Effect of triacylglycerol species on the crystallizing behavior of a model water/oil emulsion

Author(s):  
Leo Tanaka ◽  
Tomoyuki Isogai ◽  
Susumu Miura ◽  
Mototake Murakami
2005 ◽  
Vol 2005 (1) ◽  
pp. 647-654
Author(s):  
Merv Fingas ◽  
Ben Fieldhouse

ABSTRACT Water-in-oil mixtures were grouped into four states or classes: stable, mesostable, unstable, and entrained water. Only stable and mesostable states can be characterized as emulsions. These states were established according to lifetime, visual appearance, complex modulus, and differences in viscosity. Water-in-oil emulsions made from crude oils have different classes of stability as a result of the asp haltene and resin contents, as well as differences in the viscosity of the starting oil. In this paper a new numerical modelling scheme is proposed and is based on empirical data and the corresponding physical knowledge of emulsion formation. The density, viscosity, saturate, asphaltene and resin contents are used to compute a class index which yields either an unstable or entrained water-in-oil state or a meso-stable or stable emulsion. A prediction scheme is given to estimate the water content and viscosity of the resulting water-in-oil state and the time to formation with input of wave-height.


Author(s):  
Stefiani Emasurya Indrajaya ◽  
◽  
Andreanus A. Soemardji ◽  
Siti Fara Rahmawati ◽  
◽  
...  
Keyword(s):  

2019 ◽  
Vol 23 (3) ◽  
pp. 746-754
Author(s):  
Dinar Dilshatovich Fazullin ◽  
Gennady Vitalievich Mavrin ◽  
Vladislav Olegovich Dryakhlov ◽  
Ildar Gilmanovich Shaikhiev ◽  
Irek Rashatovich Nizameyev

1987 ◽  
Vol 22 (3) ◽  
pp. 437-443 ◽  
Author(s):  
N. Kosaric ◽  
Z. Duvnjak

Abstract Aerobic sludge from a municipal activated sludge treatment plant, sludge from a conventional municipal anaerobic digester, aerobic sludge from an activated sludge process of a petroleum refinery, and granular sludge from an upflow sludge blanket reactor (USBR) were tested in the deemulsification of a water-in-oil emulsion. All sludges except the last one, showed a good deemulsification capability and could he used for a partial deemulsification of such emulsions. The rate and degree of the deemulsifications increased with an increase in sludge concentrations. The deemulsifications were faster at 85°C and required smaller amounts of sludge than in the case of the deemulsifications at room temperature. An extended stirring (up to a certain limit) in the course of the dispersion of sludge emulsion helped the deemulsification. Too vigorous agitation had an adverse effect. The deemulsification effect of sludge became less visible with an increase in the dilution of emulsion which caused an increase in its spontaneous deemulsification.


2012 ◽  
Vol 9 (1) ◽  
pp. 110-115
Author(s):  
L.A. Kovaleva ◽  
R.R. Zinnatullin ◽  
V.N. Blagochinnov ◽  
A.A. Musin ◽  
Yu.I. Fatkhullina ◽  
...  

Some results of experimental and numerical studies of the influence of radio-frequency (RF) and microwave (MW) electromagnetic (EM) fields on water-in-oil emulsions are presented. A detailed investigation of the dependence of the dielectric properties of emulsions on the frequency of the field makes it possible to establish the most effective frequency range of the EM influence. The results of water-in-oil emulsion stability in the RF EM field depending on their dielectric properties are presented. The effect of the MW EM field on the emulsion in a dynamic mode has been studied experimentally. In an attempt to understand the mechanism of emulsion destruction the mathematical model for a single emulsion droplet dynamics in radio-frequency (RF) and microwave (MW) electromagnetic fields is formulated.


Author(s):  
Abed Saad ◽  
Nour Abdurahman ◽  
Rosli Mohd Yunus

: In this study, the Sany-glass test was used to evaluate the performance of a new surfactant prepared from corn oil as a demulsifier for crude oil emulsions. Central composite design (CCD), based on the response surface methodology (RSM), was used to investigate the effect of four variables, including demulsifier dosage, water content, temperature, and pH, on the efficiency of water removal from the emulsion. As well, analysis of variance was applied to examine the precision of the CCD mathematical model. The results indicate that demulsifier dose and emulsion pH are two significant parameters determining demulsification. The maximum separation efficiency of 96% was attained at an alkaline pH and with 3500 ppm demulsifier. According to the RSM analysis, the optimal values for the input variables are 40% water content, 3500 ppm demulsifier, 60 °C, and pH 8.


2021 ◽  
Vol 167 ◽  
pp. 106900
Author(s):  
G. Sahasrabudhe ◽  
G. DeIuliis ◽  
J. Davy ◽  
K.P. Galvin

Sign in / Sign up

Export Citation Format

Share Document