Allylation of Carbonyl Compounds Mediated by Aluminum/Fluoride Salts in Water

2010 ◽  
Vol 28 (4) ◽  
pp. 578-582 ◽  
Author(s):  
Shizhen Yuan ◽  
Jin Liu ◽  
Ling Xu ◽  
Shaofeng Zhu
Keyword(s):  
Carbonyl Compounds ◽  
Aluminum Fluoride ◽  
Fluoride Salts

ChemInform Abstract: Allylation of Carbonyl Compounds Mediated by Aluminum/Fluoride Salts in Water.

ChemInform ◽  
2010 ◽  
Vol 41 (36) ◽  
pp. no-no
Author(s):  
Shizhen Yuan ◽  
Jin Liu ◽  
Ling Xu ◽  
Shaofeng Zhu
Keyword(s):  
Carbonyl Compounds ◽  
Aluminum Fluoride ◽  
Fluoride Salts

scholarly journals Selective Adsorption of Sodium Aluminum Fluoride Salts from Molten Aluminum

2007 ◽  
Author(s):  
Leonard S Aubrey ◽  
Christine A Boyle ◽  
Eddie M Williams ◽  
David H DeYoung ◽  
Dawid D Smith ◽  
...  
Keyword(s):  
Molten Aluminum ◽  
Selective Adsorption ◽  
Aluminum Fluoride ◽  
Fluoride Salts

Silicon Assisted Sulfuration: Tetrachlorosilane-Sodium Sulfide-A New Potent Thionating Reagent for Carbonyl Compounds

2007 ◽  
Author(s):  
T. A. Salama ◽  
S. S. Elmorsy ◽  
A. M. Khalil ◽  
M. A. Ismail ◽  
A. S. El-Ahl
Keyword(s):  
Carbonyl Compounds ◽  
Sodium Sulfide

A FACILE SYNTHESIS AND REACTIONS OF AMINO SELENOLO[2,3-b]PYRIDINE CARBOXYLATE

2015 ◽  
Vol 12 (1) ◽  
pp. 3910-3918 ◽  
Author(s):  
Dr Remon M Zaki ◽  
Prof Adel M. Kamal El-Dean ◽  
Dr Nermin A Marzouk ◽  
Prof Jehan A Micky ◽  
Mrs Rasha H Ahmed
Keyword(s):  
Biological Activity ◽  
Carbonyl Compounds ◽  
Mass Spectra ◽  
The Other ◽  
Pyridine Derivatives ◽  
Facile Synthesis ◽  
High Biological Activity ◽  
Basic Hydrolysis ◽  
Pyridine Carboxylate ◽  
Hydrolysis Of

 Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f  which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.

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