scholarly journals Mechanistic Insights into Electrocatalytic Nitrogen Reduction Reaction on the Pd‐W Heteronuclear Diatom Supported on C 2 N Monolayer: Role of H Pre‐Adsorption

2022 ◽  
Author(s):  
Zeyun Zhang ◽  
Xuefei Xu
Keyword(s):  
Reduction Reaction ◽  
Nitrogen Reduction

scholarly journals The Role of Structured Carbon in Downsized Transition Metal-Based Electrocatalysts toward a Green Nitrogen Fixation

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1529
Author(s):  
Marcello Ferrara ◽  
Michele Melchionna ◽  
Paolo Fornasiero ◽  
Manuela Bevilacqua
Keyword(s):  
Nitrogen Fixation ◽  
Catalytic Activity ◽  
Heterogeneous Catalysis ◽  
Transition Metal ◽  
Reduction Reaction ◽  
Metal Species ◽  
Nanostructured Carbon ◽  
Nitrogen Reduction ◽  
Recent Trends

Electrocatalytic Nitrogen Reduction Reaction (NRR) to ammonia is one of the most recent trends of research in heterogeneous catalysis for sustainability. The stark challenges posed by the NRR arise from many factors, beyond the strongly unfavored thermodynamics. The design of efficient heterogeneous electrocatalysts must rely on a suitable interplay of different components, so that the majority of research is focusing on development of nanohybrids or nanocomposites that synergistically harness the NRR sequence. Nanostructured carbon is one of the most versatile and powerful conductive supports that can be combined with metal species in an opportune manner, so as to guide the correct proceeding of the reaction and boost the catalytic activity.

The Role of Defects in Metal–Organic Frameworks for Nitrogen Reduction Reaction: When Defects Switch to Features

2021 ◽  
Vol 31 (17) ◽  
pp. 2010052
Author(s):  
Islam E. Khalil ◽  
Cong Xue ◽  
Wenjing Liu ◽  
Xiaohan Li ◽  
Yu Shen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Metal Organic

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

Boosting electrochemical nitrogen reduction reaction performance of two-dimensional Mo porphyrin monolayers via turning the coordination environment

2021 ◽  
Vol 23 (7) ◽  
pp. 4178-4186
Author(s):  
Shiqiang Liu ◽  
Zhiwen Cheng ◽  
Yawei Liu ◽  
Xiaoping Gao ◽  
Yujia Tan ◽  
...  
Keyword(s):  
Energy Conversion ◽  
Reduction Reaction ◽  
Metal Catalysts ◽  
Two Dimensional ◽  
Coordination Environment ◽  
Nitrogen Reduction ◽  
Reaction Performance ◽  
Conversion Efficiencies

Designing atomically dispersed metal catalysts for the nitrogen reduction reaction (NRR) is an effective approach to achieve better energy conversion efficiencies.

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