scholarly journals One-Pot Preparation of Dimethyl Isosorbide fromd-Sorbitol via Dimethyl Carbonate Chemistry

ChemSusChem ◽  
2016 ◽  
Vol 10 (1) ◽  
pp. 53-57 ◽  
Author(s):  
F. Aricò ◽  
A. S. Aldoshin ◽  
P. Tundo
Keyword(s):  
Dimethyl Carbonate ◽  
Carbonate Chemistry ◽  
One Pot

One-pot synthesis of bio-based polycarbonates from dimethyl carbonate and isosorbide under metal-free condition

2020 ◽  
Vol 22 (14) ◽  
pp. 4550-4560
Author(s):  
Wenjuan Fang ◽  
Zhencai Zhang ◽  
Zifeng Yang ◽  
Yaqin Zhang ◽  
Fei Xu ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
One Pot ◽  
Free Condition ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Synthetic Strategy

A synthetic strategy for bio-based polycarbonate was developed via one-pot polymerization of renewable monomer isosorbide and dimethyl carbonate using eco-friendly organo-catalysts.

Retracted Article: One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2

2013 ◽  
Vol 15 (10) ◽  
pp. 2929-2934 ◽  
Author(s):  
Rongxian Bai ◽  
Hongkun Zhang ◽  
Fuming Mei ◽  
Shu Wang ◽  
Tao Li ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Solid Catalyst ◽  
One Pot ◽  
Highly Efficient ◽  
One Pot Synthesis ◽  
Retracted Article

One-pot synthesis of glycidol from glycerol and dimethyl carbonate over KF/sepiolite catalyst

2014 ◽  
Vol 487 ◽  
pp. 181-188 ◽  
Author(s):  
Y.T. Algoufi ◽  
U.G. Akpan ◽  
M. Asif ◽  
B.H. Hameed
Keyword(s):  
Dimethyl Carbonate ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals Hydrogen peroxide/dimethyl carbonate: a green system for epoxidation of N-alkylimines and N-sulfonylimines. One-pot synthesis of N-alkyloxaziridines from N-alkylamines and (hetero)aromatic aldehydes

2016 ◽  
Vol 18 (18) ◽  
pp. 4859-4864 ◽  
Author(s):  
Jamil Kraïem ◽  
Donia Ghedira ◽  
Thierry Ollevier
Keyword(s):  
Hydrogen Peroxide ◽  
Dimethyl Carbonate ◽  
Aromatic Aldehydes ◽  
Environmentally Benign ◽  
Green Method ◽  
One Pot ◽  
One Pot Synthesis ◽  
Green System

A green method for epoxidation of imines using an environmentally benign oxidant system, H2O2/dimethyl carbonate, was developed.

One-pot synthesis of dimethyl carbonate and glycols from supercritical CO2, ethylene oxide or propylene oxide, and methanol

2004 ◽  
Vol 263 (2) ◽  
pp. 179-186 ◽  
Author(s):  
Yanhong Chang ◽  
Tao Jiang ◽  
Buxing Han ◽  
Zhimin Liu ◽  
Weize Wu ◽  
...  
Keyword(s):  
Ethylene Oxide ◽  
Propylene Oxide ◽  
Supercritical Co2 ◽  
Dimethyl Carbonate ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals One-Pot Synthesis of Dimethyl Carbonate over Basic Zeolite Catalysts

2013 ◽  
Vol 02 (02) ◽  
pp. 22-27 ◽  
Author(s):  
Wenshuai Xu ◽  
Shengrong Ji ◽  
Wei Quan ◽  
Jianqiang Yu
Keyword(s):  
Dimethyl Carbonate ◽  
Zeolite Catalysts ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals One-Pot, Metal-Free Synthesis of Dimethyl Carbonate from CO2 at Room Temperature

2020 ◽  
Vol 1 (3) ◽  
pp. 298-314
Author(s):  
Santosh Govind Khokarale ◽  
Thai Q. Bui ◽  
Jyri-Pekka Mikkola
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Dimethyl Carbonate ◽  
High Selectivity ◽  
Chemical Species ◽  
Side Reactions ◽  
Ambient Conditions ◽  
Reaction Conditions ◽  
One Pot ◽  
Metal Free

Herein, we report on the metal-free, one-pot synthesis of industrially important dimethyl carbonate (DMC) from molecular CO2 under ambient conditions. In this process, initially the CO2 was chemisorbed through the formation of a switchable ionic liquid (SIL), [DBUH] [CH3CO3], by the interaction of CO2 with an equivalent mixture of organic superbase 1,8-diazabicyclo-[5.4.0]-undec-7-ene (DBU) and methanol. The obtained SIL further reacted with methyl iodide (CH3I) to form DMC. The synthesis was carried out in both dimethyl sulfoxide (DMSO) and methanol. Methanol is preferred, as it not only served as a reagent and solvent in CO2 capture and DMC synthesis, but it also assisted in controlling the side reactions between chemical species such as CH3I and [DBUH]+ cation and increased the yield of DMC. Hence, the use of methanol avoided the loss of captured CO2 and favored the formation of DMC with high selectivity. Under the applied reaction conditions, 89% of the captured CO2 was converted to DMC. DBU was obtained, achieving 86% recovery of its salts formed during the synthesis. Most importantly, in this report we describe a simple and renewable solvent-based process for a metal-free approach to DMC synthesis under industrially feasible reaction conditions.

scholarly journals New developments in dimethyl carbonate chemistry

2001 ◽  
Vol 73 (7) ◽  
pp. 1117-1124 ◽  
Author(s):  
Pietro Tundo
Keyword(s):  
Aromatic Amines ◽  
Dimethyl Carbonate ◽  
Catalytic Amount ◽  
Inorganic Salts ◽  
Cyclic Ketones ◽  
Carbonate Chemistry ◽  
Methyl Halides ◽  
New Developments ◽  
Primary Aromatic Amines ◽  
By Products

Dimethylcarbonate (DMC) is a valuable methylating reagent which can replace methyl halides and dimethylsulfate in the methylation of a variety of nucleophiles. It couples tunable reactivity and unprecedented selectivity toward mono-C- and mono-N-methylation in the reactions of acidic CH2 and primary aromatic amines, respectively. In addition, it is a prototype example of a green reagent, since it is nontoxic, made by a clean process, and biodegradable, and it reacts in the presence of a catalytic amount of base thereby avoiding the formation of undesirable inorganic salts as by-products. Other remarkable reactions are those where DMC behaves as an oxidant: cyclic ketones are transformed into a,w-dimethyl esters with a reaction of atom efficiency of 1.0.

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