An Efficient Route to Ethyl 5-Alkyl- (Aryl)-1H-1,2,4-triazole-3-carboxylates

2014 ◽  
Vol 52 (5) ◽  
pp. 1273-1277 ◽  
Author(s):  
M. V. Chudinov ◽  
A. V. Matveev ◽  
N. I. Zhurilo ◽  
A. N. Prutkov ◽  
V. I. Shvets
Keyword(s):  
Alkyl Aryl ◽  
Efficient Route

ChemInform Abstract: An Efficient Route to Ethyl 5-Alkyl- (Aryl)-1H-1,2,4-triazole-3-carboxylates.

ChemInform ◽  
2016 ◽  
Vol 47 (8) ◽  
pp. no-no
Author(s):  
M. V. Chudinov ◽  
A. V. Matveev ◽  
N. I. Zhurilo ◽  
A. N. Prutkov ◽  
V. I. Shvets
Keyword(s):  
Alkyl Aryl ◽  
Efficient Route

Hydroborations: A New Efficient Route to 1-Organo-2-indanones from 1-Alkyl(aryl)indenes

Synthesis ◽  
1990 ◽  
Vol 1990 (09) ◽  
pp. 815-816 ◽  
Author(s):  
B. S. Kirkiacharian ◽  
P. G. Koutsourakis
Keyword(s):  
Alkyl Aryl ◽  
Efficient Route

Stereoselective synthesis of E-3-(arylmethylidene)-5-(alkyl/aryl)-2(3H)-furanones by sequential hydroacyloxylation-Mizoroki–Heck reactions of iodoalkynes

2018 ◽  
Vol 16 (42) ◽  
pp. 7971-7983 ◽  
Author(s):  
Gopinathan Muthusamy ◽  
Sunil V. Pansare
Keyword(s):  
Heck Reaction ◽  
Stereoselective Synthesis ◽  
Heck Reactions ◽  
Cinnamic Acids ◽  
Alkyl Aryl ◽  
Efficient Route

Stereoselective hydroacyloxylation of iodoalkynes with β-aryl cinnamic acids and subsequent Mizoroki–Heck reaction provides an efficient route to substituted 2(3H)-furanones.

ChemInform Abstract: Hydroborations: A New Efficient Route to 1-Organo-2-indanones from 1- Alkyl(aryl)indenes.

ChemInform ◽  
2010 ◽  
Vol 22 (3) ◽  
pp. no-no
Author(s):  
B. S. KIRKIACHARIAN ◽  
P. G. KOUTSOURAKIS
Keyword(s):  
Alkyl Aryl ◽  
Efficient Route

Carbon Monoxide Related Reductions

INEOS OPEN ◽  
2020 ◽  
Vol 3 ◽  
Author(s):  
O. I. Afanasyev ◽  
◽  
D. Chusov ◽  
Keyword(s):  
Organic Chemistry ◽  
Carbon Monoxide ◽  
Reducing Agent ◽  
Current Development ◽  
Efficient Route ◽  
Development Prospects

Carbon monoxide is a unique reducing agent that is only gaining popularity in organic chemistry. This review highlights the main approaches to the application of CO as a reducing agent, summarizes and critically analyzes the key trends in this field, and describes the current development prospects. Potentially the most selective and efficient route for the realization of these processes is demonstrated.

Palladium Nanowire Thin Films via Template Growth

2003 ◽  
Vol 775 ◽  
Author(s):  
Donghai Wang ◽  
David T. Johnson ◽  
Byron F. McCaughey ◽  
J. Eric Hampsey ◽  
Jibao He ◽  
...  
Keyword(s):  
Thin Film ◽  
Electron Microscopy ◽  
Thin Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Conductive Substrate ◽  
Palladium Nanowires ◽  
Efficient Route ◽  
Silica Thin Film

AbstractPalladium nanowires have been electrodeposited into mesoporous silica thin film templates. Palladium continually grows and fills silica mesopores starting from a bottom conductive substrate, providing a ready and efficient route to fabricate a macroscopic palladium nanowire thin films for potentially use in fuel cells, electrodes, sensors, and other applications. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicate it is possible to create different nanowire morphology such as bundles and swirling mesostructure based on the template pore structure.

Metal-Metal Cooperative Bond Activation by Heterobimetallic Alkyl, Aryl, and Acetylide PtII/CuI Complexes

2020 ◽  
Author(s):  
Shubham Deolka ◽  
Orestes Rivada Wheelaghan ◽  
Sandra Aristizábal ◽  
Robert Fayzullin ◽  
Shrinwantu Pal ◽  
...  
Keyword(s):  
Alkyl Group ◽  
Bond Activation ◽  
Bond Cleavage ◽  
Terminal Alkyne ◽  
Alkyl Aryl ◽  
Metal Metal ◽  
The Stability ◽  
Selective Formation ◽  
Organoplatinum Compounds

We report selective formation of heterobimetallic PtII/CuI complexes that demonstrate how facile bond activation processes can be achieved by altering reactivity of common organoplatinum compounds through their interaction with another metal center. The interaction of the Cu center with Pt center and with a Pt-bound alkyl group increases the stability of PtMe2 towards undesired rollover cyclometalation. The presence of the CuI center also enables facile transmetalation from electron-deficient tetraarylborate [B(ArF)4]- anion and mild C-H bond cleavage of a terminal alkyne, which was not observed in the absence of an electrophilic Cu center. The DFT study indicates that the role of Cu center acts as a binding site for alkyne substrate, while activating its terminal C-H bond.

Thermodynamic Properties of Microemulsion Formed by Different Kinds of Alkyl Aryl Sulfonates

2012 ◽  
Vol 29 (11) ◽  
pp. 1309
Author(s):  
Tao YU ◽  
Shiqiong LUO ◽  
Wei DING ◽  
Huimin WANG ◽  
Guangmiao QU ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Alkyl Aryl

Efficient Route for Synthesis of Enamines from 1,3-Alkyl-2-Thioxodihydropyrimidine-4,6(1H,5H)-dione Enols

2019 ◽  
Vol 16 (7) ◽  
pp. 538-540
Author(s):  
Anamika Sharma ◽  
Zainab M. Almarhoon ◽  
Ayman El-Faham ◽  
Beatriz G. de la Torre ◽  
Fernando Albericio
Keyword(s):  
Ammonium Chloride ◽  
Thiobarbituric Acid ◽  
Acid Acid ◽  
Efficient Route ◽  
Harsh Conditions

Here we report a greener approach for the synthesis of enamines from enols of 1,3-alkyl-2- thioxodihydropyrimidine-4,6(1H,5H)-dione (thiobarbituric acid) acid using ammonium chloride and ethanol as solvents. This protocol removes the need for catalysts or harsh conditions.

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