scholarly journals Ionic Liquids in Extractive Distillation Solvent Selection, Conceptual Process Design, and Pilot Plant Validation

2013 ◽  
Vol 85 (9) ◽  
pp. 1358-1358
Author(s):  
A. B. de Haan ◽  
G. W. Meindersma ◽  
E. Quijada-Maldonado ◽  
M. T. G. Jongmans ◽  
J. P. Gutiérrez Hernandez ◽  
...  
Author(s):  
G. Wytze Meindersma ◽  
Esteban Quijada-Maldonado ◽  
Mark T. G. Jongmans ◽  
Juan Pablo Gutiérrez Hernandez ◽  
Boelo Schuur ◽  
...  

2015 ◽  
Vol 69 (2) ◽  
Author(s):  
Boelo Schuur

AbstractSince the late 1990’s there has been a tremendous growth in literature on ionic liquids (ILs) for a broad range of applications, i.e. catalysis, electrolytes for batteries, in solvolysis of biomass, and also in separation technology. ILs can be applied as solvents for absorption (e.g. of CO2), extractive distillation and extraction processes. That ILs are not magic solvents but have their limitations has also become evident during the past years. Especially the high costs associated with ILs and the lack of experience with these materials in the industrial practice are factors limiting industrial adoption of ILs. The often praised versatility of properties that can be achieved through combination of different cations and anions generates a huge amount of options and makes it difficult to decide where to start when selecting/designing a solvent. This paper focuses on solvent selection/design for applications in extractive distillations and liquid-liquid extractions; also, solvent performance in several specific case studies taken from the open literature is discussed. Important recommendations include: a) make a conceptual process design including the recovery step, regeneration of the IL may be a critical parameter; b) if extractions from aqueous streams are studied, the uptake of water by the IL is an important factor because such co-extracted water is evaporated during the regeneration; c) compare the process with conventional processes to check whether it performs better than the state-of-the-art in industry.


2012 ◽  
Vol 90 (12) ◽  
pp. 2086-2100 ◽  
Author(s):  
Mark T.G. Jongmans ◽  
Eline Hermens ◽  
Mark Raijmakers ◽  
Jenny I.W. Maassen ◽  
Boelo Schuur ◽  
...  

2009 ◽  
Vol 13 (4) ◽  
pp. 690-697 ◽  
Author(s):  
Daniel Hsieh ◽  
Alexander J. Marchut ◽  
Chenkou Wei ◽  
Bin Zheng ◽  
Steve S. Y. Wang ◽  
...  

Author(s):  
G. Wytze Meindersma ◽  
Esteban Quijada-Maldonado ◽  
Tim A. M. Aelmans ◽  
Juan Pablo Gutierrez Hernandez ◽  
André B. de Haan

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 455
Author(s):  
Nikolaos Boukis ◽  
I. Katharina Stoll

Gasification of organic matter under the conditions of supercritical water (T > 374 °C, p > 221 bar) is an allothermal, continuous flow process suitable to convert materials with high moisture content (<20 wt.% dry matter) into a combustible gas. The gasification of organic matter with water as a solvent offers several benefits, particularly the omission of an energy-intensive drying process. The reactions are fast, and mean residence times inside the reactor are consequently low (less than 5 min). However, there are still various challenges to be met. The combination of high temperature and pressure and the low concentration of organic matter require a robust process design. Additionally, the low value of the feed and the product predestinate the process for decentralized applications, which is a challenge for the economics of an application. The present contribution summarizes the experience gained during more than 10 years of operation of the first dedicated pilot plant for supercritical water gasification of biomass. The emphasis lies on highlighting the challenges in process design. In addition to some fundamental results gained from comparable laboratory plants, selected experimental results of the pilot plant “VERENA” (acronym for the German expression “experimental facility for the energetic exploitation of agricultural matter”) are presented.


Energies ◽  
2017 ◽  
Vol 10 (9) ◽  
pp. 1276 ◽  
Author(s):  
Carlos Cantero ◽  
Guadalupe Lopez ◽  
Victor Alvarado ◽  
Ricardo Jimenez ◽  
Jesse Morales ◽  
...  

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