Estimating the relative stability of polymorphs and hydrates from heats of solution and solubility data

2001 ◽  
Vol 90 (9) ◽  
pp. 1277-1287 ◽  
Author(s):  
Chong‐Hui Gu ◽  
David J.W. Grant
Keyword(s):  
Relative Stability ◽  
Solubility Data ◽  
Heats Of Solution

The solubility of calcium carbonate  in green liquor handling systems

TAPPI Journal ◽  
2019 ◽  
Vol 18 (10) ◽  
pp. 595-602
Author(s):  
ALISHA GIGLIO ◽  
VLADIMIROS G. PAPANGELAKIS ◽  
HONGHI TRAN
Keyword(s):  
Calcium Carbonate ◽  
Systematic Study ◽  
Kraft Pulp ◽  
Thermodynamic Simulation ◽  
Solubility Data ◽  
Pulp Mills ◽  
Persistent Problem ◽  
Green Liquor ◽  
Kraft Pulp Mills ◽  
Salt Systems

The formation of hard calcite (CaCO3) scale in green liquor handling systems is a persistent problem in many kraft pulp mills. CaCO3 precipitates when its concentration in the green liquor exceeds its solubility. While the solubility of CaCO3 in water is well known, it is not so in the highly alkaline green liquor environment. A systematic study was conducted to determine the solubility of CaCO3 in green liquor as a function of temperature, total titratable alkali (TTA), causticity, and sulfidity. The results show that the solubility increases with increased temperature, increased TTA, decreased causticity, and decreased sulfidity. The new solubility data was incorporated into OLI (a thermodynamic simulation program for aqueous salt systems) to generate a series of CaCO3 solubility curves for various green liquor conditions. The results help explain how calcite scale forms in green liquor handling systems.

Equilibrium Studies of Binary and Ternary Complexes of Palladium(II) Involving Amino Acids

1993 ◽  
Vol 58 (5) ◽  
pp. 1103-1108 ◽  
Author(s):  
Mohamed M. Shoukry ◽  
Eman M. Shoukry
Keyword(s):  
Amino Acids ◽  
Relative Stability ◽  
Ternary Complex ◽  
Formation Constants ◽  
Ternary Complexes ◽  
Conductivity Measurements ◽  
Equilibrium Studies ◽  
Binary And Ternary Complexes ◽  
Binary Complexes

The formation constants of the binary and ternary complexes of palladium(II) with diethylenetriamine and amino acids as ligands have been determined potentiometrically at 25 °C in 0.1 M NaNO3 solution. The relative stability of each ternary complex was compared with that of the corresponding binary complexes in terms of ∆logK values. The mode of chelation was ascertained by conductivity measurements.

Heats of Solution of Some Sodium and Potassium Salts in Water and in Water-Methanol Mixtures

1992 ◽  
Vol 57 (11) ◽  
pp. 2227-2234 ◽  
Author(s):  
Ján Benko ◽  
Oľga Vollárová
Keyword(s):  
Transfer Functions ◽  
Enthalpies Of Solution ◽  
Potassium Salts ◽  
Solvent Interactions ◽  
Heats Of Solution ◽  
Solvent Molecules ◽  
Sodium And Potassium

The enthalpies of solution ∆Hs0 were determined for NaSCN, KSCN, NaBrO3, KBrO3, NaClO3, KClO3, NaIO4, KMnO4, KNO2 and NaNO2 in water-methanol mixtures. The transfer functions ∆Ht0 of the salts and anions were calculated based on the extrathermodynamic TPTB assumption. The ∆Ht0 values of the anion obtained from the sodium and potassium salts were compared. The differences observed, particularly at higher concentrations of the cosolvent, are discussed with respect to the interactions between the solvent molecules and the solute-solvent interactions.

The Molar Heats of Solution of Boric Oxide and Boric Acid1

1951 ◽  
Vol 73 (2) ◽  
pp. 579-581 ◽  
Author(s):  
Ervin R. Van Artsdalen ◽  
Keith P. Anderson
Keyword(s):  
Boric Oxide ◽  
Heats Of Solution

scholarly journals A Novel Index (RI) to Evaluate the Relative Stability of Soils Using Ultrasonic Agitation

2021 ◽  
Vol 13 (8) ◽  
pp. 4229
Author(s):  
Fakher Abbas ◽  
Fang Lin ◽  
Zhaolong Zhu ◽  
Shaoshan An
Keyword(s):  
Relative Stability ◽  
Characteristic Curve ◽  
Geometric Mean ◽  
Relative Strength ◽  
Soil Stability ◽  
Dispersion Energy ◽  
Ultrasonic Agitation ◽  
Mean Weight Diameter ◽  
Change In Mean ◽  
Wet Sieving

As soil stability is a complex phenomenon, various methods and indexes were introduced to assess the strength of soils. Because of the limitations of different stability methods and indexes (including wet sieving-based), we aimed to presents a relative stability index (RI) that was based on the estimated components of the soil overall disruptive characteristic curve (SODC): (1) soil disruption constant (Ki, that is based upon dispersion energy of soils); (2) resulting change in mean weight diameter (ΔMWD). To evaluate the effectiveness and limitations of RI as well as to compare it with classical soil stability indexes of mean weight diameter (MWD) and geometric mean diameter (GMD). Ultrasonic agitation (UA) along with a wet sieving method (followed by dry sieving) was applied against four different soils named on the basis of sample location, Qingling soil (QL), Guanzhong soil (GZ), Ansai soil (AS), and Jingbian soil (JB). To evaluate the relative strength of soils at different applied energies (increase in sonication duration usually resulted in increased input energy and temperature of soil–water suspension), soils were subjected to six sonication durations (0, 30, 60, 120, 210, and 300 s) with a fixed (and exact) initial amplitude and temperature. Output energy was calculated based on the amplitude and temperature of the suspension, vessel, and system. The most abrupt and maximum disruption of soil aggregates was observed at a dispersion energy level of 0–200 J g−1. The MWD value of surface and subsurface ranged between 0.58 to 0.15 mm and 0.37 to 0.17 mm, respectively, while GMD was ranged from 0.14 to 0.33 mm overall. The results for MWD and GMD showed a similar trend. MWD and GMD showed more strong associations with physicochemical characteristics of soil than RI. A non-significant correlation was found between RI and MWD/GMD. Contrary to MWD and GMD, RI was significantly positively correlated with sand content; this finding indicated the influential role of sand in assessing the soil’s relative strength. The results indicated that JB soil possessed the least MWD and GMD but proved to be relatively stable because of having the highest RI value.

A Convenient Protecting Group for Uridine Ureido Nitrogen: (4,4′-Bisfluorophenyl)methoxymethyl Group

Synthesis ◽  
2021 ◽  
Author(s):  
Michio Kurosu ◽  
Katsuhiko Mitachi ◽  
David Mingle
Keyword(s):  
Chemical Transformation ◽  
Relative Stability ◽  
Protecting Group

Abstract(4,4′-Bisfluorophenyl)methoxymethyl (BFPM) group of uridine ureido nitrogen shows good relative stability in a variety of chemical transformation reactions for uridine. The BFPM group can be cleaved by 2% of TFA in CH2Cl2 without affecting the Boc group.

scholarly journals Solubility Data of Potential Salts in the MgO-CaO-SO2-H2O-O2 System for Process Modeling

Processes ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 50
Author(s):  
Barbara D. Weiß ◽  
Michael Harasek
Keyword(s):  
Process Modeling ◽  
Ph Value ◽  
Process Models ◽  
Solubility Data ◽  
Solid Base ◽  
International Union ◽  
The Stability ◽  
Experimental Values ◽  
So2 Absorption ◽  
Reliable Basis

This review studies unwanted precipitation reactions, which can occur in SO2 absorption processes using a magnesium hydroxide slurry. Solubility data of potential salts in the MgO-CaO-SO2-H2O system are evaluated. The reviewed data can serve as a reliable basis for process modeling of this system used to support the optimization of the SO2 absorption process. This study includes the solubility data of MgSO3, MgSO4, Mg(OH)2, CaSO3, CaSO4, and Ca(OH)2 as potential salts. The solubility is strongly dependent on the state of the precipitated salts. Therefore, this review includes studies on the stability of different forms of the salts under different conditions. The solubility data in water over temperature serve as a base for modeling the precipitation in such system. Furthermore, influencing factors such as pH value, SO2 content and the co-existence of other salts are included and available data on such dependencies are reviewed. Literature data evaluated by the International Union of Pure and Applied Chemistry (IUPAC) are revisited and additional and newer studies are supplemented to obtain a solid base of accurate experimental values. For temperatures higher than 100 °C the available data are scarce. For a temperature range from 0 to 100 °C, the reviewed investigations and data provide a good base to evaluate and adapt process models for processes in order to map precipitations issues accurately.

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