ChemInform Abstract: Synthesis, Crystal Structure and High-Temperature Transport Properties of the New Cluster Compound Rb2Mo15Se19.

ChemInform ◽  
2016 ◽  
Vol 47 (24) ◽  
Author(s):  
Gilles Daigre ◽  
Patrick Gougeon ◽  
Philippe Gall ◽  
Regis Gautier ◽  
Olivier Guillou ◽  
...  
2016 ◽  
Vol 237 ◽  
pp. 1-6 ◽  
Author(s):  
Gilles Daigre ◽  
Patrick Gougeon ◽  
Philippe Gall ◽  
Régis Gautier ◽  
Olivier Guillou ◽  
...  

2017 ◽  
Vol 56 (16) ◽  
pp. 9684-9692 ◽  
Author(s):  
Patrick Gougeon ◽  
Philippe Gall ◽  
Odile Merdrignac-Conanec ◽  
Lionel Aranda ◽  
Anne Dauscher ◽  
...  

2013 ◽  
Vol 52 (24) ◽  
pp. 14364-14367 ◽  
Author(s):  
Yongkwan Dong ◽  
Hsin Wang ◽  
George S. Nolas

2011 ◽  
Vol 184 (3) ◽  
pp. 698-704 ◽  
Author(s):  
M.S. Kaluzhskikh ◽  
S.M. Kazakov ◽  
G.N. Mazo ◽  
S.Ya. Istomin ◽  
E.V. Antipov ◽  
...  

2017 ◽  
Vol 35 (3) ◽  
pp. 496-500 ◽  
Author(s):  
Lingjiao Kong ◽  
Hongan Ma ◽  
Yuewen Zhang ◽  
Xin Guo ◽  
Bing Sun ◽  
...  

AbstractN-type polycrystalline skutterudite compounds Ni0.15Co3.85Sb12 and Fe0.2Ni0.15Co3.65Sb12 with the bcc crystal structure were synthesized by high pressure and high temperature (HPHT) method. The synthesis time was sharply reduced to approximately half an hour. Typical microstructures connected with lattice deformations and dislocations were incorporated in the samples of Ni0.15Co3.85Sb12 and Fe0.2Ni0.15Co3.65Sb12 after HPHT. Electrical and thermal transport properties were meticulously researched in the temperature range of 300 K to 700 K. The Fe0.2Ni0.15Co3.65Sb12 sample shows a lower thermal conductivity than that of Ni0.15Co3.85Sb12. The dimensionless thermoelectric figure-of-merit (zT) reaches the maximal values of 0.52 and 0.35 at 600 K and 700 K respectively, for Ni0.15Co3.85Sb12 and Fe0.2Ni0.15Co3.65Sb12 samples synthesized at 1 GPa.


2019 ◽  
Vol 74 (4) ◽  
pp. 357-363
Author(s):  
Daniela Vitzthum ◽  
Hubert Huppertz

AbstractThe mixed cation triel borate Ga4In4B15O33(OH)3 was synthesized in a Walker-type multianvil apparatus at high-pressure/high-temperature conditions of 12.5 GPa and 1300°C. Although the product could not be reproduced in further experiments, its crystal structure could be reliably determined via single-crystal X-ray diffraction data. Ga4In4B15O33(OH)3 crystallizes in the tetragonal space group I41/a (origin choice 2) with the lattice parameters a = 11.382(2), c = 15.244(2) Å, and V = 1974.9(4) Å3. The structure of the quaternary triel borate consists of a complex network of BO4 tetrahedra, edge-sharing InO6 octahedra in dinuclear units, and very dense edge-sharing GaO6 octahedra in tetranuclear units.


1995 ◽  
Vol 64 (6) ◽  
pp. 2118-2126 ◽  
Author(s):  
Sakae Todo ◽  
Kiiti Siratori ◽  
Shigeyuki Kimura

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