]) and polymerization temperature (T) on polymerization reaction rate (Rp) were discussed. Rp is proportional to (c[I])1.4 which is different with classical emulsion polymerization whose Rp is proportion to (c[I])0.4, that indicate polymerization mechanism of the reaction in the study is different with classical mechanism. The value of Ea, 56.4 kJ/mol, is lower than the value of general radical polymerization’s Ea (80.0-96.0 kJ/mol), which indicates the FFM6 can initiate acrylic emulsion polymerization at a lower temperature compared with the other kinds of initiator.

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