ChemInform Abstract: Hybrid Organic-Inorganic Structured Materials as Single-Site Heterogeneous Catalysts

ChemInform ◽  
2012 ◽  
Vol 43 (48) ◽  
pp. no-no
Author(s):  
Urbano Diaz ◽  
Mercedes Boronat ◽  
Avelino Corma
Keyword(s):  
Heterogeneous Catalysts ◽  
Single Site ◽  
Structured Materials

scholarly journals Hybrid organic–inorganic structured materials as single-site heterogeneous catalysts

2012 ◽  
Vol 468 (2143) ◽  
pp. 1927-1954 ◽  
Author(s):  
Urbano Díaz ◽  
Mercedes Boronat ◽  
Avelino Corma
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Structural Characteristics ◽  
Inorganic Materials ◽  
Single Site ◽  
Structured Materials ◽  
Solid Catalysts ◽  
Highly Active ◽  
Molecular Catalysts ◽  
Inorganic Structure

Catalyst selectivity is associated with well-defined homogeneous active sites. Transition metal complexes and organocatalysts are highly active and selective in the homogeneous phase, and their heterogenization by incorporating them into inorganic solid materials allows combining their excellent catalytic activity with improved separation, recovering and recycling properties. In this article, we present the structural characteristics and catalytic properties of hybrid organic–inorganic materials in which the molecular catalysts are part of the inorganic structure, emphasizing the possibilities of periodic mesoporous hybrid materials and coordination polymers as single-site solid catalysts.

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework

2016 ◽  
Vol 138 (32) ◽  
pp. 10232-10237 ◽  
Author(s):  
Robert J. Comito ◽  
Keith J. Fritzsching ◽  
Benjamin J. Sundell ◽  
Klaus Schmidt-Rohr ◽  
Mircea Dincă
Keyword(s):  
Cation Exchange ◽  
Heterogeneous Catalysts ◽  
Olefin Polymerization ◽  
Metal Organic Framework ◽  
Single Site ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Single-Site Heterogeneous Catalysts

2005 ◽  
Vol 44 (40) ◽  
pp. 6456-6482 ◽  
Author(s):  
John Meurig Thomas ◽  
Robert Raja ◽  
Dewi W. Lewis
Keyword(s):  
Heterogeneous Catalysts ◽  
Single Site
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