Electrochemically induced spinel-layered phase transition of Mn3O4 in high performance neutral aqueous rechargeable zinc battery

2018 ◽  
Vol 259 ◽  
pp. 170-178 ◽  
Author(s):  
Jianwu Hao ◽  
Jian Mou ◽  
Jingwen Zhang ◽  
Liubing Dong ◽  
Wenbao Liu ◽  
...  
2017 ◽  
Vol 29 (19) ◽  
pp. 1700210 ◽  
Author(s):  
Peng-Fei Wang ◽  
Hu-Rong Yao ◽  
Xin-Yu Liu ◽  
Jie-Nan Zhang ◽  
Lin Gu ◽  
...  

2020 ◽  
Vol 8 (36) ◽  
pp. 18880-18890 ◽  
Author(s):  
Ady Suwardi ◽  
Jing Cao ◽  
Lei Hu ◽  
Fengxia Wei ◽  
Jing Wu ◽  
...  

The rhombohedral–cubic phase transition temperature of GeTe can be tailored via Sn-alloying, leading to high performance thermoelectric GeTe.


2020 ◽  
pp. 2005362
Author(s):  
Jinhyup Han ◽  
Jehee Park ◽  
Seong‐Min Bak ◽  
Seoung‐Bum Son ◽  
Jihyeon Gim ◽  
...  

ChemSusChem ◽  
2012 ◽  
Vol 5 (10) ◽  
pp. 2023-2031 ◽  
Author(s):  
Shanshan Jiang ◽  
Wei Zhou ◽  
Yingjie Niu ◽  
Zhonghua Zhu ◽  
Zongping Shao

2018 ◽  
Vol 115 (21) ◽  
pp. 5332-5337 ◽  
Author(s):  
Zihang Liu ◽  
Jifeng Sun ◽  
Jun Mao ◽  
Hangtian Zhu ◽  
Wuyang Ren ◽  
...  

Germanium telluride (GeTe)-based materials, which display intriguing functionalities, have been intensively studied from both fundamental and technological perspectives. As a thermoelectric material, though, the phase transition in GeTe from a rhombohedral structure to a cubic structure at ∼700 K is a major obstacle impeding applications for energy harvesting. In this work, we discovered that the phase-transition temperature can be suppressed to below 300 K by a simple Bi and Mn codoping, resulting in the high performance of cubic GeTe from 300 to 773 K. Bi doping on the Ge site was found to reduce the hole concentration and thus to enhance the thermoelectric properties. Mn alloying on the Ge site simultaneously increased the hole effective mass and the Seebeck coefficient through modification of the valence bands. With the Bi and Mn codoping, the lattice thermal conductivity was also largely reduced due to the strong point-defect scattering for phonons, resulting in a peak thermoelectric figure of merit (ZT) of ∼1.5 at 773 K and an average ZT of ∼1.1 from 300 to 773 K in cubic Ge0.81Mn0.15Bi0.04Te. Our results open the door for further studies of this exciting material for thermoelectric and other applications.


2019 ◽  
Vol 11 (16) ◽  
pp. 14848-14853 ◽  
Author(s):  
Kezhu Jiang ◽  
Xueping Zhang ◽  
Haoyu Li ◽  
Xiaoyu Zhang ◽  
Ping He ◽  
...  

2020 ◽  
Vol 5 (41) ◽  
pp. eaaz4239 ◽  
Author(s):  
Seyed M. Mirvakili ◽  
Douglas Sim ◽  
Ian W. Hunter ◽  
Robert Langer

Pneumatic artificial muscles have been widely used in industry because of their simple and relatively high-performance design. The emerging field of soft robotics has also been using pneumatic actuation mechanisms since its formation. However, these actuators/soft robots often require bulky peripheral components to operate. Here, we report a simple mechanism and design for actuating pneumatic artificial muscles and soft robotic grippers without the use of compressors, valves, or pressurized gas tanks. The actuation mechanism involves a magnetically induced liquid-to-gas phase transition of a liquid that assists the formation of pressure inside the artificial muscle. The volumetric expansion in the liquid-to-gas phase transition develops sufficient pressure inside the muscle for mechanical operations. We integrated this actuation mechanism into a McKibben-type artificial muscle and soft robotic arms. The untethered McKibben artificial muscle generated actuation strains of up to 20% (in 10 seconds) with associated work density of 40 kilojoules/meter3, which favorably compares with the peak strain and peak energy density of skeletal muscle. The untethered soft robotic arms demonstrated lifting objects with an input energy supply from only two Li-ion batteries.


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