ChemInform Abstract: Stereoselective Synthesis of Trisubstituted Alkenes Through Sequential Iron-Catalyzed Reductive anti-Carbozincation of Terminal Alkynes and Base-Metal-Catalyzed Negishi Cross-Coupling.

ChemInform ◽  
2016 ◽  
Vol 47 (16) ◽  
Author(s):  
Chi Wai Cheung ◽  
Xile Hu
Keyword(s):  
Base Metal ◽  
Stereoselective Synthesis ◽  
Cross Coupling ◽  
Terminal Alkynes ◽  
Metal Catalyzed ◽  
Trisubstituted Alkenes

A Facile Stereoselective Synthesis of 1,3-dienyltellurides via Palladium Catalysed Cross-Coupling Reactions

2005 ◽  
Vol 2005 (6) ◽  
pp. 369-371 ◽  
Author(s):  
Mingzhong Cai ◽  
Junmin Chen ◽  
Wenyan Hao
Keyword(s):  
Stereoselective Synthesis ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Terminal Alkynes ◽  
Cross Coupling Reactions

Hydrozirconation of terminal alkynes 1 gives (E)-alkenylzirconium complexes 3, which cross-couple with (E)-α-iodovinyltellurides 4 in the presence of [Pd(PPh3)4] catalyst to afford stereoselectively 1,3-dienyltellurides 5 in good yields.

A regio- and stereoselective entry to (Z)-β-halo alkenyl sulfides and their applications to access stereodefined trisubstituted alkenes

2014 ◽  
Vol 12 (14) ◽  
pp. 2310-2321 ◽  
Author(s):  
Ge Liu ◽  
Lichun Kong ◽  
Ji Shen ◽  
Gangguo Zhu
Keyword(s):  
Stereoselective Synthesis ◽  
Cross Coupling ◽  
Trisubstituted Alkenes ◽  
New Entry

A regio- and stereoselective synthesis of (Z)-β-halo alkenyl sulfides via K2CO3-promoted hydrothiolation of haloalkynes has been reported, permitting a new entry to trisubstituted alkenes featuring the iterative cross-coupling of carbon–halide and carbon–sulfur bonds.

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