Synthesis and Surface Activity Study of a Novel Branched Fluorinated Anion Surfactant with CF3CF2CF2C(CF3)2Group

2014 ◽  
Vol 32 (10) ◽  
pp. 995-998 ◽  
Author(s):  
Min Sha ◽  
Renming Pan ◽  
Lewu Zhan ◽  
Ping Xing ◽  
Biao Jiang
Keyword(s):  
Surface Activity ◽  
Anion Surfactant

Influence of Partial Blocking of the Electrode Surface on the Transfer Coefficients

1993 ◽  
Vol 58 (3) ◽  
pp. 496-505
Author(s):  
Ondřej Wein
Keyword(s):  
Surface Activity ◽  
Elliptic Problem ◽  
Electrode Surface ◽  
Driving Force ◽  
Two Dimensional ◽  
Transfer Coefficients ◽  
Constant Potential ◽  
Numeric Solution ◽  
Active Zones ◽  
Partial Blocking

Partial blocking of the transport surface under the stagnant (nerst) layer is simulated by periodically alternating bands of perfectly insulating zones and active zones with a constant potential of driving force. The numeric solution of the corresponding two-dimensional elliptic problem is represented by a simple empirical correlation for the transfer coefficients. The result is interpreted in terms of a simple electrochemical problem about limiting diffusion currents at electrodes with non-uniform surface activity.

Betaine and l-carnitine ester bromides: Synthesis and comparative study of their thermal behaviour and surface activity

2021 ◽  
Vol 334 ◽  
pp. 115988
Author(s):  
Angelica Mero ◽  
Andrea Mezzetta ◽  
Janusz Nowicki ◽  
Justyna Łuczak ◽  
Lorenzo Guazzelli
Keyword(s):  
Comparative Study ◽  
Surface Activity ◽  
Thermal Behaviour

Sputtered titanium nitride films with finely tailored surface activity and porosity for high performance on-chip micro-supercapacitors

2021 ◽  
Vol 489 ◽  
pp. 229406
Author(s):  
Nana Sun ◽  
Dayu Zhou ◽  
Wenwen Liu ◽  
Aikui Li ◽  
Yunpeng Su ◽  
...  
Keyword(s):  
Titanium Nitride ◽  
Surface Activity ◽  
High Performance ◽  
On Chip

scholarly journals Surface Activity of Humic Acid and Its Sub-Fractions from Forest Soil

2021 ◽  
Vol 13 (15) ◽  
pp. 8122
Author(s):  
Shijie Tian ◽  
Weiqiang Tan ◽  
Xinyuan Wang ◽  
Tingting Li ◽  
Fanhao Song ◽  
...  
Keyword(s):  
Surface Tension ◽  
Particle Size ◽  
Humic Acid ◽  
Forest Soil ◽  
Surface Activity ◽  
Self Assembly ◽  
Average Particle Size ◽  
Gaussian Model ◽  
Exponential Model ◽  
Average Particle

Surface activity of humic acid (HA) and its six sub-fractions isolated from forest soil were characterized by surface tension measurements, dynamic light scattering, and laser doppler electrophoresis. The surface tension of HA and its sub-fractions reduced from 72.4 mN·m−1 to 36.8 mN·m−1 in exponential model with the increasing concentration from 0 to 2000 mg·L−1. The critical micelle concentration (CMC) and Z-average particle size ranged from 216–1024 mg·L−1 and 108.2–186.9 nm for HA and its sub-fractions, respectively. The CMC have related with alkyl C, O-alkyl C, aromatic C, and carbonyl C (p < 0.05), respectively, and could be predicted with the multiple linear regression equation of CMC, CMC = 18896 − 6.9 × C-296 × alkyl C-331 × aromatic C-17019 × H/C + 4054 × HB/HI (p < 0.05). The maximum particle size was 5000 nm after filtered by a membrane with pore size of 450 nm, indicating HA and its sub-fractions could progressed self-assembly at pH 6.86. The aggregate sizes of number-base particle size distributions were mainly in six clusters including 2 ± 1 nm, 5 ± 2 nm, 10 ± 3 nm, 21 ± 8 nm, 40 ± 10 nm, and >50 nm analyzed by Gaussian model that maybe due to the inconsistency of the components and structures of the HA sub-fractions, requiring further study. It is significance to explore the surface activity of HA and its sub-fractions, which is helpful to clarify the environmental behavior of HA.

scholarly journals Improving heavy oil recovery, part (I): synthesis and surface activity evaluation of some novel organometallic surfactants based on salen–M complexes

RSC Advances ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 1750-1761
Author(s):  
M. M. Abdelhamid ◽  
S. A. Rizk ◽  
M. A. Betiha ◽  
S. M. Desouky ◽  
A. M. Alsabagh
Keyword(s):  
Surface Activity ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Heavy Oil Recovery ◽  
Activity Evaluation ◽  
New Family

This study focuses on preparing a new family of organometallic surfactants based on five ion complexes, namely Co2+, Ni2+, Cu2+, Fe3+, and Mn2+.

scholarly journals On factors affecting surface free energy of carbon black for reinforcing rubber

2020 ◽  
Vol 9 (1) ◽  
pp. 170-181 ◽  
Author(s):  
Shangyong Zhang ◽  
Ruipeng Zhong ◽  
Ruoyu Hong ◽  
David Hui
Keyword(s):  
Free Energy ◽  
Carbon Black ◽  
Surface Free Energy ◽  
Surface Activity ◽  
Gas Flow ◽  
Influential Factors ◽  
Chromatographic Column ◽  
Factors Affecting ◽  
Carrier Gas Flow

AbstractThe surface activity of carbon black (CB) is an important factor affecting the reinforcement of rubber. The quantitative determination of the surface activity (surface free energy) of CB is of great significance. A simplified formula is obtained to determine the free energy of CB surface through theoretical analysis and mathematical derivation. The surface free energy for four kinds of industrial CBs were measured by inverse gas chromatography, and the influential factors were studied. The results showed that the aging time of the chromatographic column plays an important role in accurate measurement of the surface free energy of CB, in comparison with the influences from the inlet pressure and carrier gas flow rate of the chromatographic column filled with CB. Several kinds of industrial CB were treated at high temperature, and the surface free energy of CB had a significant increase. With the increase of surface free energy, the maximum torque was decreased significantly, the elongation at break tended to increase, the heat generation of vulcanizates was increased, and the wear resistance was decreased.

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