Effects of Ionic Liquids on Pd-Catalysed Carbon–Carbon Bond Formation

2006 ◽  
Vol 2006 (17) ◽  
pp. 3791-3802 ◽  
Author(s):  
Vincenzo Calò ◽  
Angelo Nacci ◽  
Antonio Monopoli
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Regio- and Stereoselective Carbon—Carbon Bond Formation in Ionic Liquids

ChemInform ◽  
2005 ◽  
Vol 36 (1) ◽  
Author(s):  
Vincenzo Calo ◽  
Angelo Nacci ◽  
Antonio Monopoli
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Influence of Ionic Liquids on Pd-Catalyzed Carbon-Carbon Bond Formation

2001 ◽  
Vol 56 (9-10) ◽  
pp. 702-706 ◽  
Author(s):  
Vincenzo Calò ◽  
Angelo Nacci
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Tetrabutylammonium Bromide ◽  
Pd Catalyst ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Abstract Rates of Heck-type reactions, catalysed by a Pd-catalyst with benzothiazole carbene as ligands, are strongly influenced by tetrabutylammonium bromide utilized as solvent.

ChemInform Abstract: Sustainable Carbon-Carbon Bond Formation Catalyzed by New Oxamate-Containing Palladium(II) Complexes in Ionic Liquids.

ChemInform ◽  
2014 ◽  
Vol 45 (3) ◽  
pp. no-no
Author(s):  
Francisco Ramon Fortea-Perez ◽  
Isabel Schlegel ◽  
Miguel Julve ◽  
Donatella Armentano ◽  
Giovanni De Munno ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Effects of Ionic Liquids on Pd-Catalyzed Carbon—Carbon Bond Formation

ChemInform ◽  
2006 ◽  
Vol 37 (48) ◽  
Author(s):  
Vincenzo Calo ◽  
Angelo Nacci ◽  
Antonio Monopoli
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Basic Ionic Liquids: Facile Solvents for Carbon–Carbon Bond Formation Reactions and Ready Access to Palladium Nanoparticles

2007 ◽  
Vol 2007 (30) ◽  
pp. 5095-5100 ◽  
Author(s):  
Chengfeng Ye ◽  
Ji-Chang Xiao ◽  
Brendan Twamley ◽  
Aaron D. LaLonde ◽  
M. Grant Norton ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Ready Access ◽  
Bond Formation Reactions

Sustainable carbon–carbon bond formation catalyzed by new oxamate-containing palladium(II) complexes in ionic liquids

2013 ◽  
Vol 743 ◽  
pp. 102-108 ◽  
Author(s):  
Francisco Ramón Fortea-Pérez ◽  
Isabel Schlegel ◽  
Miguel Julve ◽  
Donatella Armentano ◽  
Giovanni De Munno ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Bond Formation ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Carbon Dioxide-Mediated C(sp2)–H Arylation of Primary and Secondary Benzylamines

2018 ◽  
Author(s):  
Mohit Kapoor ◽  
Pratibha Chand-Thakuri ◽  
Michael Young
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Carbon Bond ◽  
Chelate Effect ◽  
Free Amine ◽  
Carbon Carbon Bond ◽  
New Strategy ◽  
Metal Catalyzed

Carbon-carbon bond formation by transition metal-catalyzed C–H activation has become an important strategy to fabricate new bonds in a rapid fashion. Despite the pharmacological importance of <i>ortho</i>-arylbenzylamines, however, effective <i>ortho</i>-C–C bond formation from C–H bond activation of free primary and secondary benzylamines using Pd<sup>II</sup> remains an outstanding challenge. Presented herein is a new strategy for constructing <i>ortho</i>-arylated primary and secondary benzylamines mediated by carbon dioxide (CO<sub>2</sub>). The use of CO<sub>2</sub> is critical to allowing this transformation to proceed under milder conditions than previously reported, and that are necessary to furnish free amine products that can be directly used or elaborated without the need for deprotection. In cases where diarylation is possible, a chelate effect is demonstrated to facilitate selective monoarylation.

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