scholarly journals Tip-enhanced Raman spectroscopy (TERS) of malachite green isothiocyanate at Au(111): bleaching behavior under the influence of high electromagnetic fields

2005 ◽  
Vol 36 (6-7) ◽  
pp. 541-550 ◽  
Author(s):  
Bruno Pettinger ◽  
Bin Ren ◽  
Gennaro Picardi ◽  
Rolf Schuster ◽  
Gerhard Ertl
Keyword(s):  
Raman Spectroscopy ◽  
Electromagnetic Fields ◽  
Malachite Green ◽  
Tip Enhanced Raman Spectroscopy

scholarly journals Plasmonic Photocatalysts Monitored by Tip-Enhanced Raman Spectroscopy

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 109 ◽  
Author(s):  
Jingang Wang ◽  
Xinxin Wang ◽  
Xijiao Mu
Keyword(s):  
Raman Spectroscopy ◽  
Malachite Green ◽  
Resonance Raman Spectroscopy ◽  
High Vacuum ◽  
Time Dependent ◽  
Hot Electrons ◽  
Dissociation Process ◽  
Green Is ◽  
General Chemical ◽  
Tip Enhanced Raman Spectroscopy

In this review, we first prove the resonance dissociation process by using time-dependent measurements of tip-enhanced resonance Raman spectroscopy (TERRS) under high vacuum conditions. Second, we show how to use thermal electrons to dissociate Malachite Green (MG) and the hot electrons in the nanogap of the high vacuum tip-enhanced Raman spectroscopy (TERS) device that are generated by plasma decay. Malachite Green is excited by resonance and adsorbed on the Ag and Au surfaces. Finally, we describe real-world and real-time observations of plasmon-induced general chemical reactions of individual molecules.

Surface-and tip-enhanced Raman spectroscopy of silicon

2008 ◽  
Author(s):  
K. J. Yi ◽  
X. N. He ◽  
W. Q. Yang ◽  
Y. S. Zhou ◽  
W. Xiong ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Tip Enhanced Raman Spectroscopy

Capability of tip-enhanced Raman spectroscopy about nanoscale analysis of strained silicon for semiconductor devices production

2017 ◽  
Vol 110 (10) ◽  
pp. 103105 ◽  
Author(s):  
Arianna Lucia ◽  
Onofrio Antonino Cacioppo ◽  
Enrico Iulianella ◽  
Luca Latessa ◽  
Giuseppe Moccia ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Semiconductor Devices ◽  
Strained Silicon ◽  
Tip Enhanced Raman Spectroscopy

Recent Advances in Tip-Enhanced Raman Spectroscopy

2014 ◽  
Vol 5 (18) ◽  
pp. 3125-3130 ◽  
Author(s):  
Matthew D. Sonntag ◽  
Eric A. Pozzi ◽  
Nan Jiang ◽  
Mark C. Hersam ◽  
Richard P. Van Duyne
Keyword(s):  
Raman Spectroscopy ◽  
Recent Advances ◽  
Tip Enhanced Raman Spectroscopy

scholarly journals Fabrication of highly uniform nanoprobe via the automated process for tip-enhanced Raman spectroscopy

Nanophotonics ◽  
2020 ◽  
Vol 9 (9) ◽  
pp. 2989-2996
Author(s):  
Dong Hyeon Kim ◽  
Chanwoo Lee ◽  
Byeong Geun Jeong ◽  
Sung Hyuk Kim ◽  
Mun Seok Jeong
Keyword(s):  
Raman Spectroscopy ◽  
Human Error ◽  
Acidic Solution ◽  
High Spatial Resolution ◽  
Electrochemical Etching ◽  
Radius Of Curvature ◽  
Enhanced Raman Scattering ◽  
Tip Enhanced Raman Spectroscopy ◽  
Highly Uniform ◽  
Etching System

AbstractIn a tip-enhanced Raman spectroscopy (TERS) system, using a sharp nanotip that comprises a noble metal is critical to attaining high spatial resolution and highly enhanced Raman scattering. A strongly acidic solution is typically used to fabricate gold nanotips in a quick and reliable manner. However, using an acidic solution could corrode the etching system, thereby posing hazardous problems. Therefore, both the corrosion of the etching system and human error induced by the conventional method considerably decrease the quality and reproducibility of the tip. In this study, we significantly increased the reproducibility of tip fabrication by automating the electrochemical etching system. In addition, we optimized the etching conditions for an etchant that comprised a KCl solution to which ethanol was added to overcome the limitations of the acidic etchant. The automated etching system significantly increases the yield rate of tip-fabrication reproducibility from 65 to 95%. The standard deviation of the radius of curvature decreased to 7.3 nm with an average radius of curvature of 30 nm. Accordingly, the automated electrochemical etching system might improve the efficiency of TERS.

scholarly journals Tip enhanced Raman spectroscopy imaging of opaque samples in organic liquid

2016 ◽  
Vol 18 (23) ◽  
pp. 15510-15513 ◽  
Author(s):  
T. Touzalin ◽  
A. L. Dauphin ◽  
S. Joiret ◽  
I. T. Lucas ◽  
E. Maisonhaute
Keyword(s):  
Raman Spectroscopy ◽  
Organic Liquid ◽  
Tip Enhanced Raman Spectroscopy

We demonstrate the feasibility of Tip Enhanced Raman Spectroscopy in liquid for an upright illumination/collection configuration.

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