ChemInform Abstract: Controllable Assembly of Vanadium-Containing Polyoxoniobate-Based Three-Dimensional Organic-Inorganic Hybrid Compounds and Their Photocatalytic Properties.

ChemInform ◽  
2016 ◽  
Vol 47 (43) ◽  
Author(s):  
Jufang Hu ◽  
Yin Wang ◽  
Xinning Zhang ◽  
Yingnan Chi ◽  
Song Yang ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Photocatalytic Properties ◽  
Inorganic Hybrid ◽  
Hybrid Compounds

Photocatalytic properties of two POM-templated organic–inorganic hybrid compounds

2015 ◽  
Vol 56 ◽  
pp. 112-115 ◽  
Author(s):  
Xue-Jing Dui ◽  
Xiao-Yuan Wu ◽  
Jian-Zhen Liao ◽  
Teng Teng ◽  
Wei-Ming Wu ◽  
...  
Keyword(s):  
Photocatalytic Properties ◽  
Inorganic Hybrid ◽  
Hybrid Compounds

A three-dimensional hydrogen-bonded network in bis(4-hydroxyanilinium) selenate(VI) dihydrate

2009 ◽  
Vol 65 (3) ◽  
pp. o121-o122 ◽  
Author(s):  
Jan Janczak ◽  
Genivaldo Julio Perpétuo
Keyword(s):  
Crystal Engineering ◽  
Three Dimensional ◽  
The Other ◽  
Water Molecules ◽  
Inorganic Hybrid ◽  
Hybrid Compounds ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Hydroxy Groups ◽  
Oppositely Charged

The title compound, 2C6H8NO+·SeO42−·2H2O, contains 4-hydroxyanilinium cations, selenate(VI) anions and water molecules. One of the two independent cations is nearly planar (excluding the ammonium H atoms), while the other is markedly nonplanar, with the hydroxy and ammonium groups displaced from the plane of the benzene ring. This results from the antiparallel orientation of the cations, which interact through oppositely polarized ammonium and hydroxy groups. Ionic and hydrogen-bonding interactions join the oppositely charged units into a three-dimensional network. This work demonstrates the usefulness of 4-aminophenol in the crystal engineering of organic–inorganic hybrid compounds.

Two Pillared Three-Dimensional Inorganic/Organic Hybrid Structures Composed of Bimetallic Layers Bridged by Exo-bidentate Ligands

2000 ◽  
Vol 658 ◽  
Author(s):  
Long Pan ◽  
Xiaoying Huang ◽  
Jing Li
Keyword(s):  
Three Dimensional ◽  
Bidentate Ligand ◽  
Organic Ligands ◽  
Hybrid Structures ◽  
Crystal Data ◽  
Bidentate Ligands ◽  
Inorganic Hybrid ◽  
Organic Hybrid ◽  
Hydrothermal Reactions ◽  
Hybrid Compounds

ABSTRACTThe hydrothermal reactions of Cu(NO3)2.3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), γ = 86.56(3), Å3 = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

scholarly journals Synthesis, X-ray diffraction and Hirshfeld surface analysis of two new hybrid dihydrate compounds: (C6H22N4)[SnCl6]Cl2·2H2O and (C8H24N4)[SnCl6]Cl2·2H2O

2018 ◽  
Vol 74 (2) ◽  
pp. 206-211
Author(s):  
Rafika Bouchene ◽  
Zohir Lecheheb ◽  
Ratiba Belhouas ◽  
Sofiane Bouacida
Keyword(s):  
Crystal Structures ◽  
Surface Analysis ◽  
Three Dimensional ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Hybrid Compounds

Two new organic–inorganic hybrid compounds, triethylenetetraammonium hexachloridostannate (IV) dichloride dihydrate, (C6H22N4)[SnCl6]Cl2·2H2O, (I), and 1,4-bis(2-ammonioethyl)piperazin-1,4-diium hexachloridostannate (IV) dichloride dihydrate, (C8H24N4)[SnCl6]Cl2·2H2O, (II), have been synthesized from the same starting materials. In each case both the cations and anions are located about inversion centers. Their crystal structures exhibits alternating inorganic and organic stacking sheets in (I) and layers in (II), with Cl− ions and water molecules occupying the space in between. The cohesion of the three-dimensional frameworks are governed by N—H...Cl, N—H...O, C—H...Cl and O—H...Cl hydrogen bonds. Hirshfeld surface analysis of both crystal structures indicates that the H...Cl/Cl...H contacts exert an important influence on the stabilization of the packing.

Novel Organic-Inorganic Hybrid Compounds Containing Alkyldiammonium Salts

2002 ◽  
Vol 376 (1) ◽  
pp. 89-94 ◽  
Author(s):  
Takashi Matsui ◽  
Mitsuyasu Kawahara ◽  
Kenjiro Teshima ◽  
Masahiro Rikukawa ◽  
Kohei Sanui
Keyword(s):  
Inorganic Hybrid ◽  
Hybrid Compounds

Architecture and surface morphology of organic-inorganic hybrid compounds

2003 ◽  
Vol 137 (1-3) ◽  
pp. 907-908 ◽  
Author(s):  
K. Mizusawa ◽  
K. Kikuchi ◽  
Y. Takeoka ◽  
M. Rikukawa ◽  
K. Sanui
Keyword(s):  
Surface Morphology ◽  
Inorganic Hybrid ◽  
Hybrid Compounds
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