Atom Transfer Radical Copolymerization of?-Olefins with Methyl Acrylate: Determination of Activation Rate Parameters

2005 ◽  
Vol 206 (5) ◽  
pp. 547-552 ◽  
Author(s):  
Rajan Venkatesh ◽  
Frank Vergouwen ◽  
Bert Klumperman
Keyword(s):  
Methyl Acrylate ◽  
Radical Copolymerization ◽  
Atom Transfer ◽  
Activation Rate

Determination of Gel Point during Atom Transfer Radical Copolymerization with Cross-Linker

2007 ◽  
Vol 40 (22) ◽  
pp. 7763-7770 ◽  
Author(s):  
Haifeng Gao ◽  
Ke Min ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Radical Copolymerization ◽  
Gel Point ◽  
Atom Transfer ◽  
Cross Linker

Atom Transfer Radical Copolymerization of Acrylamide Under Microwave Irradiation

2013 ◽  
Vol 30 (4) ◽  
pp. 398
Author(s):  
Wei DING ◽  
Ling WANG ◽  
Tao YU ◽  
Guangmiao QU ◽  
Xiang GAO ◽  
...  
Keyword(s):  
Microwave Irradiation ◽  
Radical Copolymerization ◽  
Atom Transfer

Comparison of the viscoelastic penetration and tensile behaviour of poly(methyl acrylate) and poly(ethyl acrylate)

1979 ◽  
Vol 44 (6) ◽  
pp. 1942-1948 ◽  
Author(s):  
Jaroslav Hrouz ◽  
Michal Ilavský ◽  
Ivan Havlíček ◽  
Karel Dušek
Keyword(s):  
Methyl Acrylate ◽  
Poisson Ratio ◽  
Young Modulus ◽  
Ethyl Acrylate ◽  
Sample Volume ◽  
Viscoelastic Behaviour ◽  
Tensile Behaviour ◽  
Temperature Superposition ◽  
Main Transition

The viscoelastic penetration and tensile behaviour of poly(methyl acrylate) and poly(ethyl acrylate) in the main transition region have been investigated. It was found that the time-temperature superposition could be carried out in the case of the penetration viscoelastic behaviour; the temperature dependence of the penetration and tensile shift factors was the same. The superimposed curves of the penetration and Young modulus allowed us to calculate the dependence of the Poisson ratio and thus to characterize the change in sample volume with deformation. It was demonstrated that the penetration method of determination of the viscoelastic behaviour is equivalent to the tensile method.

Development of Branching in Atom Transfer Radical Copolymerization of Styrene with Triethylene Glycol Dimethacrylate

2009 ◽  
Vol 42 (16) ◽  
pp. 5976-5982 ◽  
Author(s):  
Hong-Jun Yang ◽  
Bi-Biao Jiang ◽  
Wen-Yan Huang ◽  
Dong-Liang Zhang ◽  
Li-Zhi Kong ◽  
...  
Keyword(s):  
Triethylene Glycol ◽  
Radical Copolymerization ◽  
Atom Transfer ◽  
Glycol Dimethacrylate ◽  
Triethylene Glycol Dimethacrylate
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