ChemInform Abstract: Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene-Yne-Ketones as Carbene Precursors.

ChemInform ◽  
2014 ◽  
Vol 45 (9) ◽  
pp. no-no
Author(s):  
Jianbo Wang ◽  
et al. et al.
Keyword(s):  
Migratory Insertion ◽  
Palladium Catalyzed

scholarly journals Recent Advances in Palladium-Catalyzed Bridging C–H Activation by Using Alkenes, Alkynes or Diazo Compounds as Bridging Reagents

Synthesis ◽  
2020 ◽  
Vol 53 (02) ◽  
pp. 238-254
Author(s):  
Fulin Zhang ◽  
Luoting Xin ◽  
Saihu Liao ◽  
Xueliang Huang ◽  
Yinghua Yu
Keyword(s):  
Bond Distance ◽  
Short Review ◽  
Diazo Compounds ◽  
Bond Functionalization ◽  
Migratory Insertion ◽  
Intramolecular Reactions ◽  
Palladium Catalyzed ◽  
Direct Functionalization ◽  
Intermolecular Reactions ◽  
Metal Catalyzed

AbstractTransition-metal-catalyzed direct inert C–H bond functionalization has attracted much attention over the past decades. However, because of the high strain energy of the suspected palladacycle generated via C–H bond palladation, direct functionalization of a C–H bond less than a three-bond distance from a catalyst center is highly challenging. In this short review, we summarize the advances on palladium-catalyzed bridging C–H activation, in which an inert proximal C–H bond palladation is promoted by the elementary step of migratory insertion of an alkene, an alkyne or a metal carbene intermediate.1 Introduction2 Palladium-Catalyzed Alkene Bridging C–H Activation2.1 Intramolecular Reactions2.2 Intermolecular Reactions3 Palladium-Catalyzed Alkyne Bridging C–H Activation3.1 Intermolecular Reactions3.2 Intramolecular Reactions4 Palladium-Catalyzed Carbene Bridging C–H Activation5 Conclusion and Outlook

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

2018 ◽  
Vol 54 (92) ◽  
pp. 12994-12997 ◽  
Author(s):  
Qiu-Chao Mu ◽  
Xing-Ben Wang ◽  
Fei Ye ◽  
Yu-Li Sun ◽  
Xing-Feng Bai ◽  
...  
Keyword(s):  
Alkyl Halides ◽  
One Pot ◽  
Migratory Insertion ◽  
Palladium Catalyzed ◽  
Vinyl Silanes

One-pot formation of (E)-vinyl silanes and (E)-silyl-substituted α, β-unsaturated amides could be completed easily via palladium carbene migratory insertion in good yields and high chemoselectivity.

Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides by Carbene Migratory Insertion

2018 ◽  
Vol 130 (10) ◽  
pp. 2746-2750 ◽  
Author(s):  
Yunpeng Gao ◽  
Guojiao Wu ◽  
Qi Zhou ◽  
Jianbo Wang
Keyword(s):  
Cross Coupling ◽  
Migratory Insertion ◽  
Palladium Catalyzed

Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene–Yne–Ketones as Carbene Precursors

2013 ◽  
Vol 135 (36) ◽  
pp. 13502-13511 ◽  
Author(s):  
Ying Xia ◽  
Shuanglin Qu ◽  
Qing Xiao ◽  
Zhi-Xiang Wang ◽  
Peiyuan Qu ◽  
...  
Keyword(s):  
Migratory Insertion ◽  
Palladium Catalyzed

Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide

2014 ◽  
Vol 12 (22) ◽  
pp. 3590-3593 ◽  
Author(s):  
Fangdong Hu ◽  
Ying Xia ◽  
Zhenxing Liu ◽  
Chen Ma ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Aryl Halide ◽  
Type Reaction ◽  
Three Component Reaction ◽  
Migratory Insertion ◽  
Palladium Catalyzed

A palladium-catalyzed three-component reaction that involves an intermolecular Heck-type reaction and alkyl palladium carbene migratory insertion has been demonstrated.

Palladium-Catalyzed Carbene Migratory Insertion and Trapping with Sulfinic Acid Salts toward Allylic Sulfones

2018 ◽  
Vol 83 (8) ◽  
pp. 4762-4768 ◽  
Author(s):  
Ping-Xin Zhou ◽  
Yalei Zhang ◽  
Chunbo Ge ◽  
Yong-Min Liang ◽  
Changzheng Li
Keyword(s):  
Sulfinic Acid ◽  
Migratory Insertion ◽  
Palladium Catalyzed ◽  
Acid Salts
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