Raman study of lithium coordination in EMI-TFSI additive systems as lithium-ion battery ionic liquid electrolytes

2006 ◽  
Vol 38 (1) ◽  
pp. 110-112 ◽  
Author(s):  
Laurence J. Hardwick ◽  
Michael Holzapfel ◽  
Alexander Wokaun ◽  
Petr Novák
2015 ◽  
Author(s):  
Kisoo Yoo ◽  
Prashanta Dutta ◽  
Soumik Banerjee

A mathematical model is developed for transport of ionic components to study the performance of ionic liquid based lithium batteries. The mathematical model is based on a univalent ternary electrolyte frequently encountered in ionic liquid electrolytes used for lithium batteries. Owing to the very high concentration of components in ionic liquid, the transport of lithium ions are described by the mutual diffusion phenomena using Maxwell-Stefan diffusivity. The model is used to study a lithium ion battery where the cations and anions of ionic liquid are mppy+ and TFSI-. The electric performance results predicted by the model are in good agreement with experimental data. We also studied the effect of load current density on the performance of lithium ion battery using this model. Numerical results indicate that low rate of lithium ion transport causes lithium depleted zone in the porous cathode regions as the load current density increases. This lithium depleted region is responsible for lower specific capacity in lithium-ion cells. The model presented in this study can be used for optimum design of ionic liquid electrolytes for lithium-ion and lithium-air batteries.


2020 ◽  
Vol 32 (18) ◽  
pp. 1904205 ◽  
Author(s):  
Candice F. J. Francis ◽  
Ilias L. Kyratzis ◽  
Adam S. Best

2020 ◽  
Vol 1 (4) ◽  
pp. 625-631 ◽  
Author(s):  
Kei Hosoya ◽  
Toshiki Kamidaira ◽  
Tetsuya Tsuda ◽  
Akihito Imanishi ◽  
Masakazu Haruta ◽  
...  

An appropriate combination of Si anodes and binary bis(fluorosulfonyl)amide-based ionic liquid electrolytes significantly improves Li-ion battery performances.


2020 ◽  
Vol 479 ◽  
pp. 228791 ◽  
Author(s):  
S. Brutti ◽  
E. Simonetti ◽  
M. De Francesco ◽  
A. Sarra ◽  
A. Paolone ◽  
...  

2016 ◽  
Vol 72 ◽  
pp. 148-152 ◽  
Author(s):  
Guojun Wang ◽  
Shaohua Fang ◽  
Dong Luo ◽  
Li Yang ◽  
Shin-ichi Hirano

2016 ◽  
Vol 22 (20) ◽  
pp. 6808-6814 ◽  
Author(s):  
Giuseppe Antonio Elia ◽  
Ulderico Ulissi ◽  
Franziska Mueller ◽  
Jakub Reiter ◽  
Nikolaos Tsiouvaras ◽  
...  

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