ChemInform Abstract: 5-Membered N-Heterocyclic Compounds by Dimethyl Carbonate Chemistry.

ChemInform ◽  
2012 ◽  
Vol 43 (25) ◽  
pp. no-no
Author(s):  
Fabio Arico ◽  
Umberto Toniolo ◽  
Pietro Tundo
2012 ◽  
Vol 14 (1) ◽  
pp. 58-61 ◽  
Author(s):  
Fabio Aricò ◽  
Umberto Toniolo ◽  
Pietro Tundo

ChemSusChem ◽  
2016 ◽  
Vol 10 (1) ◽  
pp. 53-57 ◽  
Author(s):  
F. Aricò ◽  
A. S. Aldoshin ◽  
P. Tundo

2001 ◽  
Vol 73 (7) ◽  
pp. 1117-1124 ◽  
Author(s):  
Pietro Tundo

Dimethylcarbonate (DMC) is a valuable methylating reagent which can replace methyl halides and dimethylsulfate in the methylation of a variety of nucleophiles. It couples tunable reactivity and unprecedented selectivity toward mono-C- and mono-N-methylation in the reactions of acidic CH2 and primary aromatic amines, respectively. In addition, it is a prototype example of a green reagent, since it is nontoxic, made by a clean process, and biodegradable, and it reacts in the presence of a catalytic amount of base thereby avoiding the formation of undesirable inorganic salts as by-products. Other remarkable reactions are those where DMC behaves as an oxidant: cyclic ketones are transformed into a,w-dimethyl esters with a reaction of atom efficiency of 1.0.


1997 ◽  
Vol 7 (C2) ◽  
pp. C2-527-C2-528
Author(s):  
St Bender ◽  
R. Franke ◽  
J. Hormes ◽  
A. A. Pavlychev ◽  
N. G. Fominykh ◽  
...  

2018 ◽  
Vol 601 ◽  
pp. 59-76
Author(s):  
MM White ◽  
DT Drapeau ◽  
LC Lubelczyk ◽  
VC Abel ◽  
BC Bowler ◽  
...  

2016 ◽  
Author(s):  
Liubov Biliavska ◽  
Yulia Pankivska ◽  
Olga Povnitsa ◽  
Svitlana Zagorodnya ◽  
Ganna Gudz ◽  
...  

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