Highly Efficient Gas-Phase Oxidation of Renewable Furfural to Maleic Anhydride over Plate Vanadium Phosphorus Oxide Catalyst

ChemSusChem ◽  
2018 ◽  
Vol 11 (3) ◽  
pp. 612-618 ◽  
Author(s):  
Xiukai Li ◽  
Jogie Ko ◽  
Yugen Zhang
2017 ◽  
Vol 348 ◽  
pp. 265-275 ◽  
Author(s):  
N. Alonso-Fagúndez ◽  
M. Ojeda ◽  
R. Mariscal ◽  
J.L.G. Fierro ◽  
M. López Granados

2002 ◽  
Vol 208 (1) ◽  
pp. 238-246 ◽  
Author(s):  
Andréa M. Duarte de Farias ◽  
Wilma de A. Gonzalez ◽  
Paulo G. Pries de Oliveira ◽  
Jean-Guillaume Eon ◽  
Jean-Marie Herrmann ◽  
...  

1993 ◽  
Vol 58 (12) ◽  
pp. 2867-2874
Author(s):  
Jaroslav Machek ◽  
Josef Tichý ◽  
Jiří Švachula

The catalytic gas-phase oxidation of isobutene has been studied on polycomponent Mo-Co-Ni-Bi-Fe-K oxide catalyst suitable for industrial preparation of propenal from propene. It has been found that within the temperature interval 290 - 350 °C the main oxidation products are 2-methylpropenal, acetone, 2-methylpropenoic acid, acetic acid and carbon dioxide. A modification of the mentioned catalyst by addition of a further component (W, P, Te, and Zn) showed that zinc increases the conversion of isobutene and at the same time markedly increases its selectivity for 2-methylpropenal, whereas the additions of tungsten and phosphorus decrease the conversion of isobutene with simultaneous increase of selectivity for CO2. If tert-butyl alcohol is used as the starting material instead of isobutene, then the extent of reaction is slightly decreased with simultaneous increase of selectivity for 2-methylpropenal, whereas the selectivities for the acids remain almost unchanged.


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