Omnidirectional light‐harvesting enhancement of dye‐sensitized solar cells with ZnO nanorods

2019 ◽  
Vol 43 (8) ◽  
pp. 3413-3420 ◽  
Author(s):  
Fang‐I Lai ◽  
Jui‐Fu Yang ◽  
Yu‐Chao Hsu ◽  
Shou‐Yi Kuo
2011 ◽  
Vol 196 (4) ◽  
pp. 2416-2421 ◽  
Author(s):  
Kun-Mu Lee ◽  
Ying-Chan Hsu ◽  
Masashi Ikegami ◽  
Tsutomu Miyasaka ◽  
K.R. Justin Thomas ◽  
...  

2014 ◽  
Vol 67 (5) ◽  
pp. 819
Author(s):  
Syed Mujtaba Shah ◽  
Zafar Iqbal ◽  
Muzaffar Iqbal ◽  
Naila Shahzad ◽  
Amina Hana ◽  
...  

Porphyrin dyes have an inherent tendency to aggregate. This leads to a self-quenching phenomenon that hinders electron transfer to the conduction band of semiconductors in dye-sensitized solar cells. Self-quenching adversely affects the efficiency of solar cells. Here, we report the interaction of porphyrin with pristine and acid-functionalized fullerene molecules on the surface of ZnO nanoparticles under chemisorbed conditions. Chemisorption of porphyrin only on ZnO nanoparticles instigates aggregation of the porphyrin molecules. These aggregates can be effectively broken by chemisorbing fullerene molecules on the surface of the ZnO nanoparticles. This is due to self-assembly formation processes because of porphyrin–fullerene interactions. The nanohybrid material, consisting of ZnO nanorods, acid-functionalized porphyrin, and fullerene derivatives, was characterized by UV–visible spectroscopy, fourier transform infrared spectroscopy, fluorescence spectroscopy, and transmission electron microscopy. The material generates better performing dye-sensitized solar cells when compared with those fabricated from porphyrin-based photo-active material.


2018 ◽  
Vol 5 (2) ◽  
pp. 171054 ◽  
Author(s):  
J. Llanos ◽  
I. Brito ◽  
D. Espinoza ◽  
Ramkumar Sekar ◽  
P. Manidurai

Y 1.86 Eu 0.14 WO 6 phosphors were prepared using a solid-state reaction method. Their optical properties were analysed, and they was mixed with TiO 2 , sintered, and used as a photoelectrode (PE) in dye-sensitized solar cells (DSSCs). The as-prepared photoelectrode was characterized by photoluminescence spectroscopy, diffuse reflectance, electrochemical impedance spectroscopy (EIS) and X-ray diffraction. The photoelectric conversion efficiency of the DSSC with TiO 2 :Y 1.86 Eu 0.14 WO 6 (100:2.5) was 25.8% higher than that of a DSCC using pure TiO 2 as PE. This high efficiency is due to the ability of the luminescent material to convert ultraviolet radiation from the sun to visible radiation, thus improving the solar light harvesting of the DSSC.


RSC Advances ◽  
2020 ◽  
Vol 10 (46) ◽  
pp. 27615-27632 ◽  
Author(s):  
Marwa Ben Manaa ◽  
Noureddine Issaoui ◽  
Youssef O. Al-Ghamdi ◽  
Hafedh Belmabrouk ◽  
Abdelmottaleb Ben Lamine

Adsorption isotherms of N719 dye on (a) ZNP and (b) ZNR and the molecular electrostatic potential (MEP) map of (c) N719 dye and (d) ZnO.


2015 ◽  
Vol 44 (23) ◽  
pp. 8386-8398 ◽  
Author(s):  
Catherine E. Housecroft ◽  
Edwin C. Constable

The development of bis(diimine)copper(i) complexes as dyes in dye-sensitized solar cells is described. We assess the progress made in terms of light-harvesting and overall photoconversion efficiencies, and highlight areas that remain ripe for development and improvement, and the advantages of copper dyes over conventional ruthenium dyes.


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