ChemInform Abstract: Solvent-Assisted Linker Exchange: An Alternative to the de novo Synthesis of Unattainable Metal-Organic Frameworks

ChemInform ◽  
2014 ◽  
Vol 45 (27) ◽  
pp. no-no
Author(s):  
Olga Karagiaridi ◽  
Wojciech Bury ◽  
Joseph E. Mondloch ◽  
Joseph T. Hupp ◽  
Omar K. Farha
Keyword(s):  
De Novo ◽  
Metal Organic Frameworks ◽  
De Novo Synthesis ◽  
Metal Organic ◽  
Linker Exchange

Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks

2014 ◽  
Vol 53 (18) ◽  
pp. 4530-4540 ◽  
Author(s):  
Olga Karagiaridi ◽  
Wojciech Bury ◽  
Joseph E. Mondloch ◽  
Joseph T. Hupp ◽  
Omar K. Farha
Keyword(s):  
De Novo ◽  
Metal Organic Frameworks ◽  
De Novo Synthesis ◽  
Metal Organic ◽  
Linker Exchange

Metal–Organic Frameworks Containing (Alkynyl)Gold Functionalities: A Comparative Evaluation of Solvent-Assisted Linker Exchange, de Novo Synthesis, and Post-synthesis Modification

2014 ◽  
Vol 14 (12) ◽  
pp. 6320-6324 ◽  
Author(s):  
Sherzod T. Madrahimov ◽  
Tulay A. Atesin ◽  
Olga Karagiaridi ◽  
Amy A. Sarjeant ◽  
Omar K. Farha ◽  
...  
Keyword(s):  
Comparative Evaluation ◽  
De Novo ◽  
Metal Organic Frameworks ◽  
De Novo Synthesis ◽  
Metal Organic ◽  
Post Synthesis ◽  
Linker Exchange

Approaches to drug delivery: Confinement of aspirin in MIL-100(Fe) and aspirin in the de novo synthesis of metal–organic frameworks

2016 ◽  
Vol 223 ◽  
pp. 254-260 ◽  
Author(s):  
Brenda Singco ◽  
Li-Hao Liu ◽  
Ya-Ting Chen ◽  
Yung-Han Shih ◽  
Hsi-Ya Huang ◽  
...  
Keyword(s):  
Drug Delivery ◽  
De Novo ◽  
Metal Organic Frameworks ◽  
De Novo Synthesis ◽  
Metal Organic

Solvent-assisted linker exchange enabled preparation of cerium-based metal–organic frameworks constructed from redox active linkers

2020 ◽  
Vol 7 (4) ◽  
pp. 984-990 ◽  
Author(s):  
Florencia A. Son ◽  
Ahmet Atilgan ◽  
Karam B. Idrees ◽  
Timur Islamoglu ◽  
Omar K. Farha
Keyword(s):  
De Novo ◽  
Metal Organic Frameworks ◽  
Chemical Warfare Agents ◽  
Chemical Warfare ◽  
Redox Active ◽  
Warfare Agents ◽  
Metal Organic ◽  
Linker Exchange

Preparation of Ce(iv)-based MOFs with redox active linkers, unattainable de novo, using SALE for the detoxification of chemical warfare agents.

Linker Exchange via Migration along the Backbone in Metal–Organic Frameworks

2021 ◽  
Author(s):  
Nader Al Danaf ◽  
Waldemar Schrimpf ◽  
Patrick Hirschle ◽  
Don C. Lamb ◽  
Zhe Ji ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Linker Exchange

scholarly journals Opening Metal–Organic Frameworks Vol. 2: Inserting Longer Pillars into Pillared-Paddlewheel Structures through Solvent-Assisted Linker Exchange

2013 ◽  
Vol 25 (17) ◽  
pp. 3499-3503 ◽  
Author(s):  
Olga Karagiaridi ◽  
Wojciech Bury ◽  
Emmanuel Tylianakis ◽  
Amy A. Sarjeant ◽  
Joseph T. Hupp ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Linker Exchange

Enhancement of photocatalytic performance in two zinc-based metal–organic frameworks by solvent assisted linker exchange

CrystEngComm ◽  
2017 ◽  
Vol 19 (38) ◽  
pp. 5749-5754 ◽  
Author(s):  
Mohammad Yaser Masoomi ◽  
Minoo Bagheri ◽  
Ali Morsali
Keyword(s):  
Photocatalytic Performance ◽  
Metal Organic Frameworks ◽  
Photocatalytic Properties ◽  
Metal Organic ◽  
Linker Exchange

Solvent-assisted linker exchange (SALE) was performed on two pillared metal–organic frameworks (MOFs), [Zn2(oba)2(4-bpdb)]n·(DMF)2 (TMU-4) and [Zn(oba)(4-bpmb)0.5]n·(DMF)1.5 (TMU-6), to tune their photocatalytic properties.

scholarly journals Remodelling a Shp: Transmetallation in a Rare-Earth Cluster-Based Metal–Organic Framework

2021 ◽  
Author(s):  
Hudson de Aguiar Bicalho ◽  
P. Rafael Donnarumma ◽  
Victor Quezada-Novoa ◽  
Hatem M. Titi ◽  
Ashlee J Howarth
Keyword(s):  
Rare Earth ◽  
Single Crystal ◽  
Surface Area ◽  
De Novo ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Exchange ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic

<div> <p>Post-synthetic modification (PSM) of metal–organic frameworks (MOFs) is an important strategy for accessing MOF analogues that cannot be easily synthesized <i>de novo</i>. In this work, the rare-earth (RE) cluster-based MOF, Y-CU-10, with <b>shp</b> topology was modified through transmetallation using a series of RE ions, including: La(III), Nd(III), Eu(III), Tb(III), Er(III), Tm(III), and Yb(III). In all cases, metal-exchange higher than 70 % was observed, with reproducible results. All transmetallated materials were fully characterized and compared to the parent MOF, Y-CU-10, in regards to crystallinity, surface area, and morphology. Additionally, single-crystal X-ray diffraction (SCXRD) measurements were performed to provide further evidence of transmetallation occurring in the nonanuclear cluster nodes of the MOF. </p> </div>

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities

2010 ◽  
Vol 2 (11) ◽  
pp. 944-948 ◽  
Author(s):  
Omar K. Farha ◽  
A. Özgür Yazaydın ◽  
Ibrahim Eryazici ◽  
Christos D. Malliakas ◽  
Brad G. Hauser ◽  
...  
Keyword(s):  
Surface Area ◽  
De Novo ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
De Novo Synthesis ◽  
Metal Organic ◽  
Organic Framework
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