ChemInform Abstract: Extremely Bulky Amide Ligands in Main Group Chemistry

ChemInform ◽  
2016 ◽  
Vol 47 (14) ◽  
Author(s):  
Deborah L. Kays
Keyword(s):  
Main Group ◽  
Main Group Chemistry ◽  
Amide Ligands

Extremely bulky amide ligands in main group chemistry

2016 ◽  
Vol 45 (4) ◽  
pp. 1004-1018 ◽  
Author(s):  
Deborah L. Kays
Keyword(s):  
Small Molecule ◽  
Main Group ◽  
Small Molecule Activation ◽  
Coordination Modes ◽  
Main Group Chemistry ◽  
Amide Ligands ◽  
Outstanding Feature ◽  
Sterically Demanding ◽  
Group Species

The development of extremely sterically demanding, monodentate amide ligands facilitates the isolation of main group species with new and highly reactive coordination modes. An outstanding feature of these ligands is the ability to tune their steric demands. Reactivity investigations highlight the potential for small molecule activation chemistry and catalysis for these compounds.

scholarly journals Main-group chemistry of the 2,4,6-tris(trifluoromethyl)phenyl substituent: x-ray crystal structures of [2,4,6-(CF3)3C6H2]2Zn, [2,4,6-(CF3)3C6H2]2Cd(MeCN) and [2,4,6-(CF3)3C6H3]2Hg

1992 ◽  
Vol 11 (1) ◽  
pp. 192-195 ◽  
Author(s):  
Sally Brooker ◽  
Norbert Bertel ◽  
Dietmar Stalke ◽  
Mathias Noltemeyer ◽  
Herbert W. Roesky ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Main Group ◽  
Phenyl Substituent ◽  
X Ray ◽  
Main Group Chemistry

Hyperbonding and Hypercoordination in Main-Group Chemistry

2013 ◽  
pp. 109-132 ◽  
Author(s):  
R.M. Minyaev ◽  
T.N. Gribanova ◽  
V.I. Minkin
Keyword(s):  
Main Group ◽  
Main Group Chemistry

scholarly journals Push and pull: the potential role of boron in N2 activation

2018 ◽  
Vol 47 (31) ◽  
pp. 10377-10381 ◽  
Author(s):  
Adam J. Ruddy ◽  
Darren M. C. Ould ◽  
Paul D. Newman ◽  
Rebecca L. Melen
Keyword(s):  
Potential Role ◽  
Main Group ◽  
Main Group Chemistry ◽  
Recent Developments ◽  
Push And Pull ◽  
N2 Activation

Recent developments in main group chemistry towards the activation and conversion of N2 have lead to the revelation that boron can greatly affect these processes.

Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage

2019 ◽  
Vol 119 (14) ◽  
pp. 8262-8290 ◽  
Author(s):  
S. P. Fisher ◽  
A. W. Tomich ◽  
S. O. Lovera ◽  
J. F. Kleinsasser ◽  
J. Guo ◽  
...  
Keyword(s):  
Energy Storage ◽  
Main Group ◽  
Main Group Chemistry ◽  
Carborane Anions
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