Synthesis of Block Copolymers of 2-Ethylhexyl Methacrylate, n -Hexyl Methacrylate and Methyl Methacrylate via Anionic Polymerization at Ambient Temperature

2018 ◽  
Vol 36 (10) ◽  
pp. 934-938 ◽  
Author(s):  
Guijin Zou ◽  
Anna Zheng ◽  
Dafu Wei ◽  
Zheng Li ◽  
Ling Su ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Hexyl Methacrylate

scholarly journals Synthesis of poly(n-hexyl methacrylate)-b-poly(methyl methacrylate) via anionic polymerization with t-BuOK as the initiator at ambient temperature

RSC Advances ◽  
2017 ◽  
Vol 7 (85) ◽  
pp. 53996-54001 ◽  
Author(s):  
Anna Zheng ◽  
Ling Su ◽  
Zheng Li ◽  
Guijin Zou ◽  
Xiang Xu ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Initiation Mechanism ◽  
Poly Methyl Methacrylate ◽  
Hexyl Methacrylate

Initiation mechanism of t-BuOK on anionic polymerization of n-HMA in THF.

scholarly journals A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16049-16056 ◽  
Author(s):  
Zheng Li ◽  
Jianding Chen ◽  
Guijin Zou ◽  
Tongyuan Zhang ◽  
Dafu Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Synthesis Method ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate ◽  
High Yields

A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .

scholarly journals Multi-stimuli responsive block copolymers as a smart release platform for a polypyridyl ruthenium complex

2017 ◽  
Vol 8 (5) ◽  
pp. 890-900 ◽  
Author(s):  
Michael Appold ◽  
Cristina Mari ◽  
Christina Lederle ◽  
Johannes Elbert ◽  
Claudia Schmidt ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Ruthenium Complex ◽  
Stimuli Responsive ◽  
Poly Methyl Methacrylate ◽  
Dimethylaminoethyl Methacrylate

An efficient protocol for the preparation of poly(N,N-dimethylaminoethyl methacrylate)(PDMAEMA)-based multi-stimuli responsive block copolymers (BCPs) with poly(methyl methacrylate) (PMMA)viaanionic polymerization protocols is presented.

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