A New Building Block for Organometallic-Inorganic Hybrid Polymers: The Mixed Group 15/16 Element Ligand Complex [Cp*2Mo2(μ,η2:2-PSe)2(μ-Se)] (Cp* = C5Me5)

2010 ◽  
Vol 2010 (33) ◽  
pp. 5298-5303 ◽  
Author(s):  
Michael Bodensteiner ◽  
Michal Dušek ◽  
Marek M. Kubicki ◽  
Michael Pronold ◽  
Manfred Scheer ◽  
...  
Keyword(s):  
Building Block ◽  
Mixed Group ◽  
Ligand Complex ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Group 15

An Unusual Building Block for Supramolecular Aggregates: The Mixed Group 15/16 Element Ligand Complex [(Cp*Mo)2(μ,η3-P3)(μ,η2-PS)]

2007 ◽  
Vol 46 (31) ◽  
pp. 5966-5970 ◽  
Author(s):  
Laurence J. Gregoriades ◽  
Gábor Balázs ◽  
Eike Brunner ◽  
Christian Gröger ◽  
Joachim Wachter ◽  
...  
Keyword(s):  
Building Block ◽  
Mixed Group ◽  
Ligand Complex ◽  
Group 15 ◽  
Supramolecular Aggregates

scholarly journals Lewis pairing and frustration of group 13/15 elements geometrically enforced by (ace)naphthalene, biphenylene and (thio)xanthene backbones

2021 ◽  
Author(s):  
Omar Sadek ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Mixed Group ◽  
Group 13 ◽  
Group 15

The synthesis, structure, and reactivity of mixed group 13/group 15 compounds (E13 = B, Al, Ga, In, Tl; E15 = N, P, Sb, Bi) featuring a rigid (ace)naphthalene, biphenylene or (thio)xanthene backbone are discussed in this review.

Synthesis of Photosensitive Organic-Inorganic Hybrid Polymers via Anhydrous Sol-Gel Process for Integrated Optics

2003 ◽  
Vol 780 ◽  
Author(s):  
Xinshi Luo ◽  
Congji Zha ◽  
Barry Luther-Davies
Keyword(s):  
Low Cost ◽  
Sol Gel ◽  
Optical Loss ◽  
Hybrid Polymer ◽  
Optical Losses ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Wide Range ◽  
Integrated Optical ◽  
Sol Gel Process

AbstractPhotosensitive organic-inorganic hybrid polymers were synthesised for integrated optical and optoelectronic devices by a non-hydrous sol-gel process of hydrolysis/condensation of 3-methacryloxypropyltrimethoxysilane (MPS), diphenyldimethoxysilane (DPhDMS), and zirconium isopropoxide (TPZ) with boric acid under anhydrous conditions. The methacryl groups of MPS are UVpolymerizable, which are suitable for low cost fabrication of waveguides with a “UV write/develop” process. The incorporation of DPhDMS and TPZ was found useful in reducing the optical loss and in enhancing the thermostability of the polymer. The refractive index of the hybrid polymer is tuneable from 1.4950 to 1.5360 by variation of the ratio among MPS, DPhDMS and TPZ. Optical characterisation showed that the material has low optical losses at the telecommunications windows (0.16 dB/cm at 1310 nm and 0.4 dB/cm at 1550nm). The hybrid polymer also showed a low birefringence (1.2×10-4), a large thermo-optic (TO) coefficient (-2.77 ×10-4), and an outstanding linearity of dn/dT in a wide range of temperature (from 25 °C to 200 °C). Waveguides forming ability for the hybrid polymer with UV imprinting was also demonstrated.

Organic-Inorganic Hybrid Polymers from Atom Transfer Radical Polymerization and Poly(dimethylsiloxane)

2000 ◽  
pp. 270-283 ◽  
Author(s):  
Krzysztof Matyjaszewski ◽  
Peter J. Miller ◽  
Guido Kickelbick ◽  
Yoshiki Nakagawa ◽  
Steven Diamanti ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Hybrid Polymers ◽  
Inorganic Hybrid

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

2016 ◽  
Vol 52 (93) ◽  
pp. 13616-13619 ◽  
Author(s):  
Wen-Ming Wan ◽  
Andrew W. Baggett ◽  
Fei Cheng ◽  
Huina Lin ◽  
Shih-Yuan Liu ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Hybrid Polymers ◽  
Inorganic Hybrid ◽  
Materials Properties

Free radical polymerization of B-vinyl- and B-styryl-functionalized azaborinine monomers gives organic–inorganic hybrid polymers with distinctly different materials properties compared to the corresponding carbonaceous polystyrene derivatives.

scholarly journals Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

2018 ◽  
Vol 47 (4) ◽  
pp. 1014-1017 ◽  
Author(s):  
M. Elsayed Moussa ◽  
B. Attenberger ◽  
E. V. Peresypkina ◽  
M. Scheer
Keyword(s):  
Hybrid Networks ◽  
Two Dimensional ◽  
Ligand Complex ◽  
Hybrid Polymers ◽  
Organic Hybrid

The reaction of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic–organic hybrid networks.

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