Recent Advances in Photocatalytic CO2 Reduction Using Earth-Abundant Metal Complexes-Derived Photocatalysts

2018 ◽  
Vol 36 (5) ◽  
pp. 455-460 ◽  
Author(s):  
Yanfei Zhao ◽  
Zhimin Liu
Keyword(s):  
Metal Complexes ◽  
Co2 Reduction ◽  
Recent Advances ◽  
Earth Abundant

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

ACS Catalysis ◽  
2016 ◽  
Vol 7 (1) ◽  
pp. 70-88 ◽  
Author(s):  
Hiroyuki Takeda ◽  
Claudio Cometto ◽  
Osamu Ishitani ◽  
Marc Robert
Keyword(s):  
Metal Complexes ◽  
Co2 Reduction ◽  
Earth Abundant ◽  
Molecular Catalysis

Photophysics and photochemistry with Earth-abundant metals – fundamentals and concepts

2020 ◽  
Vol 49 (4) ◽  
pp. 1057-1070 ◽  
Author(s):  
Christoph Förster ◽  
Katja Heinze
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Precious Metal ◽  
Recent Advances ◽  
Earth Abundant ◽  
Precious Metal Ions

This review summarizes fundamental challenges and recent advances in the design of photoactive and luminescent mononuclear transition metal complexes with Earth-abundant metal ions as sustainable alternatives to precious metal ions.

scholarly journals Recent Advances in Metal Catalyst Design for CO2 Hydroboration to C1 Derivatives

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 58
Author(s):  
Sylwia Kostera ◽  
Maurizio Peruzzini ◽  
Luca Gonsalvi
Keyword(s):  
Transition Metals ◽  
Chemical Synthesis ◽  
Building Block ◽  
Co2 Reduction ◽  
Main Group ◽  
Catalyst Design ◽  
Metal Catalyst ◽  
Simple Molecule ◽  
Recent Advances ◽  
Renewable Feedstock

The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The current minireview article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.

scholarly journals Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction

2021 ◽  
Author(s):  
Ally Aukauloo ◽  
Philipp Gotico ◽  
Winfried Leibl ◽  
Zakaria Halime
Keyword(s):  
Metal Complexes ◽  
Co2 Reduction ◽  
Electrocatalytic Performance

scholarly journals A high throughput optical method for studying compositional effects in electrocatalysts for CO2 reduction

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jeremy L. Hitt ◽  
Yuguang C. Li ◽  
Songsheng Tao ◽  
Zhifei Yan ◽  
Yue Gao ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
High Throughput ◽  
High Throughput Screening ◽  
Screening Method ◽  
Co2 Reduction ◽  
Fold Increase ◽  
Faradaic Efficiency ◽  
Atomic Pair Distribution Function ◽  
Earth Abundant ◽  
Ternary Catalysts

AbstractIn the problem of electrochemical CO2 reduction, the discovery of earth-abundant, efficient, and selective catalysts is essential to enabling technology that can contribute to a carbon-neutral energy cycle. In this study, we adapt an optical high throughput screening method to study multi-metallic catalysts for CO2 electroreduction. We demonstrate the utility of the method by constructing catalytic activity maps of different alloyed elements and use X-ray scattering analysis by the atomic pair distribution function (PDF) method to gain insight into the structures of the most active compositions. Among combinations of four elements (Au, Ag, Cu, Zn), Au6Ag2Cu2 and Au4Zn3Cu3 were identified as the most active compositions in their respective ternaries. These ternary electrocatalysts were more active than any binary combination, and a ca. 5-fold increase in current density at potentials of −0.4 to −0.8 V vs. RHE was obtained for the best ternary catalysts relative to Au prepared by the same method. Tafel plots of electrochemical data for CO2 reduction and hydrogen evolution indicate that the ternary catalysts, despite their higher surface area, are poorer catalysts for the hydrogen evolution reaction than pure Au. This results in high Faradaic efficiency for CO2 reduction to CO.

CO2 reduction catalysis by tunable square-planar transition-metal complexes: a theoretical investigation using nitrogen-substituted carbon nanotube models

2017 ◽  
Vol 19 (43) ◽  
pp. 29068-29076 ◽  
Author(s):  
Yu-Te Chan ◽  
Ming-Kang Tsai
Keyword(s):  
Density Functional Theory ◽  
Carbon Nanotube ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional ◽  
Co2 Reduction ◽  
Functional Theory ◽  
Square Planar ◽  
Planar Transition

The CO2 reduction capabilities of transition-metal-chelated nitrogen-substituted carbon nanotube models (TM-4N2v-CNT, TM = Fe, Ru, Os, Co, Rh, Ir, Ni, Pt or Cu) are characterized by density functional theory.

Hierarchical three-dimensional copper selenide nanocubes microelectrodes for improved carbon dioxide reduction reaction

2021 ◽  
Author(s):  
Rajasekaran Elakkiya ◽  
Govindhan Maduraiveeran
Keyword(s):  
Carbon Dioxide ◽  
High Performance ◽  
Three Dimensional ◽  
Co2 Reduction ◽  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Earth Abundant ◽  
Carbon Dioxide Co2 ◽  
Co2 Reduction Reaction

Design of high-performance and Earth-abundant electrocatalysts for electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) into fuels and value-added chemicals offers an emergent pathway for environment and energy sustainable concerns. Herein,...

Recent Advances in Biological and Catalytic Activities of Schiff base containing Acetylacetone and their Metal Complexes - A Short Overview

2020 ◽  
Vol 13 (5) ◽  
pp. 395-406
Author(s):  
Raisul Islam ◽  
Ekhlass Uddin ◽  
Ashrafuzzaman ◽  
Nur Amin Bitu ◽  
Ali Asraf ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Catalytic Activities ◽  
Short Overview ◽  
Recent Advances
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