scholarly journals Recent Advances in Electrode Materials with Anion Redox Chemistry for Sodium-Ion Batteries

2021 ◽  
Vol 2021 ◽  
pp. 1-22
Author(s):  
Natalia Voronina ◽  
Seung-Taek Myung
Keyword(s):  
Redox Reactions ◽  
Electrode Materials ◽  
State Of The Art ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Future Research ◽  
Sodium Ion Batteries ◽  
Layered Oxides ◽  
Activity Structure ◽  
New Strategies

The development of sodium-ion batteries (SIBs), which are promising alternatives to lithium-ion batteries (LIBs), offers new opportunities to address the depletion of Li and Co resources; however, their implementation is hindered by their relatively low capacities and moderate operation voltages and resulting low energy densities. To overcome these limitations, considerable attention has been focused on anionic redox reactions, which proceed at high voltages with extra capacity. This manuscript covers the origin and recent development of anionic redox electrode materials for SIBs, including state-of-the-art P2- and O3-type layered oxides. We sequentially analyze the anion activity–structure–performance relationship in electrode materials. Finally, we discuss remaining challenges and suggest new strategies for future research in anion-redox cathode materials for SIBs.

scholarly journals Electrode Materials for High-Performance Sodium-Ion Batteries

Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 1952 ◽  
Author(s):  
Santanu Mukherjee ◽  
Shakir Bin Mujib ◽  
Davi Soares ◽  
Gurpreet Singh
Keyword(s):  
High Performance ◽  
Large Scale ◽  
Electrode Materials ◽  
State Of The Art ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Cycle Life ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Grid Storage

Sodium ion batteries (SIBs) are being billed as an economical and environmental alternative to lithium ion batteries (LIBs), especially for medium and large-scale stationery and grid storage. However, SIBs suffer from lower capacities, energy density and cycle life performance. Therefore, in order to be more efficient and feasible, novel high-performance electrodes for SIBs need to be developed and researched. This review aims to provide an exhaustive discussion about the state-of-the-art in novel high-performance anodes and cathodes being currently analyzed, and the variety of advantages they demonstrate in various critically important parameters, such as electronic conductivity, structural stability, cycle life, and reversibility.

scholarly journals State-of-the-Art Electrode Materials for Sodium-Ion Batteries

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3453 ◽  
Author(s):  
Alain Mauger ◽  
Christian M. Julien
Keyword(s):  
Transition Metal Oxides ◽  
Solid Electrolytes ◽  
Electrode Materials ◽  
State Of The Art ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Exponential Increase ◽  
Prussian Blue Analogs ◽  
Made In

Sodium-ion batteries (SIBs) were investigated as recently as in the seventies. However, they have been overshadowed for decades, due to the success of lithium-ion batteries that demonstrated higher energy densities and longer cycle lives. Since then, the witness a re-emergence of the SIBs and renewed interest evidenced by an exponential increase of the publications devoted to them (about 9000 publications in 2019, more than 6000 in the first six months this year). This huge effort in research has led and is leading to an important and constant progress in the performance of the SIBs, which have conquered an industrial market and are now commercialized. This progress concerns all the elements of the batteries. We have already recently reviewed the salts and electrolytes, including solid electrolytes to build all-solid-state SIBs. The present review is then devoted to the electrode materials. For anodes, they include carbons, metal chalcogenide-based materials, intercalation-based and conversion reaction compounds (transition metal oxides and sulfides), intermetallic compounds serving as functional alloying elements. For cathodes, layered oxide materials, polyionic compounds, sulfates, pyrophosphates and Prussian blue analogs are reviewed. The electrode structuring is also discussed, as it impacts, importantly, the electrochemical performance. Attention is focused on the progress made in the last five years to report the state-of-the-art in the performance of the SIBs and justify the efforts of research.

Rational Design of Ti-Based Oxygen Redox Layered Oxides for Advanced Sodium-ion Batteries

2021 ◽  
Author(s):  
Jaewoon Lee ◽  
Sojung Koo ◽  
Jinwoo Lee ◽  
Duho Kim
Keyword(s):  
Transition Metals ◽  
Redox Reactions ◽  
Rational Design ◽  
Alkali Metals ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Layered Oxides

Considering Mn4+ (3d3)-based cations, various layered oxides (A[AyM1-y]O2, where A and M refer to alkali metals and transition metals, respectively) exhibiting oxygen-redox reactions have been investigated extensively to achieve high...

scholarly journals RECENT ADVANCES IN SODIUM INTERCALATION POSITIVE ELECTRODE MATERIALS FOR SODIUM ION BATTERIES

2013 ◽  
Vol 06 (01) ◽  
pp. 1330001 ◽  
Author(s):  
JING XU ◽  
DAE HOE LEE ◽  
YING SHIRLEY MENG
Keyword(s):  
Electrode Materials ◽  
High Energy ◽  
Positive Electrode ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Significant Progress ◽  
Layered Oxides ◽  
Solid State Physics ◽  
The Past ◽  
Positive Electrode Materials

Significant progress has been achieved in the research on sodium intercalation compounds as positive electrode materials for Na-ion batteries. This paper presents an overview of the breakthroughs in the past decade for developing high energy and high power cathode materials. Two major classes, layered oxides and polyanion compounds, are covered. Their electrochemical performance and the related crystal structure, solid state physics and chemistry are summarized and compared.

scholarly journals Nano Hard Carbon Anodes for Sodium-Ion Batteries

Nanomaterials ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 793 ◽  
Author(s):  
Dae-Yeong Kim ◽  
Dong-Hyun Kim ◽  
Soo-Hyun Kim ◽  
Eun-Kyung Lee ◽  
Sang-Kyun Park ◽  
...  
Keyword(s):  
Carbon Material ◽  
Electrode Materials ◽  
Coulombic Efficiency ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Amorphous Structure ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Intercalation Reaction

A hindrance to the practical use of sodium-ion batteries is the lack of adequate anode materials. By utilizing the co-intercalation reaction, graphite, which is the most common anode material of lithium-ion batteries, was used for storing sodium ion. However, its performance, such as reversible capacity and coulombic efficiency, remains unsatisfactory for practical needs. Therefore, to overcome these drawbacks, a new carbon material was synthesized so that co-intercalation could occur efficiently. This carbon material has the same morphology as carbon black; that is, it has a wide pathway due to a turbostratic structure, and a short pathway due to small primary particles that allows the co-intercalation reaction to occur efficiently. Additionally, due to the numerous voids present in the inner amorphous structure, the sodium storage capacity was greatly increased. Furthermore, owing to the coarse co-intercalation reaction due to the surface pore structure, the formation of solid-electrolyte interphase was greatly suppressed and the first cycle coulombic efficiency reached 80%. This study shows that the carbon material alone can be used to design good electrode materials for sodium-ion batteries without the use of next-generation materials.

scholarly journals Polymer Electrode Materials for Sodium-ion Batteries

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2567 ◽  
Author(s):  
Qinglan Zhao ◽  
Andrew Whittaker ◽  
X. Zhao
Keyword(s):  
Electrode Materials ◽  
Low Cost ◽  
Structural Diversity ◽  
Sodium Ion ◽  
Future Research ◽  
Sodium Ion Batteries ◽  
Energy Storage Devices ◽  
Promising Alternative ◽  
Research Perspectives ◽  
Battery Technology

Sodium-ion batteries are promising alternative electrochemical energy storage devices due to the abundance of sodium resources. One of the challenges currently hindering the development of the sodium-ion battery technology is the lack of electrode materials suitable for reversibly storing/releasing sodium ions for a sufficiently long lifetime. Redox-active polymers provide opportunities for developing advanced electrode materials for sodium-ion batteries because of their structural diversity and flexibility, surface functionalities and tenability, and low cost. This review provides a short yet concise summary of recent developments in polymer electrode materials for sodium-ion batteries. Challenges facing polymer electrode materials for sodium-ion batteries are identified and analyzed. Strategies for improving polymer electrochemical performance are discussed. Future research perspectives in this important field are projected.

Carbon nanofiber-based nanostructures for lithium-ion and sodium-ion batteries

2017 ◽  
Vol 5 (27) ◽  
pp. 13882-13906 ◽  
Author(s):  
Weihan Li ◽  
Minsi Li ◽  
Keegan R. Adair ◽  
Xueliang Sun ◽  
Yan Yu
Keyword(s):  
Lithium Ion Batteries ◽  
Carbon Nanofibers ◽  
Electrode Materials ◽  
Carbon Nanofiber ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
One Dimensional ◽  
Conductive Additives

Carbon nanofibers (CNFs) belong to a class of one-dimensional (1D) carbonaceous materials with excellent electronic conductivity, leading to their use as conductive additives in electrode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs).

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries

2012 ◽  
Vol 2 (7) ◽  
pp. 710-721 ◽  
Author(s):  
Sung-Wook Kim ◽  
Dong-Hwa Seo ◽  
Xiaohua Ma ◽  
Gerbrand Ceder ◽  
Kisuk Kang
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Sodium Ion ◽  
Sodium Ion Batteries
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