ChemInform Abstract: A New Class of PN3-Pincer Ligands for Metal-Ligand Cooperative Catalysis

ChemInform ◽  
2015 ◽  
Vol 46 (47) ◽  
pp. no-no
Author(s):  
Huaifeng Li ◽  
Bin Zheng ◽  
Kuo-Wei Huang
Keyword(s):  
Pincer Ligands ◽  
New Class ◽  
Cooperative Catalysis ◽  
Metal Ligand

scholarly journals A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

2015 ◽  
Vol 293-294 ◽  
pp. 116-138 ◽  
Author(s):  
Huaifeng Li ◽  
Bin Zheng ◽  
Kuo-Wei Huang
Keyword(s):  
Pincer Ligands ◽  
New Class ◽  
Cooperative Catalysis ◽  
Metal Ligand

scholarly journals Diversifying metal‐ligand cooperative catalysis in semi‐synthetic [Mn]‐hydrogenases

2021 ◽  
Author(s):  
Huijie Pan ◽  
Gangfeng Huang ◽  
Matthew Wodrich ◽  
Farzaneh Fadaei Tirani ◽  
Kenichi Ataka ◽  
...  
Keyword(s):  
Cooperative Catalysis ◽  
Metal Ligand

scholarly journals Metal-ligand complexes as a new class of long-lived fluorophores for protein hydrodynamics

1995 ◽  
Vol 68 (1) ◽  
pp. 342-350 ◽  
Author(s):  
E. Terpetschnig ◽  
H. Szmacinski ◽  
H. Malak ◽  
J.R. Lakowicz
Keyword(s):  
New Class ◽  
Metal Ligand

scholarly journals Asymmetric Magnesium‐Catalyzed Hydroboration by Metal‐Ligand Cooperative Catalysis

2019 ◽  
Vol 58 (49) ◽  
pp. 17567-17571 ◽  
Author(s):  
Alban Falconnet ◽  
Marc Magre ◽  
Bholanath Maity ◽  
Luigi Cavallo ◽  
Magnus Rueping
Keyword(s):  
Cooperative Catalysis ◽  
Metal Ligand

Tetranuclear Strontium and Barium Siloxide/Amide Clusters in Metal-Ligand Cooperative Catalysis

2018 ◽  
Vol 2018 (18) ◽  
pp. 1938-1944 ◽  
Author(s):  
Benjamin Freitag ◽  
Phillip Stegner ◽  
Katharina Thum ◽  
Christian A. Fischer ◽  
Sjoerd Harder
Keyword(s):  
Cooperative Catalysis ◽  
Metal Ligand

scholarly journals Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand

2021 ◽  
Author(s):  
Kate Jesse ◽  
Mu-Chieh Chang ◽  
Alexander S. Filatov ◽  
John Anderson
Keyword(s):  
Redox State ◽  
Oxidation States ◽  
Pincer Ligands ◽  
Detailed Characterization ◽  
Metal Centers ◽  
Redox Couples ◽  
Redox Active ◽  
Secondary Coordination Sphere ◽  
Powerful Strategy ◽  
Metal Ligand

<div>Nature uses control of the secondary coordination sphere</div><div>to facilitate an astounding variety of transformations. Similarly, synthetic chemists have found metal-ligand cooperativity to be a powerful strategy for designing complexes that can mediate challenging reactivity. In particular, this strategy has been used to facilitate two electron reactions with first row transition metals that</div><div>more typically engage in one electron redox processes. While NNN pincer ligands feature prominently in this area, examples which can potentially engage in both proton and electron transfer are less common. Dihydrazonopyrrole (DHP) ligands have been isolated in a variety of redox and protonation states when complexed to Ni. However, the redox-state of this ligand scaffold is less obvious when</div><div>complexed to metal centers with more accessible redox couples. Here, we synthesize a new series of Fe-DHP complexes in two distinct oxidation states. Detailed characterization supports that the redox chemistry</div><div>in this set is still primarily ligand based. Finally, these</div><div>complexes exist as 5-coordinate species with an open coordination site offering the possibility of enhanced reactivity.</div>

Metal-Ligand Cooperation at Phosphine-Based Acceptor Pincer Ligands

2020 ◽  
Author(s):  
Martine R. Tiddens ◽  
Marc-Etienne Moret
Keyword(s):  
Pincer Ligands ◽  
Metal Ligand

scholarly journals Diphosphinine Derivatives of Terpyridine: A New Class of Neutral π-Accepting PNP-Pincer Ligands

2008 ◽  
Vol 14 (29) ◽  
pp. 8803-8807 ◽  
Author(s):  
Christian Müller ◽  
Evgeny A. Pidko ◽  
Martin Lutz ◽  
Anthony L. Spek ◽  
Dieter Vogt
Keyword(s):  
Pincer Ligands ◽  
New Class ◽  
Derivatives Of
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