PhotoRAFT Polymerization of Vinylidene Fluoride Using a Household White LED as Light Source at Room Temperature

ChemPhotoChem ◽  
2019 ◽  
Vol 3 (11) ◽  
pp. 1095-1099 ◽  
Author(s):  
Qizhi Yang ◽  
Vincent Ladmiral ◽  
Bruno Améduri
2003 ◽  
Vol 769 ◽  
Author(s):  
Asha Sharma ◽  
Deepak ◽  
Monica Katiyar ◽  
Satyendra Kumar ◽  
V. Chandrasekhar ◽  
...  

AbstractThe optical degradation of polysilane copolymer has been studied in spin cast thin films and solutions using light source of 325 nm wavelength. The room temperature photoluminescence (PL) spectrum of these films show a sharp emission at 368 nm when excited with a source of 325 nm. However, the PL intensity deteriorates with time upon light exposure. Further the causes of this degradation have been examined by characterizing the material for its transmission behaviour and changes occurring in molecular weight as analysed by GPC data.


2010 ◽  
Vol 152-153 ◽  
pp. 44-50 ◽  
Author(s):  
Gui Bao Guo ◽  
Er Ding Han ◽  
Sheng Li An

A new method based on a solution graft technique was used to prepare poly (vinylidene fluoride) grafted polystyrene sulfonated acid (PVDF-g-PSSA) proton exchange membrane. Polystyrene is grafted into PVDF modified by plain sodium silicate (Na4SiO4). There is a linear relationship between the degree of grafting and the content of Na4SiO4. Fourier transform infrared spectroscopy is used to characterize changes of the membrane's microstructures after grafting and sulfonation. The morphology of the membrane's microstructures after grafting and sulfonation is studied by scanning electrolytic microscope (SEM). The effect of plain sodium silicate (Na4SiO4) concentration and relative humidity on the conductivity of the electrolyte was investigated by the impedance at room temperature. The results show that the styrene has been grafted into PVDF. The conductivity of PVDF-g-PSSA electrolyte doped 10% plain sodium silicate (Na4SiO4) is 0.016 S/cm at room temperature. The conductivity of the electrolyte changes slightly at a relative humidity range of 20%-70%. The weightlessness of PVDF-g-PSSA electrolyte heated to 40°C was less than 2%, which indicated that water capacity was good.


2018 ◽  
Author(s):  
X. Geng ◽  
C. Zhang ◽  
H. Charlier ◽  
M. Debliquy ◽  
D. Lahem ◽  
...  

2008 ◽  
Vol 495 (1) ◽  
pp. 80/[432]-96/[448] ◽  
Author(s):  
L. S. Chou ◽  
I-Hsin Lin
Keyword(s):  

2013 ◽  
Vol 815 ◽  
pp. 287-292
Author(s):  
Li Jing Min ◽  
Jing Fen Li

[Objectiv The aim is to study the extraction technology of melanin from banana peel, and discuss its stability. [Metho We used banana peel as raw material, the absorbance at 410 nm as the index, extracted melanin by base-acid method, and optimized the extraction technology by the single factor and orthogonal test. Then we discussed the melanins stability at different temperature, light source, pH value, metal ions, antioxidant and reducing agents.[Result The best extraction conditions of melanin is that, hydrochloric acid soak time 5 h, alkaline solution pH value 14, extracting time 20 min, extraction temperature 70 °C, absorbance value about 0.309 A. Melanin from banana peel is stable at high temperature, different light source irradiation, reducing agent coexist; but at room temperature, metal ions and oxidizing agent coexist, it is unstable. [Conclusio This study provided experimental basis for the optimization and development of melanin from banana peel.


2016 ◽  
Vol 613 ◽  
pp. 59-63 ◽  
Author(s):  
M.J. Lo Faro ◽  
C. D'Andrea ◽  
E. Messina ◽  
B. Fazio ◽  
P. Musumeci ◽  
...  

2019 ◽  
Vol 2019 ◽  
pp. 1-16 ◽  
Author(s):  
Ya Liu ◽  
Xiuxia Ren ◽  
Byoung Ryong Jeong

Adenophora triphylla(Thunb.) A.DC., a well-known herbaceous medicinal species, has been reported to protect against human obesity, cancer, and inflammation. Supplementary lighting is a practical strategy to improve crop quality, especially at a propagation stage. However, there has been no study available on the optimal supplementary light source for the commercial production ofA. triphyllaseedlings. In this study, plug seedlings were cultivated in a greenhouse for four weeks under an average daily light intensity of 490μmol·m−2·s−1PPFD coming from the sun and a supplemental lighting (16 h per day) at 120μmol·m−2·s−1PPFD provided by high pressure sodium (HPS), metal halide (MH), far-red (FR) light, white LED (red: green: blue = 2:4:3, LED-w), or mixed (red: green: blue = 4:1:4) LED (LED-mix). The results showed that LED-mix, with a higher percentage of red and blue light, substantially promoted seedling growth compared to other treatments by increasing stem diameter, biomass, specific leaf weight, and root to shoot ratio. The LED-mix also promoted accumulation of soluble sugar, starch, and chlorophyll in the tissue and increased contents of total phenols and flavonoids. Moreover, stomata density and pore area per leaf area under the LED-mix were remarkably greater than those under other treatments. Furthermore, the Western blot analysis revealed that the expression of photosynthetic protein, D1, was notably enhanced by the LED-mix as compared with other light sources. In addition, the LED-mix alleviated the oxidative damage of seedlings by improving enzymatic and nonenzymatic antioxidant systems. Collectively, these results suggest that the LED-mix was the optimal supplementary light source for the production of highest qualityA. triphyllaseedlings.


2019 ◽  
Vol 1 (8) ◽  
pp. 2999-3008 ◽  
Author(s):  
Rajan Kumar Singh ◽  
Sudipta Som ◽  
Somrita Dutta ◽  
Neha Jain ◽  
Mei-Tsun Kuo ◽  
...  

We present a facile room temperature synthesis of CH3NH3Pb1−xMnxI3 perovskite quantum dots (PQDs) substituting manganese (Mn2+) at the lead (Pb2+) sites to minimize environmental pollution and make it commercially feasible.


2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Maria Josè Lo Faro ◽  
Cristiano D’Andrea ◽  
Elena Messina ◽  
Barbara Fazio ◽  
Paolo Musumeci ◽  
...  

A description is given of a Raman apparatus designed primarily for intensity measurements by direct photo-electric recording. A special feature is a high- intensity light source with four Toronto-type mercury arcs. It is possible to use a variety of sample volumes and to make measurements on samples over a wide range of temperatures both above and below room temperature. Semi-quantitative polarization measurements can also be made. The recording system uses an E. M. I. eleven-stage photomultiplier cell with a. c. amplification at 285 c/s, followed by rectification in a phase-sensitive homodyne circuit. The output is fed to a Cambridge recording potentiometer. Details of calibration for intensity measurements are given and sample records are shown illustrating the various applications of the apparatus.


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