Relationship between the Molecular Structure of Cyanine Dyes and the Vibrational Fine Structure of their Electronic Absorption Spectra

ChemPhysChem ◽  
2009 ◽  
Vol 10 (5) ◽  
pp. 835-840 ◽  
Author(s):  
Heinz Mustroph ◽  
Knut Reiner ◽  
Jürgen Mistol ◽  
Steffen Ernst ◽  
Dietmar Keil ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Fine Structure ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Cyanine Dyes

Electronic absorption spectra of nitroanilines

1979 ◽  
Vol 44 (5) ◽  
pp. 1613-1618 ◽  
Author(s):  
Viktor Řehák ◽  
Vladimír Kadeřábek
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bond ◽  
Absorption Spectra ◽  
Intramolecular Hydrogen Bond ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Electronic System ◽  
Intramolecular Hydrogen ◽  
Absorption Transitions

Electronic absorption spectra of N-alkyl and N-arylsubstituted 2,4-dinitro- and 2,6-dinitroanilines are discussed in the terms of energy and intensity of the energetically lowest absorption transitions and molecular structure (intramolecular hydrogen bond, sterical effects, hyperconjugation and increase of the π-electronic system of the molecule.

scholarly journals Structure and electronic absorption spectra of cyanine dyes – derivatives of tetrazolo- and triazoloisoindole

2017 ◽  
Vol 5 (2) ◽  
pp. 95-102
Author(s):  
Tatyana Yegorova ◽  
Andriy Kysil ◽  
Igor Levkov ◽  
Andrei Ilchenko ◽  
Zoia Voitenko
Keyword(s):  
Electronic Structure ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Cyanine Dyes ◽  
End Groups ◽  
Electron Donation ◽  
Derivatives Of

The electronic structure and absorption spectra of cyanine dyes – tetrazoloisoindole derivatives and triazoloisoindole were calculated. It was shown that these dyes, in terms of their electronic structure, are trimethine cyanine, although formally they are monomethine cyanine. The electron donation of the tetrazoloisoindole and triazoloisoindole residues was determined on the Ilchenko scale, which allows them to quantitatively quantify their Bruker basicity in comparison with the most known heterocyclic end groups of cyanine dyes.

scholarly journals Optical properties of gumus acids of chernozem podzolized after applying litter and compostes on its basis

2017 ◽  
Vol 18 (3-4) ◽  
pp. 30-36
Author(s):  
Ie. V. Skrylnik ◽  
Iu. M. Tovstiy ◽  
M. A. Popirniy
Keyword(s):  
Molecular Structure ◽  
Absorption Spectra ◽  
Humic Acids ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Qualitative Composition ◽  
Electron Absorption Spectra ◽  
Humus Substances ◽  
Ultraviolet Range ◽  
Chicken Litter

Investigation of electronic absorption spectra of humic acids (HA) is considered as one of their objective diagnostic features and indicators of transformation of HA components. Electron absorption spectra of the HA in the visible and ultraviolet range, in general, are gentle curves, which monotonically decrease with increasing wavelength. However, even such spectra reveal the difference in the spectral properties of the HA not only of different soils, but also of one type under excellent soil conditions, which allows the use of spectrophotometric analysis as a sensitive method for the study of humic acids. A thorough study of the properties and nature of humus substances using modern methods helps to understand the features the formation of humus substances in different natural conditions. The purpose of the study is to determine the change in the qualitative composition of humic acids extracted from chernozem podzoled after application of the litter and compost on its basis by spectrophotometry. To achieve this goal, the following methods were used: modeling, laboratory analysis, mathematical and statistical. Field studies have been carried out to determine the effect of litter and compost on its basis on the formation of the molecular structure of humic acids from chernozem podzoled. The studies carried out by us, the electronic absorption spectra of humic acids of chernozem podzoled correspond to the curves typical for a class of humus, the shape of the spectrum does not change, which indicates the similarity in the molecular structure of humic acids, but differ in the angle of incidence in the region of the ultraviolet range. The qualitative composition of structural elements of humic acids is determined on the basis of the analysis of electron absorption spectra of humic acids in the spectral range of 200–800 nm. The change of optical characteristics of humic acids extracted from chernozem of podzolized after introduction of the litter and compost on its basis was determined. The application of chicken litter and compost (scent + husk) contributes to enhancing the aroma of humic acids and increasing their resistance to mineralization. It has been established that composting has a longer-lasting effect on the formation of the structure of humic acids of black podzolized soils on the introduction of non-composting litter. In the UV range (200–400 nm), we note the characteristic intensive absorption of light for humic acids extracted from chernozem podzolized after the introduction of chicken litter and compost (scent + husk), due to the loss of weakly colored peripheral chains of molecules. The character of the inclination of the curves determined by the ratio D 465/665 allows us to conclude that the humic acids extracted from the chernozem podzolized after composting (laced + husk) have a more condensed nucleus than the introduction of chicken litter and compost (laced + husk). It is determined that the intensity of the influence on the mobility of the aromatic electronic system of humic acids depends on the period of composting of the source material and is manifested in absorption spectra in the ultraviolet light range.

Absorptions- and Electronic Raman Spectra of Chloro- Bromo-Osmate (IV), [OsClnBr6-nJ 2-, n=0-6

1991 ◽  
Vol 46 (9) ◽  
pp. 803-808 ◽  
Author(s):  
K. Irmer ◽  
W. Preetz
Keyword(s):  
Fine Structure ◽  
Absorption Spectra ◽  
Raman Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Orbit Coupling ◽  
Spin Orbit Coupling ◽  
Spin Orbit

Abstract The electronic absorption spectra of the solid tetrabutylammonium salts of [OsClnBr6-n ]2-, n = 0-6, including the stereoisomers for n = 2, 3, 4, are measured at 10 K. The weak intraconfigurational excitations within the t2g4, manifold of Os(lV) are split by spin orbit coupling and lowered symmetry into multiplets, observed in the NIR regions 2600-3100, 4800-5400, 10 500-11 400 and 16 000 17 200 cm-1. The 0-0-transitions are deduced from vibrational fine structure and they are confirmed by electronic Raman bands with the same frequencies

scholarly journals Solvatochromism and halochromism of some furo/pyrazole cyanine dyes

2021 ◽  
Author(s):  
CI Chemistry International
Keyword(s):  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Mixed Solvents ◽  
Cyanine Dyes ◽  
Buffer Solutions ◽  
Ph Values ◽  
Universal Buffer ◽  
Different Types

In this study, the electronic absorption spectra of some furo[2,3-b]pyrazole cyanine dyes was recorded and investigated in a number of 6 (six) pure solvents having different polarities [water (78.54), D.M.F (36.70), ethanol (24.3), chloroform (4.806), CC14 (2.238) and dioxane (2.209)], mixed solvents [DMF- H2O] and/or in a series of 8 (eight) aqueous universal buffer solutions having varied pH values [1.65, 2.32, 4.62, 5.85, 6.41, 7.82, 9.61 and 11.63 units] to evaluate their solvatochromic and/or halochromic properties, respectively. The study covers different types of cyanine dyes, it includes monomethine cyanine dyes (simple cyanine dyes), dimethine cyanine dyes and tetramethine cyanine dyes.

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