Kinetic measurements of acrylic acid polymerization in a pendular slug reactor

2020 ◽  
Vol 92 (9) ◽  
pp. 1362-1362
Author(s):  
T. Klement ◽  
T. Röder ◽  
N. Kockmann
Keyword(s):  
Acrylic Acid ◽  
Kinetic Measurements

Formation of By-products in Pure and Aqueous Acrylic Acid - Kinetic Measurements and Formation Mechanisms

2017 ◽  
Vol 40 (4) ◽  
pp. 755-759
Author(s):  
Christian A. Pfeifer ◽  
Cordula Scholz ◽  
Kevin Vogel ◽  
Alfons Drochner ◽  
Herbert Vogel
Keyword(s):  
Acrylic Acid ◽  
Formation Mechanisms ◽  
Kinetic Measurements ◽  
By Products

Soft ionic liquid based resistive memory characteristics in a two terminal discrete polydimethylsiloxane cylindrical microchannel

2020 ◽  
Vol 8 (38) ◽  
pp. 13368-13374
Author(s):  
Muhammad Umair Khan ◽  
Gul Hassan ◽  
Jinho Bae
Keyword(s):  
Ionic Liquid ◽  
Acrylic Acid ◽  
Sodium Hydroxide ◽  
Sodium Salt ◽  
Resistive Memory ◽  
Cylindrical Microchannel ◽  
Memory Characteristics ◽  
Poly Acrylic Acid

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.

The Role of the Initiator System in the Synthesis of Acidic Multifunctional Nanoparticles Designed for Molecular Imprinting of Proteins

2020 ◽  
Vol 65 (1) ◽  
pp. 28-41
Author(s):  
Marwa Aly Ahmed ◽  
Júlia Erdőssy ◽  
Viola Horváth
Keyword(s):  
Acrylic Acid ◽  
Binding Affinity ◽  
Molecular Imprinting ◽  
Low Temperatures ◽  
Ammonium Persulfate ◽  
Sodium Bisulfite ◽  
Multifunctional Nanoparticles ◽  
High Affinity ◽  
Initiator System

Multifunctional nanoparticles have been shown earlier to bind certain proteins with high affinity and the binding affinity could be enhanced by molecular imprinting of the target protein. In this work different initiator systems were used and compared during the synthesis of poly (N-isopropylacrylamide-co-acrylic acid-co-N-tert-butylacrylamide) nanoparticles with respect to their future applicability in molecular imprinting of lysozyme. The decomposition of ammonium persulfate initiator was initiated either thermally at 60 °C or by using redox activators, namely tetramethylethylenediamine or sodium bisulfite at low temperatures. Morphology differences in the resulting nanoparticles have been revealed using scanning electron microscopy and dynamic light scattering. During polymerization the conversion of each monomer was followed in time. Striking differences were demonstrated in the incorporation rate of acrylic acid between the tetramethylethylenediamine catalyzed initiation and the other systems. This led to a completely different nanoparticle microstructure the consequence of which was the distinctly lower lysozyme binding affinity. On the contrary, the use of sodium bisulfite activation resulted in similar nanoparticle structural homogeneity and protein binding affinity as the thermal initiation.

Propane Selective Oxidation to Acrylic Acid over Combined Catalysts

2014 ◽  
Vol 32 (6) ◽  
pp. 1022-1026
Author(s):  
Wen FANG ◽  
Qingjie GE ◽  
Jiafeng YU ◽  
Hengyong XU
Keyword(s):  
Acrylic Acid ◽  
Selective Oxidation ◽  
Combined Catalysts ◽  
Propane Selective Oxidation
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