Precise Synthesis of Dendrimer-Like Star-Branched Polystyrenes and Block Copolymers Composed of Polystyrene and Poly(methyl methacrylate) Segments by an Iterative Methodology Using Living Anionic Polymerization

2009 ◽  
Vol 42 (13) ◽  
pp. 4558-4570 ◽  
Author(s):  
Hee-Soo Yoo ◽  
Takumi Watanabe ◽  
Akira Hirao
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate

scholarly journals Synthesis and post-polymerization reaction of end-clickable stereoregular polymethacrylates via termination of stereospecific living anionic polymerization

2015 ◽  
Vol 6 (7) ◽  
pp. 1078-1087 ◽  
Author(s):  
Yasuhiro Kohsaka ◽  
Takashi Kurata ◽  
Kazuki Yamamoto ◽  
Shoya Ishihara ◽  
Tatsuki Kitayama
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Polymerization Reaction ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate ◽  
End Groups

Poly(methyl methacrylate)s with high stereoregularity and clickable end-groups were synthesized via terminating reactions with α-(halomethyl)acrylates in stereospecific living anionic polymerization.

scholarly journals Multi-stimuli responsive block copolymers as a smart release platform for a polypyridyl ruthenium complex

2017 ◽  
Vol 8 (5) ◽  
pp. 890-900 ◽  
Author(s):  
Michael Appold ◽  
Cristina Mari ◽  
Christina Lederle ◽  
Johannes Elbert ◽  
Claudia Schmidt ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Ruthenium Complex ◽  
Stimuli Responsive ◽  
Poly Methyl Methacrylate ◽  
Dimethylaminoethyl Methacrylate

An efficient protocol for the preparation of poly(N,N-dimethylaminoethyl methacrylate)(PDMAEMA)-based multi-stimuli responsive block copolymers (BCPs) with poly(methyl methacrylate) (PMMA)viaanionic polymerization protocols is presented.

scholarly journals Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization

2018 ◽  
Vol 18 (3) ◽  
pp. 537 ◽  
Author(s):  
Melahat Göktaş ◽  
Guodong Deng
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Gel Permeation Chromatography ◽  
High Yield ◽  
Resonance Spectroscopy ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate ◽  
Redox Polymerization

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.

scholarly journals A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16049-16056 ◽  
Author(s):  
Zheng Li ◽  
Jianding Chen ◽  
Guijin Zou ◽  
Tongyuan Zhang ◽  
Dafu Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ambient Temperature ◽  
Anionic Polymerization ◽  
Diblock Copolymers ◽  
Synthesis Method ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Alkyl Methacrylate ◽  
High Yields

A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .

scholarly journals Two-dimensional chromatography of complex polymers. 3. Full analysis of polystyrene-poly(methyl methacrylate) diblock copolymers

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Harald Pasch ◽  
Kibret Mequanint ◽  
Adrian Jörg
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Diblock Copolymers ◽  
Size Exclusion ◽  
Molecular Heterogeneity ◽  
Two Dimensional ◽  
Poly Methyl Methacrylate ◽  
Mass Distributions ◽  
Exclusion Chromatography ◽  
Complex Polymers

AbstractPoly(styrene-block-methyl methacrylate)s were fully analyzed by liquid chromatography at the critical point of adsorption (LC-CC) and two-dimensional chromatography. Operating at chromatographic conditions corresponding to the critical points of the homopolymers polystyrene and poly(methyl methacrylate), the block lengths distributions for the different blocks of the block copolymers were determined quantitatively. Information on the amounts and molar mass distributions of homopolymers and coupling products that were identified in the samples as by-products was obtained by on-line coupled 2D chromatography. It was shown that a complete picture of the molecular heterogeneity of block copolymers can be obtained only when information from different chromatographic experiments is combined. Size exclusion chromatography alone is inappropriate for evaluating the molecular heterogeneity of such samples.

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