ChemInform Abstract: Rational Design of Single-Site Heterogeneous Catalysts: Towards High Chemo-, Regio- and Stereoselectivity

ChemInform ◽  
2012 ◽  
Vol 43 (48) ◽  
pp. no-no
Author(s):  
Vladimiro Dal Santo ◽  
Matteo Guidotti ◽  
Rinaldo Psaro ◽  
Leonardo Marchese ◽  
Fabio Carniato ◽  
...  
Keyword(s):  
Rational Design ◽  
Heterogeneous Catalysts ◽  
Single Site

scholarly journals Rational design of single-site heterogeneous catalysts: towards high chemo-, regio- and stereoselectivity

2012 ◽  
Vol 468 (2143) ◽  
pp. 1904-1926 ◽  
Author(s):  
Vladimiro Dal Santo ◽  
Matteo Guidotti ◽  
Rinaldo Psaro ◽  
Leonardo Marchese ◽  
Fabio Carniato ◽  
...  
Keyword(s):  
Rational Design ◽  
Heterogeneous Catalysts ◽  
Direct Synthesis ◽  
Single Site ◽  
Added Value ◽  
Catalytic Systems ◽  
Oxide Supports ◽  
Key Factor ◽  
Catalytically Active ◽  
Post Synthesis

The main methods for the design and preparation of single-site heterogeneous catalysts on inorganic oxide supports are described and reviewed. Catalytically active metal sites can be either introduced into the framework of porous materials via direct synthesis or added to a pre-existing support by post-synthesis techniques. Particular attention is paid to selected examples where the geometry, the nature and the chemical surroundings of the active single site is a key factor to obtain catalytic systems with enhanced chemo-, regio- and stereoselectivity. The ever-increasing capabilities of ‘nanoarchitecture’ at molecular level enable chemists to build ideal catalysts for the sustainable transformation of bulky and high added-value molecules.

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework

2016 ◽  
Vol 138 (32) ◽  
pp. 10232-10237 ◽  
Author(s):  
Robert J. Comito ◽  
Keith J. Fritzsching ◽  
Benjamin J. Sundell ◽  
Klaus Schmidt-Rohr ◽  
Mircea Dincă
Keyword(s):  
Cation Exchange ◽  
Heterogeneous Catalysts ◽  
Olefin Polymerization ◽  
Metal Organic Framework ◽  
Single Site ◽  
Metal Organic ◽  
Organic Framework

ChemInform Abstract: Hybrid Organic-Inorganic Structured Materials as Single-Site Heterogeneous Catalysts

ChemInform ◽  
2012 ◽  
Vol 43 (48) ◽  
pp. no-no
Author(s):  
Urbano Diaz ◽  
Mercedes Boronat ◽  
Avelino Corma
Keyword(s):  
Heterogeneous Catalysts ◽  
Single Site ◽  
Structured Materials
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