Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes

2019 ◽  
Vol 2019 (28) ◽  
pp. 4613-4616 ◽  
Author(s):  
Kazuki Maeda ◽  
Takuya Kurahashi ◽  
Seijiro Matsubara
Keyword(s):  
Radical Reaction ◽  
Cobalt Complexes ◽  
Atom Transfer ◽  
Terminal Olefins ◽  
Type Radical

Iodine Atom-Transfer Ring-Opening of 1,1-Difluoro-2-(1-iodoalkyl)cyclopropanes by Free-Radical Reaction

1990 ◽  
Vol 19 (3) ◽  
pp. 467-468 ◽  
Author(s):  
Tsutomu Morikawa ◽  
Masayuki Uejima ◽  
Kazuaki Yoda ◽  
Takeo Taguchi
Keyword(s):  
Free Radical ◽  
Iodine Atom ◽  
Ring Opening ◽  
Radical Reaction ◽  
Atom Transfer ◽  
Free Radical Reaction

ChemInform Abstract: Intramolecular 1,5-Hydrogen Atom Transfer Radical Reaction of Pyrrolidine Derivatives.

ChemInform ◽  
2010 ◽  
Vol 30 (24) ◽  
pp. no-no
Author(s):  
Miyuki Ishizaki ◽  
Hideaki Takano ◽  
Osamu Hoshino
Keyword(s):  
Hydrogen Atom ◽  
Radical Reaction ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer

Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide

2016 ◽  
Vol 128 (49) ◽  
pp. 15549-15554 ◽  
Author(s):  
Thomas L. Gianetti ◽  
Rafael E. Rodríguez-Lugo ◽  
Jeffrey R. Harmer ◽  
Monica Trincado ◽  
Matthias Vogt ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Oxygen Atom ◽  
Cobalt Complexes ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Facile Covalent Attachment of Well-Defined Poly(t-butyl acrylate) on Carbon Nanotubes via Radical Addition Reaction

2008 ◽  
Vol 8 (9) ◽  
pp. 4598-4602 ◽  
Author(s):  
Saet Byeol Oh ◽  
Hye Lynn Kim ◽  
Jun Ho Chang ◽  
Yong-Won Lee ◽  
Jong Hun Han ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Raman Spectroscopy ◽  
Atom Transfer Radical Polymerization ◽  
Butyl Acrylate ◽  
Addition Reaction ◽  
Radical Reaction ◽  
Covalent Bonding ◽  
Radical Addition ◽  
Covalent Attachment ◽  
Atom Transfer

We developed a new method to covalently attach well-defined polymers onto carbon nanotubes (CNTs) using a radical reaction. Well-defined poly(t-butyl acrylate) [p(tBA)] was first prepared by atom transfer radical polymerization, which formed radicals at the end of the polymer chain through an atom transfer. The generated radicals at the chain ends added CNTs to generate covalently functionalized p(tBA)-grafted CNTs. The polymer-attached CNTs showed much improved solubility in organic solvents. The synthesized MWNT-g-p(tBA) and SWNT-g-p(tBA) were characterized by IR, TGA and Raman spectroscopy, clearly indicating the formation of covalent bonding between p(tBA) and CNTs.

Zero-Valent Amino-Olefin Cobalt Complexes as Catalysts for Oxygen Atom Transfer Reactions from Nitrous Oxide

2016 ◽  
Vol 55 (49) ◽  
pp. 15323-15328 ◽  
Author(s):  
Thomas L. Gianetti ◽  
Rafael E. Rodríguez-Lugo ◽  
Jeffrey R. Harmer ◽  
Monica Trincado ◽  
Matthias Vogt ◽  
...  
Keyword(s):  
Nitrous Oxide ◽  
Oxygen Atom ◽  
Cobalt Complexes ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions
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