Synthesis of Dual‐Responsive Materials with Reversible and Switchable Phase‐Transition Properties for High‐Performance Cellulose Enzymatic Hydrolysis

ChemSusChem ◽  
2019 ◽  
Vol 13 (4) ◽  
pp. 663-667 ◽  
Author(s):  
Xing Zhu ◽  
Yi Tian ◽  
Bin He ◽  
Ting Gan ◽  
Xiao Hu ◽  
...  
Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 327
Author(s):  
Morwenna J. Spear ◽  
Simon F. Curling ◽  
Athanasios Dimitriou ◽  
Graham A. Ormondroyd

Wood modification is now widely recognized as offering enhanced properties of wood and overcoming issues such as dimensional instability and biodegradability which affect natural wood. Typical wood modification systems use chemical modification, impregnation modification or thermal modification, and these vary in the properties achieved. As control and understanding of the wood modification systems has progressed, further opportunities have arisen to add extra functionalities to the modified wood. These include UV stabilisation, fire retardancy, or enhanced suitability for paints and coatings. Thus, wood may become a multi-functional material through a series of modifications, treatments or reactions, to create a high-performance material with previously impossible properties. In this paper we review systems that combine the well-established wood modification procedures with secondary techniques or modifications to deliver emerging technologies with multi-functionality. The new applications targeted using this additional functionality are diverse and range from increased electrical conductivity, creation of sensors or responsive materials, improvement of wellbeing in the built environment, and enhanced fire and flame protection. We identified two parallel and connected themes: (1) the functionalisation of modified timber and (2) the modification of timber to provide (multi)-functionality. A wide range of nanotechnology concepts have been harnessed by this new generation of wood modifications and wood treatments. As this field is rapidly expanding, we also include within the review trends from current research in order to gauge the state of the art, and likely direction of travel of the industry.


Nanoscale ◽  
2016 ◽  
Vol 8 (19) ◽  
pp. 10316-10322 ◽  
Author(s):  
Tao Lu ◽  
Shenmin Zhu ◽  
Zhixin Chen ◽  
Wanlin Wang ◽  
Wang Zhang ◽  
...  

2017 ◽  
Vol 29 (19) ◽  
pp. 1700210 ◽  
Author(s):  
Peng-Fei Wang ◽  
Hu-Rong Yao ◽  
Xin-Yu Liu ◽  
Jie-Nan Zhang ◽  
Lin Gu ◽  
...  

2020 ◽  
Vol 10 (11) ◽  
pp. 3764
Author(s):  
Vera D. Costa ◽  
Ana Costa ◽  
Maria Amaral ◽  
Rogério S. Simões

The effect of different acid sulfite pretreatment conditions on released components in the hydrolysates and the pretreated solid residues’ response to enzymatic hydrolysis for Eucalyptus globulus chips was investigated. Sodium bisulfite (0–15%), and sulfuric acid (0–5%) were used to pretreat chips at 170 °C and 190 °C, for as long as 30 min. The hydrolysates were analyzed through high-performance liquid chromatography (HPLC) and spectrophotometry. Overall porosity and pores larger than 2.65 nm (size of a typical cellulase) on the solid residues were estimated using glucose and two dextrans with different hydrodynamic radii as probes. The external specific surface area was analyzed by dynamic light scattering. The solid residues underwent enzymatic hydrolysis with an enzymatic cocktail. Very high (84–95%) carbohydrate conversion was achieved for either an extensively delignified biomass or a biomass with very high content of sulfonated residual lignin (23.4%), since internal porosity enables enzymes accessibility. At least 5% sodium bisulfite and 1% sulfuric acid was required to attain a carbohydrate release above 90% in the enzymatic hydrolysis. Results suggest that the presence of sulfonated lignin does not impair the enzymatic hydrolysis rate and extent. The increase of pretreatment temperature had a positive effect mainly on the initial rate of carbohydrates release in the enzymatic hydrolysis. The increase of the wood material dimensions from pins to conventional chips significantly decreased the hemicellulose removal in acid sulfite pretreatment but had a small effect on the enzymatic yield.


2020 ◽  
Vol 8 (36) ◽  
pp. 18880-18890 ◽  
Author(s):  
Ady Suwardi ◽  
Jing Cao ◽  
Lei Hu ◽  
Fengxia Wei ◽  
Jing Wu ◽  
...  

The rhombohedral–cubic phase transition temperature of GeTe can be tailored via Sn-alloying, leading to high performance thermoelectric GeTe.


2020 ◽  
pp. 2005362
Author(s):  
Jinhyup Han ◽  
Jehee Park ◽  
Seong‐Min Bak ◽  
Seoung‐Bum Son ◽  
Jihyeon Gim ◽  
...  

2018 ◽  
Vol 259 ◽  
pp. 170-178 ◽  
Author(s):  
Jianwu Hao ◽  
Jian Mou ◽  
Jingwen Zhang ◽  
Liubing Dong ◽  
Wenbao Liu ◽  
...  

ChemSusChem ◽  
2012 ◽  
Vol 5 (10) ◽  
pp. 2023-2031 ◽  
Author(s):  
Shanshan Jiang ◽  
Wei Zhou ◽  
Yingjie Niu ◽  
Zhonghua Zhu ◽  
Zongping Shao

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