ChemInform Abstract: Palladium-Catalyzed Oxidative Difunctionalization of Alkenes with α-Carbonyl Alkyl Bromides Initiated Through a Heck-Type Insertion: A Route to Indolin-2-ones.

ChemInform ◽  
2015 ◽  
Vol 46 (1) ◽  
Author(s):  
Jian-Hong Fan ◽  
Wen-Ting Wei ◽  
Ming-Bo Zhou ◽  
Ren-Jie Song ◽  
Jin-Heng Li
Keyword(s):  
Alkyl Bromides ◽  
Palladium Catalyzed ◽  
Oxidative Difunctionalization

scholarly journals Palladium-Catalyzed Borylation of Primary Alkyl Bromides

2012 ◽  
Vol 77 (15) ◽  
pp. 6629-6633 ◽  
Author(s):  
Amruta Joshi-Pangu ◽  
Xinghua Ma ◽  
Mohamed Diane ◽  
Sidra Iqbal ◽  
Robert J. Kribs ◽  
...  
Keyword(s):  
Alkyl Bromides ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Carbocyclizations of Unactivated Alkyl Bromides with Alkenes Involving Auto-tandem Catalysis

2017 ◽  
Vol 139 (33) ◽  
pp. 11595-11600 ◽  
Author(s):  
Alexander R. O. Venning ◽  
Megan R. Kwiatkowski ◽  
Joan E. Roque Peña ◽  
Brendan C. Lainhart ◽  
Akil A. Guruparan ◽  
...  
Keyword(s):  
Tandem Catalysis ◽  
Alkyl Bromides ◽  
Palladium Catalyzed

scholarly journals Palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides

2017 ◽  
Vol 13 ◽  
pp. 2610-2616 ◽  
Author(s):  
Tao Fan ◽  
Wei-Dong Meng ◽  
Xingang Zhang
Keyword(s):  
Alkyl Radical ◽  
Functional Group ◽  
High Efficiency ◽  
Mechanistic Studies ◽  
Reaction Conditions ◽  
Type Reaction ◽  
Alkyl Bromides ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Hydroxy Groups

An efficient palladium-catalyzed Heck-type reaction of secondary trifluoromethylated alkyl bromides has been developed. The reaction proceeds under mild reaction conditions with high efficiency and excellent functional group tolerance, even towards formyl and hydroxy groups. Preliminary mechanistic studies reveal that a secondary trifluoromethylated alkyl radical is involved in the reaction.

Visible-Light-Driven Palladium-Catalyzed Radical Alkylation of C−H Bonds with Unactivated Alkyl Bromides

2017 ◽  
Vol 56 (49) ◽  
pp. 15683-15687 ◽  
Author(s):  
Wen-Jun Zhou ◽  
Guang-Mei Cao ◽  
Guo Shen ◽  
Xing-Yong Zhu ◽  
Yong-Yuan Gui ◽  
...  
Keyword(s):  
Visible Light ◽  
Alkyl Bromides ◽  
Visible Light Driven ◽  
Palladium Catalyzed

Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides

Synthesis ◽  
2018 ◽  
Vol 50 (15) ◽  
pp. 2908-2914 ◽  
Author(s):  
Rui Shang ◽  
Yao Fu ◽  
Guang-Zu Wang
Keyword(s):  
Blue Light ◽  
Palladium Catalyst ◽  
Light Emitting Diodes ◽  
Oxidative Addition ◽  
Phosphine Ligands ◽  
Light Emitting ◽  
Alkyl Radicals ◽  
Alkyl Bromides ◽  
Palladium Catalyzed ◽  
Tertiary Alkyl

A palladium catalyst in combination with two types of phosphine ligands efficiently catalyzes direct C–H alkylation of heteroarenes with secondary and tertiary alkyl bromides under irradiation conditions. Irradiation of blue light-emitting diodes (blue LEDs) effectively excites phosphine-ligated palladium catalyst to facilitate oxidative addition with alkyl bromides, and also excites the alkylpalladium species to enable the generation of alkyl radicals to react with heteroarenes.

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