Kinetic Investigation of Oxidation of Aromatic Anils by Potassium Peroxymonosulfate in Aqueous Acidic Medium

2013 ◽  
Vol 45 (8) ◽  
pp. 542-550 ◽  
Author(s):  
R. Venkatesh ◽  
K. Karunakaran
2014 ◽  
Vol 2014 ◽  
pp. 1-4
Author(s):  
B. Myek ◽  
S. O. Idris ◽  
J. F. Iyun

The kinetics of the oxidation of naphthol green B (NGB3−) by peroxydisulphate ion has been carried out in aqueous acidic medium at λmax of 700 nm, T=23±1°C, and I=0.50 mol dm−3 (NaCl). The reaction shows a first-order dependence on oxidant and reductant concentration, respectively. The stoichiometry of the NGB—S2O82- reaction is 1 : 2. Change in hydrogen ions concentration of the reaction medium has no effect on the rate of the reaction. Added cations and anions decreased the rate of the reaction. The results of spectroscopic and kinetic investigation indicate that no intermediate complex is probably formed in the course of this reaction.


2002 ◽  
Vol 5 (1) ◽  
pp. 21-26
Author(s):  
Sang-Jin Choi ◽  
Chil-Hoon Doh ◽  
Seong-In Moon ◽  
Mun-Su Yun ◽  
Gyeong-Chang Yug ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (62) ◽  
pp. 37695-37706
Author(s):  
José Eudes L. Santos ◽  
Djalma R. da Silva ◽  
Carlos A. Martínez-Huitle ◽  
Elisama Vieira dos Santos ◽  
Marco A. Quiroz

In this work, the electrochemical oxidation of a dye and an herbicide was investigated on non-active anodes in aqueous acidic medium in order to understand its effect to produce simultaneously hydrogen as eco-friendly energy alternative.


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