ChemInform Abstract: One-Pot Synthesis of Tetrahydrobenzo[a]xanthen-11-one Derivatives Catalyzed by Ruthenium Chloride Hydrate as a Homogeneous Catalyst.

ChemInform ◽  
2011 ◽  
Vol 42 (50) ◽  
pp. no-no
Author(s):  
Khalil Tabatabaeian ◽  
Alireza Khorshidi ◽  
Manouchehr Mamaghani ◽  
Ali Dadashi ◽  
Milad Khoshnood Jalali
2011 ◽  
Vol 89 (6) ◽  
pp. 623-627 ◽  
Author(s):  
Khalil Tabatabaeian ◽  
Alireza Khorshidi ◽  
Manouchehr Mamaghani ◽  
Ali Dadashi ◽  
Milad Khoshnood Jalali

Three-component cyclocondensation of β-naphthol, aldehydes, and 5,5-dimethylcyclohexane-1,3-dione (dimedone) was catalyzed efficiently by ruthenium chloride hydrate under mild reaction conditions to afford 12-aryl or alkyl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives in good to excellent yields.


2012 ◽  
Vol 77 (4) ◽  
pp. 407-413 ◽  
Author(s):  
Khalil Tabatabaeian ◽  
Hannaneh Heidari ◽  
Alireza Khorshidi ◽  
Manouchehr Mamaghani ◽  
Nosrat Mahmoodi

The one-pot domino Knoevenagel-type condensation/Michael reaction of aromatic, heteroaromatic and aliphatic aldehydes with 4-hydroxycoumarin in aqueous media in the presence of ruthenium salt as homogeneous catalyst was investigated. It was found that 5 mol% of RuCl3.nH2O catalyzes biscoumarin synthesis in high yields (70-95%) under optimised, mild, green and environmentally benign reaction conditions in short times (25-35min).


RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 19900-19906 ◽  
Author(s):  
Li Yang ◽  
Xiaopei Yan ◽  
Siquan Xu ◽  
Hao Chen ◽  
Haian Xia ◽  
...  

A “double character” FePO4 catalyst, which acts as a homogeneous catalyst at high temperature, was used to produce 5-HMF starting from cellulose and woody biomass without the addition of homogeneous acids.


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