Stereoselective synthesis of E-3-(arylmethylidene)-5-(alkyl/aryl)-2(3H)-furanones by sequential hydroacyloxylation-Mizoroki–Heck reactions of iodoalkynes

2018 ◽  
Vol 16 (42) ◽  
pp. 7971-7983 ◽  
Author(s):  
Gopinathan Muthusamy ◽  
Sunil V. Pansare
Keyword(s):  
Heck Reaction ◽  
Stereoselective Synthesis ◽  
Heck Reactions ◽  
Cinnamic Acids ◽  
Alkyl Aryl ◽  
Efficient Route

Stereoselective hydroacyloxylation of iodoalkynes with β-aryl cinnamic acids and subsequent Mizoroki–Heck reaction provides an efficient route to substituted 2(3H)-furanones.

Directed Ortho-Lithiation of Aminophosphazenes: An Efficient Route to the Stereoselective Synthesis of P-Chiral Compounds

2013 ◽  
Vol 15 (10) ◽  
pp. 2378-2381 ◽  
Author(s):  
María Casimiro ◽  
Laura Roces ◽  
Santiago García-Granda ◽  
María José Iglesias ◽  
Fernando López Ortiz
Keyword(s):  
Stereoselective Synthesis ◽  
Chiral Compounds ◽  
Efficient Route

Reductive Cross-Coupling of Vinyl Electrophiles

Synthesis ◽  
2020 ◽  
Vol 52 (24) ◽  
pp. 3751-3763 ◽  
Author(s):  
Xing-Zhong Shu ◽  
Xiaobo Pang ◽  
Xuejing Peng
Keyword(s):  
Transition Metal ◽  
Heck Reaction ◽  
Structural Complexity ◽  
Cross Coupling ◽  
Heck Reactions ◽  
Promising Tool ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The synthesis of alkenes (olefins) is a central subject in the synthetic community. The transition-metal-catalyzed reductive cross-coupling of vinyl electrophiles has emerged as a promising tool to produce alkenes with improved flexibility, structural complexity, and functionality tolerance. In this review, we summarized the progress in this field with respect to cross-electrophile couplings and reductive Heck reactions using vinyl electrophiles.1 Introduction2 Cross-Electrophile Coupling of Vinyl Electrophiles3 Reductive Heck Reaction of Vinyl Electrophiles4 Summary and Outlook

scholarly journals Efficient Route to 4a-Methyltetrahydrofluorenes: A Total Synthesis of (.+-.)-Dichroanal B via Intramolecular Heck Reaction.

ChemInform ◽  
2006 ◽  
Vol 37 (34) ◽  
Author(s):  
Loic Planas ◽  
Muneto Mogi ◽  
Hirofumi Takita ◽  
Tetsuya Kajimoto ◽  
Manabu Node
Keyword(s):  
Total Synthesis ◽  
Heck Reaction ◽  
Efficient Route ◽  
Intramolecular Heck Reaction

ChemInform Abstract: An Efficient Route to Ethyl 5-Alkyl- (Aryl)-1H-1,2,4-triazole-3-carboxylates.

ChemInform ◽  
2016 ◽  
Vol 47 (8) ◽  
pp. no-no
Author(s):  
M. V. Chudinov ◽  
A. V. Matveev ◽  
N. I. Zhurilo ◽  
A. N. Prutkov ◽  
V. I. Shvets
Keyword(s):  
Alkyl Aryl ◽  
Efficient Route
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