scholarly journals Front Cover: Field-Induced Single-Ion-Magnetic Behavior of Octahedral CoII in a Two-Dimensional Coordination Polymer (Eur. J. Inorg. Chem. 22/2016)

2016 ◽  
Vol 2016 (22) ◽  
pp. 3524-3524
Author(s):  
Amit Kumar Mondal ◽  
Sajal Khatua ◽  
Kapil Tomar ◽  
Sanjit Konar
Keyword(s):  
Coordination Polymer ◽  
Magnetic Behavior ◽  
Two Dimensional ◽  
Front Cover

scholarly journals Field-Induced Single-Ion-Magnetic Behavior of Octahedral CoII in a Two-Dimensional Coordination Polymer

2016 ◽  
Vol 2016 (22) ◽  
pp. 3525-3525 ◽  
Author(s):  
Amit Kumar Mondal ◽  
Sajal Khatua ◽  
Kapil Tomar ◽  
Sanjit Konar
Keyword(s):  
Coordination Polymer ◽  
Magnetic Behavior ◽  
Two Dimensional

A Mn(II) Coordination Polymer with Sulfate and trans-1,2-Bis(4- pyridyl)ethylene Bridges: Synthesis, Structure, Magnetic and Ferroelectric Properties

2013 ◽  
Vol 68 (8) ◽  
pp. 877-884 ◽  
Author(s):  
Wei Xu ◽  
Jian-Li Lin
Keyword(s):  
Coordination Polymer ◽  
Remanent Polarization ◽  
Ferroelectric Properties ◽  
Magnetic Behavior ◽  
Title Complex ◽  
Spectroscopic Measurement ◽  
Antiferromagnetic Coupling ◽  
Monoclinic Space Group ◽  
Two Dimensional ◽  
Ir Spectroscopic

Reaction of MnSO4 and trans-1,2-bis(4-pyridyl)ethene (bpe) results in a new coordination polymer, [Mn(H2O)2(bpe)(SO4)]·H2O. The title complex crystallizes in the polar monoclinic space group C2. The octahedrally coordinated Mn atoms are bridged by sulfate anions and bpe ligands to form two-dimensional sheets with (42·63·8) topology. This polar complex displays ferroelectricity with a remanent polarization (2Pr) of ca. 0:5779 μC cm-2, a coercive field (2Ec) of 8:8 kV cm-1, and a saturation of the spontaneous polarization (PS) of ca. 0:4177 μC cm-2. The magnetic behavior of the title complex suggests significant antiferromagnetic coupling interactions between Mn(II) ions bridged by sulfate anions. Furthermore, the title complex was subjected to elemental analysis, IR spectroscopic measurement and thermal analysis.

Field-Induced Single-Ion-Magnetic Behavior of Octahedral CoIIin a Two-Dimensional Coordination Polymer

2016 ◽  
Vol 2016 (22) ◽  
pp. 3545-3552 ◽  
Author(s):  
Amit Kumar Mondal ◽  
Sajal Khatua ◽  
Kapil Tomar ◽  
Sanjit Konar
Keyword(s):  
Coordination Polymer ◽  
Magnetic Behavior ◽  
Two Dimensional

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

scholarly journals Crystal structure of two-dimensional coordination polymer poly-[μ2-azido-aqua-(μ2-pyrazine-2-carboxylato-κ3O,N:N′)nickel(II)], C5H5N5O3Ni

2016 ◽  
Vol 231 (4) ◽  
pp. 1163-1164
Author(s):  
Yu Youzhu ◽  
Guo Yuhua ◽  
Yang Liguo ◽  
Niu Yongsheng
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Two Dimensional

AbstractC5H5N5O3Ni, monoclinic, C2/c (no. 15), a = 8.5804(17) Å, b = 13.790(3) Å, c = 13.969(3) Å, β = 104.37(3)°, V =1601.2(6)Å3, Z = 8, Rgt(F) = 0.0203, wRref(F2) = 0.0550, T = 293 K.

Hydrothermal synthesis, structure and magnetic properties of a three-dimensional cobalt(ii) – aminophenyltetrazolate coordination polymer

2014 ◽  
Vol 43 (19) ◽  
pp. 7263-7268 ◽  
Author(s):  
Tiffany M. Smith ◽  
Michael Tichenor ◽  
Yuan-Zhu Zhang ◽  
Kim R. Dunbar ◽  
Jon Zubieta
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Hydrothermal Synthesis ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Magnetic Behavior ◽  
Ac Magnetic Susceptibility

The three-dimensional [Co3(OH)2(H2O)2(aptet)4] exhibits magnetic properties consistent with a ferrimagnetic chain with the non-compensating resultant moment of one Co(ii) per trinuclear Co(ii) subunit and ac magnetic susceptibility indicative of glassy-like magnetic behavior.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

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