scholarly journals Synthesis of Cyclopropane-containing Building Blocks via Ir-Catalyzed Enantioselective Allylic Substitution Reaction

2010 ◽  
Vol 28 (9) ◽  
pp. 1525-1528 ◽  
Author(s):  
Jibao Xia ◽  
Chunxiang Zhuo ◽  
Shuli You
Keyword(s):  
Substitution Reaction ◽  
Building Blocks ◽  
Allylic Substitution

Stereodivergent synthesis of 1,4-bifunctional compounds by regio- and diastereoselective Pd-catalyzed allylic substitution reaction

Tetrahedron ◽  
2006 ◽  
Vol 62 (44) ◽  
pp. 10361-10378 ◽  
Author(s):  
Naoyoshi Maezaki ◽  
Masahiro Yano ◽  
Yuki Hirose ◽  
Yoshikazu Itoh ◽  
Tetsuaki Tanaka
Keyword(s):  
Substitution Reaction ◽  
Allylic Substitution ◽  
Bifunctional Compounds

scholarly journals Chiral Brønsted acid-catalyzed intramolecular SN2′ reaction for enantioselective construction of a quaternary stereogenic center

2018 ◽  
Vol 9 (26) ◽  
pp. 5747-5757 ◽  
Author(s):  
Masahiro Shimizu ◽  
Jun Kikuchi ◽  
Azusa Kondoh ◽  
Masahiro Terada
Keyword(s):  
Substitution Reaction ◽  
Allylic Substitution ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Sn2 Reaction ◽  
Brönsted Acid ◽  
Acid Catalyzed ◽  
Chiral Bronsted Acid ◽  
Stereogenic Center

Construction of a quaternary stereogenic center was accomplished through the enantioselective intramolecular allylic substitution reaction of bis-trichloroacetimidate catalyzed by a chiral phosphoramide derivative.

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