Structures and Properties of Two New Three-Dimensional Inorganic-Organic Hybrid Compounds Based on Isopolymolybdate Clusters

2015 ◽  
Vol 34 (2) ◽  
pp. 239-245 ◽  
Author(s):  
Jingjing Wang ◽  
Xuena Yin ◽  
Bao Mu ◽  
Na Li ◽  
Rudan Huang
Keyword(s):  
Three Dimensional ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Structures And Properties

Isopolymolybdate-based inorganic–organic hybrid compounds constructed by multidentate N-donor ligands: syntheses, structures and properties

2019 ◽  
Vol 48 (17) ◽  
pp. 5541-5550 ◽  
Author(s):  
Haiyang Guo ◽  
Chunhua Gong ◽  
Xianghua Zeng ◽  
Hao Xu ◽  
Qingdao Zeng ◽  
...  
Keyword(s):  
Dye Degradation ◽  
Donor Ligands ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Structures And Properties ◽  
Photocatalytic Activities

Five isopolymolybdate-based hybrid compounds were achieved and their photocatalytic activities for dye degradation were explored.

Two Pillared Three-Dimensional Inorganic/Organic Hybrid Structures Composed of Bimetallic Layers Bridged by Exo-bidentate Ligands

2000 ◽  
Vol 658 ◽  
Author(s):  
Long Pan ◽  
Xiaoying Huang ◽  
Jing Li
Keyword(s):  
Three Dimensional ◽  
Bidentate Ligand ◽  
Organic Ligands ◽  
Hybrid Structures ◽  
Crystal Data ◽  
Bidentate Ligands ◽  
Inorganic Hybrid ◽  
Organic Hybrid ◽  
Hydrothermal Reactions ◽  
Hybrid Compounds

ABSTRACTThe hydrothermal reactions of Cu(NO3)2.3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), γ = 86.56(3), Å3 = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

POM-based metal–organic compounds: Assembly, structures and properties

2021 ◽  
pp. 1-18
Author(s):  
Jian Li ◽  
Zhe Liu ◽  
Yue-Yan Liu ◽  
Jie Liu ◽  
Yuan-Yuan Li ◽  
...  
Keyword(s):  
Infrared Spectrum ◽  
Organic Compounds ◽  
Organic Dyes ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Structures And Properties ◽  
Metal Organic

Four POM-based inorganic-organic hybrid compounds, which are {[(Cu·L1’·H2O)·(α-Mo8O26)0.5]·H2O}n (1), {(Cu·L2’·H2O)·(α-Mo8O26)0.5}n (2), {[(Cu·L3’·H2O)·(β-Mo8O26)0.5]·5H2O}n (3), {(Cu·L4’·H2O)·(β-Mo8O26)}n (4)[L1’ = 1,5-bis (4-carboxylpyridine) pentane dibromide, L2’ = 1,7-bis (4-carboxylpyridine) heptane dibromide, L3’ = 1,2-bis [(4-carboxylpyridine) - N-methylene] benzene dibromide, L4’ = 1,4-bis [(4-carboxylpyridine) - N-methylene] benzene dibromide] have been successfully synthesized under hydrothermal conditions by tuning ligands. Compounds 1–4 were characterized by single crystal X-ray diffraction, infrared spectrum (IR), powder X-ray diffraction (PXRD), and thermogravimetric (TG). The transformation of ligands have a momentous effect on the [Mo8O26]4 -  structures of this series. In addition, the adsorption and photocatalytic properties of organic dyes for compounds 1–4 have been investigated.

scholarly journals Correction: Isopolymolybdate-based inorganic–organic hybrid compounds constructed by multidentate N-donor ligands: syntheses, structures and properties

2019 ◽  
Vol 48 (19) ◽  
pp. 6646-6646
Author(s):  
Haiyang Guo ◽  
Chunhua Gong ◽  
Xianghua Zeng ◽  
Hao Xu ◽  
Qingdao Zeng ◽  
...  
Keyword(s):  
Donor Ligands ◽  
Dalton Trans ◽  
Organic Hybrid ◽  
Hybrid Compounds ◽  
Structures And Properties

Correction for ‘Isopolymolybdate-based inorganic–organic hybrid compounds constructed by multidentate N-donor ligands: syntheses, structures and properties’ by Haiyang Guo et al., Dalton Trans., 2019, DOI: 10.1039/c9dt00119k.

Three-dimensional lanthanide–silver heterometallic coordination polymers: syntheses, structures and properties

CrystEngComm ◽  
2010 ◽  
Vol 12 (10) ◽  
pp. 3267 ◽  
Author(s):  
Man-Sheng Chen ◽  
Zhi Su ◽  
Min Chen ◽  
Shui-Sheng Chen ◽  
Yi-Zhi Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Heterometallic Coordination Polymers
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