Passivation Layer and Cathodic Redox Reactions in Sodium-Ion Batteries Probed by HAXPES

ChemSusChem ◽  
2015 ◽  
Vol 9 (1) ◽  
pp. 97-108 ◽  
Author(s):  
Siham Doubaji ◽  
Bertrand Philippe ◽  
Ismael Saadoune ◽  
Mihaela Gorgoi ◽  
Torbjorn Gustafsson ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Passivation Layer ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Rational Design of Ti-Based Oxygen Redox Layered Oxides for Advanced Sodium-ion Batteries

2021 ◽  
Author(s):  
Jaewoon Lee ◽  
Sojung Koo ◽  
Jinwoo Lee ◽  
Duho Kim
Keyword(s):  
Transition Metals ◽  
Redox Reactions ◽  
Rational Design ◽  
Alkali Metals ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Layered Oxides

Considering Mn4+ (3d3)-based cations, various layered oxides (A[AyM1-y]O2, where A and M refer to alkali metals and transition metals, respectively) exhibiting oxygen-redox reactions have been investigated extensively to achieve high...

Realizing Three-Electron Redox Reactions in NASICON-Structured Na3 MnTi(PO4 )3 for Sodium-Ion Batteries

2019 ◽  
Vol 9 (9) ◽  
pp. 1803436 ◽  
Author(s):  
Ting Zhu ◽  
Ping Hu ◽  
Xuanpeng Wang ◽  
Zhenhui Liu ◽  
Wen Luo ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Sodium Ion ◽  
Sodium Ion Batteries

Rational design of Na(Li1/3Mn1/2Cr1/6)O2 exhibiting cation–anion-coupled redox reactions with superior electrochemical, thermodynamic, atomic, and chemomechanical properties for advanced sodium-ion batteries

2018 ◽  
Vol 6 (37) ◽  
pp. 18036-18043 ◽  
Author(s):  
Duho Kim ◽  
Maenghyo Cho ◽  
Kyeongjae Cho
Keyword(s):  
Energy Density ◽  
Redox Reactions ◽  
Rational Design ◽  
High Energy ◽  
Sodium Ion ◽  
High Energy Density ◽  
Sodium Ion Batteries

Based on a cation–anion-coupled redox paradigm, Na(Li1/3Mn1/2Cr1/6)O2 is systematically designed to use rational anion redox reactions (O2−/O−) for high energy density cathodes in sodium-ion batteries.

Prussian blue without coordinated water as a superior cathode for sodium-ion batteries

2015 ◽  
Vol 51 (38) ◽  
pp. 8181-8184 ◽  
Author(s):  
Dezhi Yang ◽  
Jing Xu ◽  
Xiao-Zhen Liao ◽  
Hong Wang ◽  
Yu-Shi He ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Redox Reactions ◽  
Sodium Ion ◽  
Electrochemical Performances ◽  
Sodium Ion Batteries ◽  
Coordinated Water

Prussian blue without coordinated water delivered super-high electrochemical performances with sufficient redox reactions when employed as a cathode in sodium ion batteries.

Atomic insight into the structural transformation and anionic/cationic redox reactions of VS2 nanosheets in sodium-ion batteries

2018 ◽  
Vol 6 (33) ◽  
pp. 15985-15992 ◽  
Author(s):  
Dashuai Wang ◽  
Yingying Zhao ◽  
Ruqian Lian ◽  
Di Yang ◽  
Dong Zhang ◽  
...  
Keyword(s):  
First Principles ◽  
Redox Reactions ◽  
Experimental Testing ◽  
Sodium Ion ◽  
Transfer Reactions ◽  
Sodium Ion Batteries ◽  
First Principles Calculations ◽  
Diffusion Kinetics ◽  
Charge Transfer Reactions ◽  
Insight Into

The mechanisms for phase transitions, charge-transfer reactions, and ionic diffusion kinetics during Na+ insertion in VS2 nanosheets were systematically investigated via experimental testing and first principles calculations.

Low-valence titanium oxides synthesized by electric field control as novel conversion anodes for high performance sodium-ion batteries

2021 ◽  
Vol 9 (16) ◽  
pp. 10458-10465
Author(s):  
Hongwei Tao ◽  
Ruxing Wang ◽  
Yun Tang ◽  
Min Zhou ◽  
Kangli Wang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Redox Reactions ◽  
High Performance ◽  
Control Method ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Titanium Oxides ◽  
Fast Charge ◽  
Field Control

The low-valence titanium oxides (TiO, Ti2O) were synthesized by electric field control method. The multi-electron redox reactions and fast charge transfer kinetics result in the excellent Na storage performances of low-valence titanium oxides.

scholarly journals Recent Advances in Electrode Materials with Anion Redox Chemistry for Sodium-Ion Batteries

2021 ◽  
Vol 2021 ◽  
pp. 1-22
Author(s):  
Natalia Voronina ◽  
Seung-Taek Myung
Keyword(s):  
Redox Reactions ◽  
Electrode Materials ◽  
State Of The Art ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Future Research ◽  
Sodium Ion Batteries ◽  
Layered Oxides ◽  
Activity Structure ◽  
New Strategies

The development of sodium-ion batteries (SIBs), which are promising alternatives to lithium-ion batteries (LIBs), offers new opportunities to address the depletion of Li and Co resources; however, their implementation is hindered by their relatively low capacities and moderate operation voltages and resulting low energy densities. To overcome these limitations, considerable attention has been focused on anionic redox reactions, which proceed at high voltages with extra capacity. This manuscript covers the origin and recent development of anionic redox electrode materials for SIBs, including state-of-the-art P2- and O3-type layered oxides. We sequentially analyze the anion activity–structure–performance relationship in electrode materials. Finally, we discuss remaining challenges and suggest new strategies for future research in anion-redox cathode materials for SIBs.

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