Kinetics of a second order reaction involving two intermediate second order reactions

1992 ◽  
Vol 24 (5) ◽  
pp. 455-466 ◽  
Author(s):  
Richard A. Klemm ◽  
Leroy H. Klemm
Keyword(s):  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Kinetics Of

Kinetics of the reaction between hexamethylenediisocyanate and 1-pentanol

1983 ◽  
Vol 48 (11) ◽  
pp. 3279-3286
Author(s):  
Slavko Hudeček ◽  
Miloslav Bohdanecký ◽  
Ivana Hudečková ◽  
Pavel Špaček ◽  
Pavel Čefelín
Keyword(s):  
Liquid Chromatography ◽  
Rate Constants ◽  
Reversed Phase ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Reversed Phase Liquid Chromatography ◽  
Consecutive Reactions ◽  
Phase Liquid ◽  
Kinetics Of

The reaction between hexamethylenediisocyanate and 1-pentanol in toluene was studied by means of reversed-phase liquid chromatography. By employing this method, it was possible to determine all components of the reaction mixture including both products, i.e. N-(6-isocyanate hexyl)pentylcarbamate and N,N'-bis(pentyloxycarbonyl)hexamethylenediamine. Relations for the calculation of kinetic constants were derived assuming a competitive consecutive second-order reaction. It was demonstrated that the reaction involved in this case is indeed a second-order reaction, and the rate constants of the first and second consecutive reactions were determined.

Kinetics and thermodynamics of the reaction between thyroxine and antithyroxine antiserum under the conditions of radioimmunoanalysis

1982 ◽  
Vol 47 (8) ◽  
pp. 2077-2086
Author(s):  
Peter Talán ◽  
Juraj Mucha
Keyword(s):  
Reaction Rate ◽  
Serum Proteins ◽  
Relative Rate ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Reaction Enthalpy ◽  
Thermodynamics And Kinetics ◽  
Relative Rate Constants ◽  
Kinetics Of

Thermodynamics and kinetics of the reaction between thyroxine and antithyroxine antiserum has been studied using the concentration and temperature conditions usual in the radioimmunoanalysis. The reaction is assumed to be homogeneous and of the second order. Because of the initial concentrations of thyroxine and of the free bonds of the heterogeneous population of antibodies present in the used antiserum the rate constant equation for second-order reaction has been used in the integrated form. The relative rate constants have been obtained and the activation energy of the reaction in absence of the serum proteins in the reaction mixture or, respectively, in the presence of the euthyroidic serum has been calculated. The nature of the effect of so-called deblockators (J) (8-anilino-1-naphthalene sulphonic acid and tiomersal) on the reaction rate and on the change of the reaction enthalpy (or entropy) has also been investigated. The association constant of this reaction has been evaluated from the radioimmunoanalytical data transformed by the Scatchard relation, modified for the conditions of thyroxine radioimmunoanalysis.

Flow effects on the kinetics of a second-order reaction

2008 ◽  
Vol 140 (1-3) ◽  
pp. 370-380 ◽  
Author(s):  
Kien T. Nguyen ◽  
Dimitrios V. Papavassiliou
Keyword(s):  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
Flow Effects ◽  
Kinetics Of

scholarly journals DENITRIFICATION KINETICS OF PSEUDOMONAS STUTZERI AZ101

2019 ◽  
Vol 7 (7) ◽  
pp. 247-255
Author(s):  
Ahmad Idi
Keyword(s):  
Nitrogen Removal ◽  
Reaction Kinetic ◽  
Pseudomonas Stutzeri ◽  
Order Reaction ◽  
Second Order ◽  
Second Order Reaction ◽  
16S Rrna Analysis ◽  
Denitrification Kinetics ◽  
Aquaculture Wastewater ◽  
Kinetics Of

Nitrogen removal from environment is significant due to its effect on health and the whole ecosystems. Hence a highly nitrogen tolerant aerobic denitrifier, Pseudomonas stutzeri AZ101 was isolated from aquaculture wastewater and characterized using 16S rRNA analysis. The ability of the isolate to carry out simultaneously nitrification and denitrification (SND) was investigated. Different initial concentrations of nitrate and ammonium were used to determine the rate of SND. The denitrification data fitted well with the second order reaction kinetics with correlation coefficient between 0.923-0.9588. The nitrification data does not fit to both first and second order reaction kinetic but progressive shifts in the logarithm phase of the growth were observed at different initial concentrations. The kinetics data provide a significant insight to nitrogen removal from the wastewater.

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