De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities

2010 ◽  
Vol 2 (11) ◽  
pp. 944-948 ◽  
Author(s):  
Omar K. Farha ◽  
A. Özgür Yazaydın ◽  
Ibrahim Eryazici ◽  
Christos D. Malliakas ◽  
Brad G. Hauser ◽  
...  
Keyword(s):  
Surface Area ◽  
De Novo ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
De Novo Synthesis ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities

2014 ◽  
Vol 20 (39) ◽  
pp. 12389-12393 ◽  
Author(s):  
Oleksii V. Gutov ◽  
Wojciech Bury ◽  
Diego A. Gomez-Gualdron ◽  
Vaiva Krungleviciute ◽  
David Fairen-Jimenez ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Storage ◽  
Metal Organic ◽  
Organic Framework

Preferential adsorption of ethane over ethylene on a Zr-based metal-organic framework: impacts of C-H···N hydrogen bonding

2021 ◽  
Author(s):  
Yaping Zhang ◽  
Daofei Lv ◽  
Jiayu Chen ◽  
Zewei Liu ◽  
Chongxiong Duan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Surface Area ◽  
Energy Efficient ◽  
Metal Organic Framework ◽  
Bet Surface Area ◽  
Preferential Adsorption ◽  
Metal Organic ◽  
Organic Framework

The separation of ethylene/ethane mixture using energy-efficient technologies is important but challenging. Here, we prepared a Zr-based metal-organic framework (MOF-545) possessing high Brunauer-Emmett-Teller (BET) surface area of 2265.4 m2/g, and...

Formation of a Metal-Organic Framework with High Surface Area and Gas Uptake by Breaking Edges Off Truncated Cuboctahedral Cages

2013 ◽  
Vol 125 (43) ◽  
pp. 11492-11495 ◽  
Author(s):  
Ruirui Yun ◽  
Zhiyong Lu ◽  
Yi Pan ◽  
Xiaozeng You ◽  
Junfeng Bai
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

An Interpenetrated Metal–Organic Framework and Its Gas Storage Behavior: Simulation and Experiment

2011 ◽  
Vol 50 (21) ◽  
pp. 11055-11063 ◽  
Author(s):  
Daniela Frahm ◽  
Michael Fischer ◽  
Frank Hoffmann ◽  
Michael Fröba
Keyword(s):  
Metal Organic Framework ◽  
Gas Storage ◽  
Behavior Simulation ◽  
Simulation And Experiment ◽  
Metal Organic ◽  
Storage Behavior ◽  
Organic Framework

scholarly journals A new metal–organic framework with ultra-high surface area

2014 ◽  
Vol 50 (26) ◽  
pp. 3450 ◽  
Author(s):  
Ronny Grünker ◽  
Volodymyr Bon ◽  
Philipp Müller ◽  
Ulrich Stoeck ◽  
Simon Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Metal Organic ◽  
Organic Framework

The Electrochemical Reduction of a Flexible Mn(II) Salen-Based Metal-Organic Framework

2021 ◽  
Author(s):  
Marcello B Solomon ◽  
Carol Hua ◽  
Bun Chan ◽  
Tamara L Church ◽  
Seth M Cohen ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Surface Area ◽  
Metal Organic Framework ◽  
Experimental Studies ◽  
Bet Surface Area ◽  
Salen Complex ◽  
Computational Calculations ◽  
Metal Organic ◽  
Organic Framework

A new metal-organic framework (MOF) containing a Mn(II) salen complex (BET surface area = 967±6 m2 g−1) undergoes a reversible crystalline-to-amorphous transformation. Experimental studies and computational calculations show that the...

Synthesis and effect of metal–organic frame works on CO2 adsorption capacity at various pressures: A contemplating review

2019 ◽  
Vol 31 (3) ◽  
pp. 367-388 ◽  
Author(s):  
Ayesha Rehman ◽  
Sarah Farrukh ◽  
Arshad Hussain ◽  
Erum Pervaiz
Keyword(s):  
Adsorption Capacity ◽  
Surface Area ◽  
Greenhouse Gas Emission ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Climatic Changes ◽  
Microwave Assisted Synthesis ◽  
Synthesis Methods ◽  
Metal Organic ◽  
Organic Framework

The most important environmental challenge that the world is facing today is the control of the quantity of CO2 in the atmosphere, because it causes global warming. Increase in the global temperature results in greenhouse gas emission, interruption of the volcanic activity, and climatic changes. The alarming rise of the CO2 level impels to take some serious action to control these climatic changes. Various techniques are being utilized to capture CO2. However, chemical absorption and adsorption are supposed to be the most suitable techniques for post-combustion CO2 capture, but the main focus is on adsorption. The aim of this study is to provide a brief overview on the CO2 adsorption by a novel class of adsorbents called the metal–organic framework. The metal–organic framework is a porous material having high surface area with high CO2 adsorption capacity. The metal–organic frameworks possess dynamic structure and have large capacity to adsorb CO2 at either low pressure or high pressure due to its cavity size and surface area. Adsorption of CO2 in the metal–organic framework at various pressures depends upon pore volume and heat of adsorption correspondingly. In this review, different synthesis methods of the metal–organic framework such as slow evaporation, solvo thermal, mechanochemical, electrochemical, sonochemical, and microwave-assisted synthesis are briefly described as the structure of the metal–organic frameworks are mostly dependent upon synthesis techniques. In addition to this, different strategies are discussed to increase the CO2 adsorption capacity in the metal organic-framework. [Formula: see text]

A heterometallic metal–organic framework based on multi-nuclear clusters exhibiting high stability and selective gas adsorption

2019 ◽  
Vol 48 (1) ◽  
pp. 278-284 ◽  
Author(s):  
Dongmei Wang ◽  
Zihua Liu ◽  
Lili Xu ◽  
Chunxia Li ◽  
Dian Zhao ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Performance ◽  
High Stability ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Nuclear Clusters ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

Porous In/Tb-CBDA has been successfully synthesized in the light of the heterometallic cooperative crystallization (HCC) approach. In/Tb-CBDA with high thermal and chemical stability exhibited high performance for gas storage and separation.

scholarly journals Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation

2020 ◽  
Vol 12 (9) ◽  
pp. 10983-10992 ◽  
Author(s):  
Jérémy Dhainaut ◽  
Mickaële Bonneau ◽  
Ryota Ueoka ◽  
Kazuyoshi Kanamori ◽  
Shuhei Furukawa
Keyword(s):  
High Pressure ◽  
3D Printing ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Metal Organic ◽  
Microporous Solids ◽  
Organic Framework
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