Quantum dynamics of vibration-vibration energy transfer for vibrationally excited HF colliding with H2

2018 ◽  
Vol 40 (10) ◽  
pp. 1084-1090 ◽  
Author(s):  
Dongzheng Yang ◽  
Xixi Hu ◽  
Daiqian Xie
1998 ◽  
Vol 16 (7) ◽  
pp. 838-846 ◽  
Author(s):  
A. S. Kirillov

Abstract. The first-order perturbation approximation is applied to calculate the rate coefficients of vibrational energy transfer in collisions involving vibrationally excited molecules in the absence of non-adiabatic transitions. The factors of molecular attraction, oscillator frequency change, anharmonicity, 3-dimensionality and quasiclassical motion have been taken into account in the approximation. The analytical expressions presented have been normalized on experimental data of VT-relaxation times in N2 and O2 to obtain the steric factors and the extent of repulsive exchange potentials in collisions N2-N2 and O2-O2. The approach was applied to calculate the rate coefficients of vibrational-vibrational energy transfer in the collisions N2-N2, O2-O2 and N2-O2. It is shown that there is good agreement between our calculations and experimental data for all cases of energy transfer considered.Key words. Ionosphere (Auroral ionosphere; ion chemistry and composition). Atmospheric composition and structure (Aciglow and aurora).


Author(s):  
Kazuhiko Adachi ◽  
Tatsuya Sakamoto

In the authors’ previous study, the vibration energy harvester of the piezoelectric bimorph cantilever type was proposed for vibration condition monitoring applications of industrial rotating machinery. According to an ISO standard, vibration level of newly commissioned class I rotating machinery is under 0.71mm/sec rms in all frequency range. Authors assumed that the typical casing or pedestal vibration amplitude of the rotating machinery was 0.71 mm/sec rms and this low intensity excitation condition was the input for experimental evaluation of the voltage generation performance of the piezocomposit vibration energy harvester. The vibration energy harvester consists of the surface bonded two Macro-Fiber Composites (MFCs). In this study, energy transfer efficiency was derived from the system energy balance during the natural period of the proposed vibration energy harvester. Energy balance equations were successfully obtained from the governing equations of the piezoelectrically coupled electromechanical system. The maximum AC power through 114.3 Kilo-Ohm resistor which includes instrument internal resistances experimentally obtained 242.07 microwatt when subjected to vibration source input magnitude of 0.71 mm/s rms at the resonant frequency of the harvester (29.42 Hz). The impedance matching between MFCs and the electrical resistive load was effective for maximizing AC power transfer of the vibration energy harvester. Estimated energy transfer from mechanical system to electrical system shows the agreement with the experimentally evaluated generating power during the natural period of the vibration energy harvester with about 3% difference. Estimated energy transfer efficiency was about 30% for different excitation magnitudes: 0.71, 0.568 and 0.355 mm/sec rms.


1972 ◽  
Vol 56 (11) ◽  
pp. 5214-5221 ◽  
Author(s):  
John C. Stephenson ◽  
Jack Finzi ◽  
C. Bradley Moore

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